BLUE PLUS PRIMER AEROSOL SDS
Revision Date: 4 May 2007
SAFETY DATA SHEET
BLUE PLUS PRIMER AEROSOL
1 SUBSTANCE IDENTIFICATION AND COMPANY
PRODUCT NAME: GALMET BLUE PLUS PRIMER AEROSOL
PRODUCT NO. GPBPA350
USE: Anti-corrosive and decorative surface coating.
SUPPLIER ITW POLYMERS & FLUIDS ITW POLYMERS & FLUIDS (NZ)
100 HASSALL ST UNIT 2 / 38 TRUEGOOD DRIVE
WETHERILL PARK 2164 EAST TAMAKI, 2013
NEW SOUTH WALES AUCKLAND
AUSTRALIA NEW ZEALAND
T: 02 9757 8800 T: 09 272 1945
F: 02 9757 3855 F: 09 273 6489
EMERGENCY CONTACT: T: 02 9757 8800 T: 09 272 1945
2 HAZARDS IDENTIFICATION
HAZARDOUS SUBSTANCE. DANGEROUS GOODS
(According to the criteria of the NOHSC and the ADG-6 code)
CLASSIFICATION F+; Extremely Flammable, Xn; Harmful
RISK PHRASES R12 Extremely Flammable.
R20 Harmful by inhalation.
SAFETY PHRASES S2 Keep out of reach of children.
S16 Keep away from sources of ignition 鈥? No Smoking.
S23 Do not breathe vapour/spray.
S24/25 Avoid contact with skin & eyes.
S33 Take precautionary measures against static discharges.
3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS-No. Content Classification
SOLVENT NAPTHA (PETROLEUM) MEDIUM 64742-88-7 10 - < 30 % F; R10. Xn; R20, R65. Xi; R37
ALIPHATIC
TOLUENE 108-88-3 0 - < 10 % F; R10. Xn; R20
SOLVENT NAPTHA (PETROLEUM) LIGHT 64742-95-6 0 - < 10 % F; R10. Xn; R20, R65.
AROMATIC
DIMETHYL ETHER 115-10-6 30 鈥? < 60 % F+; R12
4 FIRST AID MEASURES
GENERAL INFORMATION
Avoid contact with skin and eyes. Do not breathe vapour/spray. Show this safety data sheet to doctor in attendance.
INHALATION
Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by
administering oxygen. Contact physician if discomfort continues.
INGESTION
Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit does not enter the lungs. Get medical
attention immediately!
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SKIN CONTACT
Remove contaminated clothing. Wash skin thoroughly with soap and water for several minutes. Contact physician if irritation persists.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
Contact physician if irritation persists.
5 FIRE FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Fire can be extinguished using: Alcohol resistant foam. Carbon Dioxide (CO2). Dry Chemicals.
SPECIFIC HAZARDS
Extremely flammable. Avoid breathing fire vapours. Vapour may travel considerable distance to source of ignition and flash back.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SPECIAL FIRE FIGHTING PROCEDURES
Keep upwind to avoid fumes. Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with
water until fire is out. Keep run-off water out of sewers and watercourses. Dike for water control. Aerosol containers may burst and
become airborne missiles during fire.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Warn everybody of potential hazards and evacuate if necessary. Remove sources of ignition. Avoid inhalation of spray mist and contact
with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Provide adequate ventilation.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY
alerted to the Environmental Agency or other appropriate regulatory body.
SPILL CLEAN UP METHODS
Absorb with sand or other inert absorbent. Transfer to a container for disposal. Containers with collected spillage must be properly
labeled with correct contents and hazard symbol.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded. Take precautionary measures against static discharges. Storage tanks and other containers must be grounded. Do not
smoke, use naked flames or other sources of ignition. Do not eat, drink or smoke when using the product. Observe good industrial
hygiene practices.
STORAGE PRECAUTIONS
Store in tightly closed original container in a cool, dry well-ventilated place. Keep away from heat, sparks and open flame.
8 EXPOSURE CONTROL / PERSONAL PROTECTION
EXPOSURE STANDARDS
No exposure standards available for product.
Exposure standards for ingredients:
Name TWA (LT) TWA (LT) STEL (ST) STEL (ST) Source
mg/m3 ppm mg/m3 ppm
SOLVENT NAPTHA (PETROLEUM) MEDIUM 100 Shell (2007)
ALIPHATIC
SOLVENT NAPTHA (PETROLEUM) LIGHT 100 Shell (2007)
AROMATIC
TOLUENE 191 50 574 150 NOHSC
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PROTECTIVE EQUIPMENT
PROCESS CONDITIONS
Provide eyewash, quick drench.
ENGINEERING MEASURES
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded.
RESPIRATORY EQUIPMENT
Select and use respirators in accordance with AS/NZS 1715/1716.
In poorly ventilated areas use Type A organic vapour/gas filter with half face piece.
When sanding/grinding cured product the use of a P1 dust mask (disposable) or with replaceable filters is recommended.
