Ni added Al Wire Rev.Q [e] -1/8
Drafted on March 1,1996
Revised on April.3, 2006
Material Safety Data Sheet
1.Product and Company Identification
: Ni added Al Wire TANW
Product Name
Company Information : Company Name : Tanaka Denshi Kogyo K.K.
Address: 2303-15 Yoshida, Yoshinogari-cho,
Kanzaki-gun ,Saga 842-0031 Japan
Section in Charge: Quality Assurance Department
Kazunori Fujise
Tel. No. : +81-952-53-2345
Fax. No. : +81-952-52-6087
2.Composition and Information of Ingredients
Type of Material: Single Substance Product (Alloy)
Chemical Name: Aluminum Nickel Alloy
Component & Amount: Aluminum 99.995% + Nickel 0.005% by mass
Chemical Formula: Al-0.005%Ni (Alloy)
CAS No.: Not applicable(Alloy)
7429-90-5 (Al), 7440-02-0 (Ni)
Appearance : Bright gray metallic luster
2,700kg/m3
Density :
* This material is an alloy. Since there is no data available regarding the danger or
harmfulness of this kind of alloy, the relevant information below is based on Al and
Ni respectively.
On Aluminum (Al)
3.Classification of Danger & Harmfulness
Name of Classification: N.A.
Danger: When aluminum gets in touch with water, acid or alkali, hydrogen
will be generated. And hydrogen can lead to explosion.
Harmfulness: Inhale of aluminum powder can result in lung illness.
4.Measures for Emergency
When aluminum powder enters eyes: Wash eyes thoroughly with water and
consult a doctor.
When aluminum sticks on skin: Wash thoroughly with water. Take off the
Ni added Al Wire Rev.Q [e] -2/8
Drafted on March 1,1996
Revised on April.3, 2006
contaminated clothes and consult a doctor.
Although aluminum is not poisonous, an inflammation may occur
if the powder gets into a wound.
Inhale of a large amount of aluminum powder or fume for a long period may
cause lung illness (aluminum lung). In that case, move the patient
to the place full of fresh air. Rest in peace and keep warm.
Consult a doctor.
In case aluminum is swallowed: Spit and gargle.
5.Measures for Fire
To distinguish a fire: In case of powder aluminum, cover a fire with dry
sand, straw mat etc. no water for distinguishing a fire!
Be cautious for a fire may reoccur after it has been distinguished.
Fire distinguishing power: A mixture of special powders for fire distinguishing
is adopted.
6.Measures for Leakage
Since it is a solid single metal, there is no possibility of leakage.
7.Instruction Manual & Notes for Handling and Storage
Handling: When handling aluminum powder, foil or ribbon, avoid flames,
friction or shock. Keep away from water and alkali liquid.
Storage: For storage, keep away from water, acid, alkali and halogen.
8.Measures for Exposure Avoidance
Control Concentration: Not established.
Permissible Concentration(TWA)
Japan Association on Industrial Health:
3
Respirable powder 0.5mg/m
3
Gross powder 2 mg/m
ACGIH:
3
Metal 10mg/m
3
Metallic powder 10mg/m
3
Flammable powder 5mg/m
3
Welding fume 5mg/m
Facilities: Not specified.
Safety Goods:
Safety goods for breathing: Wear air-breathing-device when handling
aluminum powder.
Safety glasses: Recommended to wear.
Safety gloves: Wear rubber or leather gloves when
Ni added Al Wire Rev.Q [e] -3/8
Drafted on March 1,1996
Revised on April.3, 2006
handling aluminum powder.
Safety wears: Wear safety clothes, rubber boots when
handling aluminum powder.
9.Physical/Chemical Characteristics
Appearance: Silver white, soft metal. Face-centered cubic lattice. Ductile.
Light and non-poisonous. Thermal and electric conductive.
2,698kg/m3
Density :
Melting point: 660.4掳C
Boiling Point: 2470掳C
Solubility: Insoluble in water under normal temperature, but soluble in
it under high temperature with hydrogen being generated.
10.Stability and Reactivity
Flash point: N.A.
Ignition point: 550-640掳C (powder)
Explosion limits: upper limit: N.A. lower limit: N.A.
Flammability: Combust fiercely in air above 700掳C
Spontaneous Combustibility: The fine powder of aluminum is in danger of
combustion.
Oxidizability: No relevant information found.
Self-reactivity/Explosiveness: Aluminum powder friction together with
other ignition source will cause explosion.
Dust explosiveness: Occurs.
