Date Prepared: 10/28/03
ChemMasters
Supersedes: 04/10/02
Product Name: Skid-Daddle
MATERIAL SAFETY DATA SHEET
1. Chemical Product and Company Information
Product Name: Skid-Daddle
Product Description: Specially Formulated Cleaner for Removal of Rubber Skid Marks on Floor Coatings.
ChemMasters In Case of Emergency Contact:
300 Edwards Street CHEMTREC 800/424-9300
Madison, Ohio 44057
440-428-2105
2. Hazards Identification
CAUTION
OSHA COMBUSTIBLE LIQUID* - Flash Point 185 Degrees Fahrenheit
*Will not Sustain Combustion per ASTM D-4206
WHMIS Hazard Classification: Class D, Division 2B Symbol: Stylized T
Causes eye and skin irritation
May cause respiratory tract irritation
Harmful if swallowed
Potential Health Hazards - Acute
Eye: Causes eye irritation. Direct contact with the liquid causes burning, tearing and redness.
Skin: May cause irritation. Prolonged or repeated exposure may cause redness and burning, drying and cracking of
the skin.
Inhalation: Excessive concentrations of vapors or mists may cause irritation of the nose and throat.
Ingestion: Liquid is slightly toxic and may be harmful if swallowed.
Potential Health Effects - Chronic
Not applicable
Carcinogenicity: NTP IARC Monographs OSHA Regulated
NO NO NO
3.Composition / Information on Ingredients
Hazardous Components CAS # Exposure Limits % by Wt
OSHA(PEL/TWA) ACGIH (TLV/TWA) OTHER
D-Limonene 5989-27-5 鈥? 鈥? 鈥? 10%
Tripropylene Glycol Methyl Ether (TPM) 25498-49-1 鈥? 鈥? 鈥? 10%
Alcohol Ethoxylate 68439-45-2 NE NE ---- 10%
Sulfonic Acid 27176-87-0 NE NE 鈥? 1-5%
Triethanolamine 102-71-6 NE NE ---- 1-5%
Tetrasodium Ethylenediaminetetraacetate 64-02-8 NE NE ---- 1-5%
Water 7732-18-5 NE NE ---- 60-65%
4. First Aid Measures
Eye: Immediately flush with plenty of clean water.
Skin: Remove contaminated clothing. Clean affected area(s) thoroughly with soap and water.
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Get medical attention.
Ingestion: Seek medical attention if large amounts are swallowed.
SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST.
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Date Prepared: 10/28/03
Supersedes: 04/10/02
Product Name: Skid-Daddle
5. Fire Fighting Measures
Flash Point (method used): 185oF (TCC with Stirring)
Flammable Limits (% volume in air): Lower = NA Upper = NA
Auto Ignition Temperature: No data available
Extinguishing Media: Extinguish with water fog, dry chemical, CO2 or foam.
Hazard Combustion Products: Carbon dioxide, carbon monoxide, sulfur dioxide and hydrogen sulfide.
Fire Fighting Instructions: Combustible, Do not enter confined fire space without full bunker gear including a
positive pressure, NIOSH approved, self-contained breathing apparatus. Cool containers exposed to fire with
water.
6. Accidental Release Measures
Spill: Shut off ignition sources. Absorb with inert material, then place in chemical waste container for later disposal.
7. Handling and Storage
Handling: Avoid personal contact with product. Keep liquid away from heat, sparks and flame. 鈥淓mpty鈥? containers
can contain explosive vapors. Do not cut, drill, grind, weld or perform similar operations on or near containers.
Do not pressurize drums to empty them.
Storage: Store containers tightly closed with adequate ventilation in a cool, dry area.