Filter capacity and respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne
concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive pressure air
supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is recommended.
HAND PROTECTION
Use protective gloves made of: Chemical resistant gloves: e.g. Nitrile.
EYE PROTECTION
Wear safety glasses or approved chemical safety goggles where eye exposure is reasonably probable.
SKIN PROTECTION
Barrier cream, Protection suit or overalls should be worn.
HYGIENE MEASURES
Keep away from food, drink and animal feeding stuffs. Good personal hygiene is necessary. Wash hands and contaminated areas with
water and soap before leaving the work site. Do not eat, drink or smoke when using the product. Change work clothing daily before
leaving work place.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Aerosol Liquid
COLOUR Various
ODOUR Solvent.
SOLUBILITY Not soluble in water
BOILING POINT (掳C) -24.84掳C RELATIVE DENSITY 0.98 @ 20潞 C
VAPOUR DENSITY (air=1) >1 VAPOUR PRESSURE 520 kPa @ 21.1潞C
EVAPORATION RATE (butyl acetate =1) 0.140 VOLATILE BY VOL. (%) > 60 %
pH-VALUE, CONC. SOLUTION n/a FLASH POINT (掳C) -41.1掳C
FLAMMABILITY LIMIT - LOWER(%) 3.4 AUTOIGNITION TEMP. (潞C) 296掳C
FLAMMABILITY LIMIT - UPPER(%) 27.0
10 STABILITY & REACTIVITY
STABILITY
Stable under normal temperature conditions and recommended use.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.
MATERIALS TO AVOID
Strong oxidising agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire or high temperatures create: Nitrous gases (NOx). Oxides of: Carbon monoxide (CO). Carbon dioxide (CO2).
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11 TOXICOLOGICAL INFORMATION
ACUTE HEALTH EFFECTS
Contains organic solvents which in case of overexposure may depress the central nervous system causing dizziness and intoxication.
Vapours may cause headache, fatigue, dizziness and nausea.
Intentional misuse by deliberately concentrating and breathing the contents can be harmful or fatal.
May cause lung damage if swallowed.
May cause irritation to eyes.
CHRONIC HEALTH EFFECTS
Prolonged and repeated contact with solvents over a long period may lead to permanent health problems.
INGREDIENT DATA:
TOLUENE:
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit): 20 mg/24h-Moderate
Oral (rat) LD50: 636 mg/kg Skin (rabbit): 500 mg -Moderate
Inhalation (human) TCLo: 100 ppm Eye (rabbit): 0.87 mg -Mild
Inhalation (man) TCLo: 200 ppm Eye (rabbit): 2 mg/24h -SEVERE
Inhalation (rat) LC50: >26700 ppm/1h Eye (rabbit): 100 mg/30sec -Mild
Dermal (rabbit) LD50: 12124 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.
PETROLEUM DISTILLATES, N.O.S. (PETROLEUM NAPTHA)
TOXICITY
Oral (rat) LD50: >5000 mg/kg (Shell)
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
________________________ ____________________ ________________ ________________ ________________
toluene IARC:3 ILOEl
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: toluene Category: 3
REPROTOXIN
ILOEl: ILO Chemicals in the electronics industry that have toxic effects on reproduction: toluene
12 ECOLOGICAL INFORMATION
ECOTOXICITY
No data available, however expected to be harmful to the aquatic environment
MOBILITY
Do not discharge into drains, water courses or onto the ground.
DEGRADABILITY
No data available.
13 DISPOSAL INFORMATION
DISPOSAL METHODS
Do not punture or incinerate can even if empty.
Dispose of waste and residues in accordance with local authority requirements.
Spray left over paint onto newspaper, allow to dry, and dispose newspaper in general waste. Empty steel can is recyclable. Check with
you local council to see if they participate in a steel can recycling program.
14 TRANSPORT INFORMATION
ADG ROAD CLASS: 2.1
PROPER SHIPPING NAME: AEROSOLS
UN NO. ROAD 1950
ROAD PACK GR. None allocated
HAZCHEM CODE 2YE IERG (HB76: 2004) Guide 49
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IMDG CLASS 2.1 UN NO. SEA 1950
IMDG PACK GR. None allocated EMS F-D, S-U
MFAG See Guide MARINE POLLUTANT No.
UN NO. AIR 1950 ICAO CLASS 2
15 REGULATORY INFORMATION
SUSDP S5
RISK PHRASES IN FULL:
R10 Flammable
R12 Extremely Flammable.
R20 Harmful by inhalation.
R37 Irritating to respiratory system.
R65 May cause lung damage if swallowed.
16 OTHER INFORMATION
Contact: Technical Manager Phone: 02 9757 8800 (Australia)
* The solvent in this product contains less than 0.1 % benzene, classification and labelling as a carcinogen is not required.
REVISION DATE: 4 May 2007
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the
date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's
responsibility to satisfy himself as to the suitability of such information for his own particular use.
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