World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00382
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sodium Hydroxide 1,600 卤 0,008 N
Catalog Number: 1437901
HACH LANGE Gmb H Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M00382
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Laboratory Reagent
CAS No.: Not applicable
Hazard: Causes severe burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31
- -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Hydroxide
EEC Number: 2151855
CAS No.: 1310732
--
Percent Range: 1,0 - 10,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 35
TLV: 2 mg/m鲁
PEL : 2 mg/m鲁
2 mg/m 3
EU Occupational Exposure Limits:
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: 90,0 - 100,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
3. HAZARDS IDENTIFICATION
Emergenc y Overview:
Appearance: Clear, colorless liquid
Odor: None
EU Symbols: C - CORROSIVE
R PHRASES: R 35: Causes severe burns.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe burns
Skin Contact (EC): Causes severe burns
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Causes: severe burns vomiting rapid pulse and respirations shock collapse death
Target Organs (Ing E): None Reported
Inhalation: Causes: severe burns
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre -existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Infor mation:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID M EASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Call physician immediately. Remove
contaminated clothing.
Ingestion (First Aid): Do not induce vomiting. Give 1 -2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Pr perties:
o Material will not burn.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: May react violently with: strong acids
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non -reactive sorbent material. Stop spilled material from being
released to the environment.
Clean -up Technique: Cover spilled material with a dry acid, such as citric or boric. Scoop up slurry into a large beaker.
Dilute with a large excess of water. Adjust to a pH between 6 and 9 with an acid, such as sulfuric or citric. Flush reacted
material to the drain with a large excess of water.
Evacua tion Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDL ING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Store between 10掳 and 25掳C. Keep a way from: acids / acid fumes.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Maintain general industrial
hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Keep away from: acids/acid fumes
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: None
pH: 14
Vapor Pressure: Not dete rmined
Vapor Density (air = 1): Not determined
Boiling Point: ~100掳 C (~212掳 F)
Melting Point: Not determined
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion L imits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,064
Evaporation Rate (water = 1): 0,58
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,00 in/yr
Aluminum: >20 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heating to decomposition. Evaporation
Reactivity / Incompatibility: May react violently in contact with: strong acids oxidizers Incompatible with: halogenated
organic compounds aluminum nitro compounds flammable liquids tin zinc
Hazardous Decomposition: No hazardous decomposition products known.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Da ta: Sodium Hydroxide: Oral rabbit LDLo = 500 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These d isposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Sodium Hydroxide Solution
--
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1824
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Sodium Hydroxide Solution
--
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1824
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Sodium Hydroxide Solution
--
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: 1824
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following cla ssification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: C - CORROSIVE
R PHRASES: R 35: Causes severe burns.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S
37/39: Wear suitable gloves and eye / face protection. S 45: In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
______________________________________
16. OTHER INFORMATION
Refere nces: Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332 -2983. TLV's
Threshold Limit Values and Biological Exposure Indices for 1992 -1993. American Conference of Governmental Industrial
Hygienists, 1992. Techni cal Judgment. In -house information. Fire Protection Guide on Hazardous Materials, 10th Ed.
Quincy, MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire
Protection Association, 1991. CCINFO RTE CS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario
Canada: 30 June 1993. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand
Reinhold Co., 1989.
R PHRASES: R 35: Causes severe burn s.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INF ORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
|