Date Prepared: 01/08/07
Supersedes: 11/11/02
ChemMasters
Product Name: Spray-Cure Clear with Red Dye
Material Safety Data Sheet
1. Chemical Product and Company Information
Product Name: Spray-Cure Clear/DR with Red Dye
Product Description: Concrete Curing Compound
ChemMasters In Case of Emergency Contact:
300 Edwards Street CHEMTREC 800/424-9300
Madison, Ohio 44057
440/428-2105
2. Composition / Information on Ingredients
Hazardous Components CAS # Exposure Limits % by Wt
OSHA(PEL/TWA) ACGIH(TLV/TWA) OTHER
Mineral Spirits 8052-41-3 100 ppm 100 ppm 鈥? 65-70
1, 2, 4 Trimethylbenzene 95-63-6 100 ppm 100 ppm --- <5
1, 3, 5 Trimethylbenzene 108-87-8 100 ppm 100 ppm --- <5
Hydrocarbon Resin Proprietary NE NE --- 25
Red Dye
3. Hazards Identification
CAUTION
COMBUSTIBLE LIQUID
Causes eye, skin and lung irritation
Harmful if inhaled
Harmful if swallowed
Potential Health Hazards - Acute
Eye: May cause eye irritation. Direct contact with the liquid or exposure to its vapors may cause burning, tearing and
redness.
Skin: May cause irritation. Prolonged or repeated exposure may cause redness and burning, drying and cracking of
the skin and dermatitis. Persons with preexisting skin disorders may be more susceptible to the effects of this
material.
Inhalation: Excessive concentrations of vapors or mists may cause irritation of the nose and throat and signs of nervous
system depression. Persons with impaired lung function or asthma like conditions may experience additional
breathing difficulties due to the irritating properties of this material.
Ingestion: Liquid is moderately toxic and may be harmful if swallowed; may produce CNS depression. May result
in vomiting. Aspiration of vomitus into the lungs must be avoided as even small quantities may result in aspiration
pneumonitis.
Potential Health Effects - Chronic
Kidney, lung and liver are probable target organs. See Section 11 for further information.
Carcinogenicity: NTP IARC Monographs OSHA Regulated
NO NO NO
4. First Aid Measures
Eye: Immediately flush with plenty of clean water.
Skin: Remove contaminated clothing. Clean affected area(s) thoroughly with soap and water.
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Get medical attention.
Ingestion: Seek medical attention! Do NOT induce vomiting. If vomiting occurs spontaneously, keep head
below hips to prevent aspiration of liquid into the lungs.
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SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST.
Date Prepared: 01/08/07
Supersedes: 11/11/02
Product Name: Spray-Cure Clear with Red Dye
5. Fire Fighting Measures
Flash Point (method used): 105oF (TCC)
Flammable Limits (% volume in air): Lower = 1 Upper = 7
Auto Ignition Temperature: No data available
Extinguishing Media: Extinguish with water fog, dry chemical, CO2 or foam.
Hazard Combustion Products: Carbon dioxide, carbon monoxide and/or organic compounds
Fire Fighting Instructions: Do not enter confined fire space without full bunker gear including a positive pressure,
NIOSH approved, self-contained breathing apparatus. Cool containers exposed to fire with water.
6. Accidental Release Measures
Spill: Shut off ignition sources. Absorb with inert material, then place in chemical waste container for later disposal.
7. Handling and Storage
Handling: Avoid inhalation of vapors and personal contact with product. Keep liquid away from heat, sparks and flame.
Use with adequate ventilation. 鈥淓mpty鈥? containers can contain explosive vapors. Do not cut, drill, grind, weld
or perform similar operations on or near containers. Do not pressurize drums to empty them.
Storage: Store containers tightly closed with adequate ventilation in a cool, dry area.
8. Exposure Controls / Personal Protection
Exposure Controls: Mechanical and local exhaust should be used for indoor use.
Personal Protection: Protective clothing, goggles, rubber gloves and a vapor respirator when TLV is exceeded.
9. Physical and Chemical Properties
Appearance: Translucent Red liquid of low viscosity
Odor: Aromatic solvent odor
Boiling Point: 300-355oF
Melting Point: Not applicable
Vapor Pressure (mm/Hg): 10.3 @ 100oF
Vapor Density (Air = 1): 4.3
Solubility in Water: Negligible (<5%)
Specific Gravity (H20 = 1): 0.83
Evaporation Rate (n-Butyl Acetate = 1): 0.1
10. Stability and Reactivity
Chemical Stability: Stable
Conditions to Avoid: Heat, sparks and flame
Incompatibility (materials to avoid): Strong oxidizing agents. Strong acids, bases and select amines.