8. Exposure Controls / Personal Protection
Exposure Controls: Mechanical exhaust should be used indoors
Personal Protection: Protective clothing, goggles and rubber gloves
9. Physical and Chemical Properties
Appearance: Clear, yellow liquid of water consistency
Odor: Citrus odor
Boiling Point: >212oF
Melting Point: Not applicable
Vapor Pressure (mm/Hg): No data available
Vapor Density (Air = 1): No data available
pH: 7 Neutral
Solubility in Water: Complete (100%)
Specific Gravity (H20 = 1): 1.0
Evaporation Rate (n-Butyl Acetate = 1): 0.1
10. Stability and Reactivity
Chemical Stability: Stable
Conditions to Avoid: Heat, sparks and flame
Incompatibility (materials to avoid): Strong oxidizing agents and cyanides
Hazardous Decomposition or By-products: Thermal decomposition in the presence of air may yield carbon
monoxide, carbon dioxide, sulfur dioxide and hydrogen sulfide
Hazardous Polymerization: Will not occur
11. Toxicological Information
Components Oral LD50 Dermal LD50 Inhalation LC50
(rat) (rabbit) (rat)
Limonene 4400 mg/kg 鈥? 鈥?
TPM 3300 mg/kg 鈥? 鈥?
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Date Prepared: 10/28/03
Supersedes: 04/10/02
Product Name: Skid-Daddle
12. Ecological Information
Possible land and water pollutant. No exact data available.
13. Disposal Considerations
Dispose of in accordance with all federal, state, and local regulations. If uncertain of local requirements, contact
the proper environmental authorities for information on waste disposal in your area.
Under RCRA 40 CFR 261 this material is hazardous waste number D001.
14. Transportation Information
For U S National Shipments < 119 gal containers: Not Regulated
For U S National Shipments > 119 gal containers: Not Regulated per DOT 49 CFR 173.120 (a) (3)
For International, Air & Vessel Shipments:
Shipping Description:
Ground: Not Regulated per DOT 49 CFR 173.120 (a) (3)
Vessel: Not Regulated per IMDG 2.3.1.3.1
Air: Not Regulated per IATA 3.3.1.3
Canada: Not Regulated per Canadian TDGR 2.18 (2) (a)
Emergency Response Guide Number: NA
When Shipping by Vessel it must be marked as a Marine Pollutant.
15. Regulatory Information
OSHA: This material is hazardous by definition of Hazardous Communications Standard (29 CFR 1910.1200)
CERCLA Reportable Quantity: The R.Q. for Sulfonic Acid is 1000 pounds. The reportable quantity for this product
would be 20000 pounds or 2400 gallons.
SARA Title III:
Section 311/312 hazard categories: acute health, delayed health, fire
Section 313 reportable ingredients:
Components CAS # Maximum %
Glycol Ethers (TPM) 25498-49-1 10 %
16. Other Information
MSDS Status: Revised Section 2, Hazards Identification; Section 14, Transportation Information, and Revised Section
2, Composition;October 28, 2003.
Industrial Abbreviation Legend on page 4 of this MSDS.
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Date Prepared: 10/28/03
Supersedes: 04/10/02
Product Name: Skid-Daddle
Industrial Abbreviation Legend
mg/m3
ACGIH American Conference of Governmental Industrial milligrams per cubic meter
NIOSH National Institute for Occupational Safety and Health
Hygienists
NTP National Toxicology Program
CAA Clean Air Act (EPA)
CERCLA Comprehensive Environmental Response, OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
Compensation & Liability Act of 1980 (Superfund) (EPA)
ppm parts per million
CNS Central Nervous System
CWA Clean Water Act (EPA) RCRA Resource Conservation and Recovery Act (EPA)
SARA EPA鈥檚 Superfund Amendment and Reauthorization
DOT Department of Transportation
Act (EPA)
EPA Environmental Protection Agency
g/kg grams per kilogram STEL Short-Term Exposure Limit, ACGIH terminology
TLV Threshold Limit Value
IARC Internal Agency for Research on Cancer
TWA Time-Weighted Average
LC50 Lethal Concentration in which 50% of the test animals are
expected to die WHMIS Canadian 鈥淲orkplace Hazardous Material Identification
System鈥?
LD50 Lethal Dose in which 50% of the test animals are
expected to die
THIS PRODUCT IS FORMULATED AND LABELED FOR
INDUSTRIAL AND COMMERCIAL APPLICATION ONLY
The information contained herein is given in good faith and based on data considered accurate. However, no warranty is
expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. ChemMasters
assumes no responsibility for personal injury or property damage to vendees, users or third parties caused by the material.
Such vendees or users assume all risks associated with the use of the material.
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This is the last page of this MSDS.
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