Stability/Reactivity: Dissolve in hydrochloric acid and dilute sulfuric
acid while hydrogen is generated. Easy to dissolve in alkali
hydroxide with hydrogen being generated. When heated, combine
with halogen, carbon, nitrogen etc. directly.
11.Information on the Harmfulness
Skin Corrosiveness: No relevant information found .
Stimulation (skin, eyes): When aluminum gets into a wound, inflammation
occurs.
Sensitization: No relevant information found .
Acute Toxicity (containing 50% of lethal dose): N.A.
Sub-acute Toxicity: N.A.
Chronic Toxicity: If the smoke caused by aluminum powder
combustion is inhaled for a long period, chronic syndromes such as
bronchial asthma, no appetite, breath difficulty etc. may appear.
Carcinogenic Effects: No relevant information found .
Mutagenic Effects (microorganism, chromosome aberration):
No relevant information found .
Effects on the Reproductive System: No relevant information found.
Ni added Al Wire Rev.Q [e] -4/8
Drafted on March 1,1996
Revised on April.3, 2006
Teratological Property: No relevant information found.
Others: May be related to Alzheimer鈥榮 disease.
12.Influence on the Environment
Biodegradability: No relevant information found.
Bioaccumulation: No relevant information found.
Fish Poisoning: No relevant information found.
13.Notes for Disposal
Collect for reuse.
14.Notes for Transportation
Not specified.
15.Relevant Laws or Regulations
Our product does not contain the substances prohibited in RoHS instruction.
Follow all regulations in your country.
(Cf.) In Japan, in case of aluminum powder:
Labor Safety & Hygiene Law: Dangerous object鈥擟ombustion
Fire Law Clause 2.7: Defined as dangerous object
Attached Table in Fire Law and Attached Table 3 in Government
Ordinance: 2nd type of dangerous object, 1st type of flammable solid, etc.
On Nickel (Ni)
3.Classification of Danger & Harmfulness
Name of Classification: N.A.
Danger: N.A.
Harmfulness: If Ni is taken in from mouth, it is found toxic inside the
trachea and veins.
4.Measures for Emergency
When Ni enters eyes: Wash eyes thoroughly with water and consult a doctor.
When Ni sticks on skin: Wash thoroughly with soap water.
Inhaled: No relevant information found.
Swallowed: Vomit and rinse the mouse with water thoroughly.
5.Measures for Fire
To distinguish a fire: Water spray
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Drafted on March 1,1996
Revised on April.3, 2006
Fire distinguishing power: Not specified.
6.Measures for Leakage
Since it is a solid simple metal, there is no possibility of leakage.
7.Instruction Manual & Notes for Handling and Storage
Handling: Keep nickel powder away from fire.
Storage: Not specified.
8.Measures for Exposure Avoidance
Control Concentration: Not established.
Permissible Concentration (TWA):
Japan Association on Industrial Health:
3
Metal 1mg/m
3
Compound 1 mg/m as Ni (carcinogenic)
ACGIH :
3
Metal 1.5mg/m (carcinogenic)
3
Dissolvable compound 0.1mg/m as Ni (carcinogenic)
3
Insoluble compound 0.2mg/m as Ni (carcinogenic)
Facilities: Not specified.
Safety Goods:
Safety goods for breathing: Wear dust-proof mask.
Safety glasses: Wear safety glasses.
Safety gloves: Wear working hygiene protection gloves.
Safety wears: Wear protection clothes.
9.Physical/Chemical Characteristics
Appearance: Silver white metallic luster. Stable under normal temperature.
8,902kg/m3
Density :
Melting point: 1453掳C
Boiling Point: 2732掳C
Solubility: Insoluble in water.
10. Stability and Reactivity
Flash point: N.A.
Ignition point: N.A.
Explosion limits: upper limit: N.A. lower limit: N.A.
Flammability: Noninflammable.
Spontaneous Combustibility: Ni powder is ignitable and may cause fire.
Oxidizability: No relevant information found.
Self-reactivity/Explosiveness: No relevant information found.
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Drafted on March 1,1996
Revised on April.3, 2006
Dust explosiveness: No relevant information found.
Stability/Reactivity: Dissolve in acid. React with carbon monoxide(CO)
to form Nickel carbonyl. React with fluorine (F), ammonium
nitrate(NH4NO3), hydrazine (NH2NH2), ammonia(NH3), performic
acid(HCOOOH), phosphorus (P), selenium (Se), sulfur(S),
hydrogen added dioxane(H + C4H6O6 ) and titan added potassium
chlorate(Ti+KClO3).