Hazardous Decomposition or By-products: Thermal decomposition in the presence of air may yield carbon monoxide,
carbon dioxide and/or unidentified organic compounds.
Hazardous Polymerization: Will not occur
11. Toxicological Information
Rats exposed for 4 months to 1700 ppm of a similar solvent showed evidence of mild damage to the liver, lungs and
kidneys. These effects were not seen in rats exposed for 1 year at 350 ppm. Rats exposed during pregnancy showed
embryo/fetotoxic toxicity. Petroleum Naphtha may contain small percentages of Xylene. Xylene in high concentrations
has resulted in hearing loss in laboratory rats.
Components Oral LD50 Dermal LD50 Inhalation LC50
(rat) (rabbit) (rat)
Petroleum Naphtha (Aromatic) 4.7 g/kg 鈥? >3670 ppm/8 hours
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Date Prepared: 01/08/07
Supersedes: 11/11/02
Product Name: Spray-Cure Clear with Red Dye
12. Ecological Information
CWA considers petroleum distillate an oil under Section 311. Spills into or leading to surface waters that cause a
sheen must be reported to the National Response Center.
13. Disposal Considerations
Dispose of in accordance with all federal, state, and local regulations. If uncertain of local requirements, contact
the proper environmental authorities for information on waste disposal in your area.
Under RCRA 40 CFR 261 this material is hazardous waste number D001.
14. Transportation Information
For U S National Shipments < 119 gal containers: Not Regulated
For U S National Shipments > 119 gal containers:
Shipping Description: Combustible Liquid, N.O.S. (Petroleum Distillates), Combustible Liquid, NA1993, III
Hazard Class: Combustible Liquid
For Air and International Shipments:
Shipping Description: Flammable Liquid, N.O.S. (Petroleum Distillates), 3, UN1993, III
Hazard Class: Flammable Liquid
Emergency Response Guide Number: 128
15. Regulatory Information
OSHA: This material is hazardous by definition of Hazardous Communications Standard (29 CFR 1910.1200)
CERCLA Reportable Quantity: CWA considers petroleum distillate an oil under Section 311. Spills into or leading to
surface waters that cause a sheen must be reported to the National Response Center.
SARA Title III:
Section 311/312 hazard categories: acute health, delayed health, fire
Section 313 reportable ingredients:
Components CAS # Maximum %
1, 2, 4 Trimethylbenzene 95-63-6 3%
16. Other Information
MSDS Status: Revised Section 9.
Industrial Abbreviation Legend on page 4 of this MSDS.
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Date Prepared: 01/08/07
Supersedes: 11/11/02
Product Name: Spray-Cure Clear with Red Dye
Industrial Abbreviation Legend
mg/m3
ACGIH American Conference of Governmental Industrial milligrams per cubic meter
NIOSH National Institute for Occupational Safety and Health
Hygienists
NTP National Toxicology Program
CAA Clean Air Act (EPA)
CERCLA Comprehensive Environmental Response, OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
Compensation & Liability Act of 1980 (Superfund) (EPA)
ppm parts per million
CNS Central Nervous System
CWA Clean Water Act (EPA) RCRA Resource Conservation and Recovery Act (EPA)
SARA EPA鈥檚 Superfund Amendment and Reauthorization
DOT Department of Transportation
Act (EPA)
EPA Environmental Protection Agency
g/kg grams per kilogram STEL Short-Term Exposure Limit, ACGIH terminology
TLV Threshold Limit Value
IARC Internal Agency for Research on Cancer
TWA Time-Weighted Average
LC50 Lethal Concentration in which 50% of the test animals are
expected to die
LD50 Lethal Dose in which 50% of the test animals are
expected to die
THIS PRODUCT IS FORMULATED AND LABELED FOR
INDUSTRIAL AND COMMERCIAL APPLICATION ONLY
The information contained herein is given in good faith and based on data considered accurate. However, no warranty is
expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. The Spray-
Cure Company assumes no responsibility for personal injury or property damage to vendees, users or third parties caused
by the material. Such vendees or users assume all risks associated with the use of the material.
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This is the last page of this MSDS.
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