World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00621
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sulfuric Acid Standard Solution 0,035 N
Catalog Number: 2349732
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Nu mber: M00621
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Standard solution
CAS No.: Not applicable
Hazard: May cause eye irritation.
Date of MSDS Preparati on:
Day: 29
Month: April
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245,
France: +33 -(0)1 -40370404, Italy: +39 -02-66101029, Netherlands: +31 -(0)30 -2748888, Switzerland: +41 -
(0)1 -2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Demineralized Water
EEC Number: 2317912
CAS No.: 7732 -18-5
Percent Range: 90,0 - 100,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase d etails given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Isopropanol
EEC Number: 2006617
CAS No.: 67-63-0
Percent Range: 1,0 - 10,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 400 ppm (500 ppm STEL)
PEL: 400 ppm
200 ppm (500 mg/m 3)
EU Occupational Exposure Limits:
Sulfuric Acid
EEC Number: 2316395
CAS No.: 7664 -93-9
Percent Range: < 0,5
Percent Range Units: weight / weight
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 35
TLV: 1 mg/m鲁 (TWA); 3 mg/m鲁 (STEL)
PEL: 1 mg/m鲁
0,1 mg/m 3
EU Occupational Exposure Limits:
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Alcoholic
EU Symbol s: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): No effects anticipated
Target Organs (S A E): Not applicable
Ingestion (EC): Very large doses may cause: drowsiness dizziness incoordination headache abdominal
pain nausea vomiting diarrhea blood pressure problems rapid pulse and respirations
Target Organs (Ing E): Central nervous system
Inhalation: No effects anticipated
Target Organs (Inh E): Not applicable
Medical Conditions Aggravated: Pre -existing: Skin conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental teratogen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: None required.
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5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gas es.
Hazardous Combustion Products: Toxic fumes of: sulfur oxides. carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: May react violently with: strong oxidizers
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Water. Carbon dioxide Dry chemical.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and f ull
protective gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances shoul d respond
to a spill involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non -reactive sorbent material. Stop spilled material from
being released to the environment.
Clean -up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoop
up slurry into a large beaker. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium
bicarbonate. Flush reacted material to th e drain with a large excess of water. Decontaminate the area of the
spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean -up. If conditions warrant, increase the size
of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after
handling. Maintain general industrial hygiene practices when using this product.
Storage: Keep away from: oxidizers Protect from: heat sparks, flames and other ignition sources Keep
container tightly closed when not in use.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Standard solution
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when
using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid cont act with: eyes skin clothing Do not breathe: mist/vapor Wash
thoroughly after handling. Keep away from: oxidizers Protect from: heat sparks, flames and other ignition
sources
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Alcoholic
pH: 1,6
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: 89掳C
Melting Point: -1掳C
Flash Point: >212掳F (100掳C)
Method: Closed cup
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Li mits: Not determined
Upper Explosion Limits: Not determined
Specific Gravity (water = 1): 0,9943
Evaporation Rate (water = 1): 0,86
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n -octanol / water): Not applicable
Sol ubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,055 in/yr
Aluminum: 0,041 in/yr
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Contact with heat, sparks, open flames or other ignition sources. Extreme temperatures
Reactivity / Incompatibility: Incompatible with: oxidizers
Hazardous Dec omposition: Toxic fumes of: sulfur oxides carbon monoxide carbon dioxide
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicologica l Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Isopropa nol: Oral rat LD = 5045 mg/kg, Oral human LD = 2770 mg/kg
50 Lo
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
____________________________________________________________ _________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by
more stringent state or local requirements. Please consult your local environmental regulators for mor e
information. In Europe: Chemical and analysis solutions must be disposed of in compliance with the
respective national regulations. Product packaging must be disposed of in compliance with the country -specific
regulations or must be passed to a packag ing return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit compos ed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit Hazard Class: 9 UN Number 3316
____________________________________________ _________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Ai r Contaminants, Federal Register,
Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332 -2983. TLV's Threshold Limit Values and Biological
Exposure Indices for 1992 -1993. American Conference of Governmental Industrial Hygienists, 1992.
Technical Judgme nt. In -house information. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy,
MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National
Fire Protection Association, 1991.
R PHRASES: Not ap plicable
Use of the substance/preparation: Standard solution
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual
site safety programs in accordance with applicable hazard communica tion standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPAN Y 漏2006
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