11.Information on the Harmfulness
Skin Corrosiveness: Dermatitis may occur to sensitive individuals.
Stimulation (skin, eyes): If in contact with skin frequently, dermatitis may
occur due to NiCl (as a result of the reaction with sweat).
Sensitization: No relevant information found.
Acute Toxicity (containing 50% of lethal dose):
No relevant information found.
Sub-acute Toxicity: If Ni is taken in from mouth, it is found toxic inside
the trachea and veins.
It is found that by animal tests Ni can cause tumor.
Chronic Toxicity: No relevant information found.
Carcinogenic Effects: It is found by animal tests that Ni is carcinogenic
and can produce new organism.
Mutagenic Effects (microorganism, chromosome aberration):
Found in dissolvable Ni-salt.
Effects on the Reproductive System: No relevant information found.
Teratological Property: No relevant information found.
12.Influence on the Environment
Biodegradability: Not biodegradable.
Bioaccumulation: No relevant information found.
Fish Poisoning: No relevant information found.
13.Notes for Disposal
Not specified.
14.Notes for Transportation
Not specified.
15.Relevant Laws or Regulations
Our product does not contain the substances prohibited in RoHS instruction.
Follow all regulations in your country.
(Cf.) In Japan:
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Drafted on March 1,1996
Revised on April.3, 2006
The Labor Standards Act: The Enforcement of the Labor Standards
Act::
A Law for Promotion of Using Recycled Resources.
Labor Safety and Hygiene Law
A Law for Pollution Release and Transfer Register
Etc.
16.Other information (References)
1) Handbook on Danger & Harm of Chemical Substances
Compiled under the editorial supervision of The Safety and Hygiene Department
of The Labor Ministry, published by Central Labor Accident Prevention
Association
2) Handbook of Reactive Chemical Hazards
Written by L. Bretherick, translated under the supervision of Tadao Yoshida and
Shozo Tamura, published by Maruzen Co., Ltd.
3) Threshold Limit Values for Chemical Substances and Physical Agents, and Biological
Exposure Indices (1998)
Published by ACGIH
4) Handbook of Hazardous Materials
Written by Tetsu Yamamoto, published by Shinsei-Shuppan Publishing Co., Ltd.
5) Data-book of Hazardous Chemical Materials
Compiled by The Consolidated Fire Protection Association under the editorial
supervision by The Fire Fighting Agency of Tokyo Metropolitan, published by
Maruzen Co., Ltd.
6)Hazardous Chemicals Desk Reference
Written by N. Irving Sax and Richard J. Lewis, Sr., translated under the
supervision of Shizuo Fujiwara, published by Maruzen Co., Ltd.
7) Regulations on Chemical Products Application
Published by The Chemical Daily Co., Ltd.
8) Chemistry Handbook
Edited by The Chemical Society of Japan, published by Maruzen Co., Ltd.
9)Encyclopaedia Chimica
Edited by The Editing Committee for Encyclopedia Chimica, published by
Kyoritsu Publishing Co., Ltd.
10)Dictionary of Elements
Edited by Hisao Mabuchi, published by Asakura Bookstore Co., Ltd.
11)Technical Handbook on Aluminum
Compiled by The Association of Light Metal, published by Light Metal
Publishing Co., Ltd.
12) Handbook on Industrial Poisoning
Edited by Minoru Gotoh et al, published by Ishiyaku Publishing Co., Ltd.
13)12695 Chemical Products
Published by The Chemical Daily Co., Ltd.
Ni added Al Wire Rev.Q [e] -8/8
Drafted on March 1,1996
Revised on April.3, 2006
14)New Chemical Index
Published by The Chemical Daily Co., Ltd.
Notes: This document is based on currently available information and materials, and no
guarantee is made concerning the data or evaluation mentioned herewith. The
datasheet is only applicable under normal application conditions; thus for special
purposes, please refer to other relevant documents.
Ni Al Rev.Q 1 6
1996.03.01
2006.04.03
1.
-0031 2303-15
0952-53-2345
0952-52-6087
Ni Al Rev.Q 2 6
1996.03.01
2006.04.03
Ni Al Rev.Q 3 6
1996.03.01
2006.04.03
Ni Al Rev.Q 4 6
1996.03.01
2006.04.03
Ni Al Rev.Q 5 6
1996.03.01
2006.04.03
Ni Al Rev.Q 6 6
1996.03.01
2006.04.03
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