World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00381
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
_____________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Mercuric Nitrate 0,2256 卤 0,0010 N
Catalog Number: 1439301
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00381
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of chloride
CAS No.: Not applicable
Hazard: Causes burns. Toxic. Cumulative poison. Experimental teratogen.
Date of MSDS Preparation:
Day: 25
Month: March
Year: 2002
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245,
France: +33-(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-
(0)1-2515151
_____________________________________________________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Nitric Acid
EEC Number: 2317142
CAS No.: 7697-37-2
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 2 ppm
PEL: 2 ppm
EU Occupational Exposure Limits: 2 ppm (5,2 mg/m3)
Mercuric Nitrate
EEC Number: 2331523
CAS No.: 7783-34-8 Contains Mercury, Dispose Per Local, State or Federal Laws.
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: T+ - VERY TOXIC
Ingredient R phrase(s) (R phrase details given in Heading 16): R 23/24/25 R 33 R 52/53
TLV: 0,025 mg(Hg)/m3 (skin)
PEL: 0,1 mg(Hg)/m3 (skin)
EU Occupational Exposure Limits: 0,1 mg/m3
Demineralized Water
EEC Number: 2317912
CAS No.: 7732-18-5
Percent Range: 90,0 - 100,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
_____________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless to light yellow liquid
Odor: Not determined
EU Symbols: T+ - VERY TOXIC
R PHRASES: R 23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R 33: Danger of
cumulative effects. R 52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): Causes irritation
Skin Absorption (EC): Toxic Will be absorbed through the skin. Effects similar to those of ingestion
Target Organs (SA E): Central nervous system Kidneys Liver
Ingestion (EC): Toxic May cause: abdominal pain nausea vomiting diarrhea shock loosening of the
teeth toxic nephritis (inflammation of the kidneys) liver damage kidney damage
Target Organs (Ing E): Central nervous system Liver Kidneys
Inhalation: No data reported.
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Allergies or sensitivity to mercury. Pre-existing: Central nervous system
diseases Kidney conditions Liver conditions
Chronic Effects: Mercury is a general protoplasmic poison; it circulates in the blood and is stored in the
liver, kidneys, spleen and bones. Main symptoms are sore mouth, tremors and psychic disturbances.
Chronic overexposure may cause central nervous system effects brain damage kidney damage liver
damage
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental teratogen.
Toxicologically Synergistic Products: None reported
_____________________________________________________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing.
Call physician immediately.
Ingestion (First Aid): Give 1-2 glasses of water. Induce vomiting using syrup of ipecac or by sticking finger
down throat. Never give anything by mouth to an unconscious person. Call physician immediately.
Inhalation: Remove to fresh air.
_____________________________________________________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, corrosive and toxic gases may be generated by thermal decomposition.
Hazardous Combustion Products: Toxic fumes of: mercury nitrogen oxides.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full
protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire.
_____________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond
to a spill involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Absorb spilled liquid
with non-reactive sorbent material. Stop spilled material from being released to the environment. Dike the
spill to contain material for later disposal.
Clean-up Technique: Mercury and its compounds are extremely toxic! Be extremely careful not to contact
the spill or breathe any vapors. Absorb spilled liquid with non-reactive sorbent material. Dispose of all
mercury contaminated material at an E.P.A. hazardous waste facility. Dispose of material in an E.P.A.
approved hazardous waste facility. Decontaminate area with commercially available mercury absorbing
compounds.
Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency
response plan) when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
_____________________________________________________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after
handling. Maintain general industrial hygiene practices when using this product.
Storage: Protect from: light heat freezing Keep away from: alkalies
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of chloride
_____________________________________________________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Maintain adequate
ventilation to keep vapor level below TWA for chemicals in this product. Maintain general industrial hygiene
practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: neoprene latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash
thoroughly after handling. Protect from: heat freezing light Keep away from: alkalies
TLV: 0,1 mg(Hg)/m3 (skin)
PEL: 0,1 mg(Hg)/m3 (skin)
EU Occupational Exposure Limits: Not established
_____________________________________________________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless to light yellow liquid
Physical State: Liquid
Odor: Not determined
pH: 0,8
Vapor Pressure: Not available
Vapor Density (air = 1): Not available
Boiling Point: Not available
Melting Point: Not available
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,033
Evaporation Rate (water = 1): Not available
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
_____________________________________________________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Exposure to direct sunlight. Extreme temperatures
Reactivity / Incompatibility: Incompatible with: alcohols alkalies
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: mercury
nitrogen oxides
Hazardous Polymerization: Will not occur.
_____________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: Mercuric Nitrate - Skin rat LD50 = 75 mg/kg
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Mercuric Nitrate - Oral rat LD50 = 26 mg/kg; Nitric acid - Oral human LDLo
= 430 mg/kg
This product does NOT contain any IARC listed chemicals.
_____________________________________________________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
_____________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by
more stringent state or local requirements. Please consult your local environmental regulators for more
information. In Europe: Chemical and analysis solutions must be disposed of in compliance with the
respective national regulations. Product packaging must be disposed of in compliance with the country-specific
regulations or must be passed to a packaging return system.
_____________________________________________________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Corrosive Liquid, N.O.S.
(Nitric Acid/Mercuric Nitrate Solution)
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1760
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Corrosive Liquid, N.O.S.
(Nitric Acid/Mercuric Nitrate Solution)
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1760
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Corrosive Liquid, N.O.S.
(Nitric Acid/Mercuric Nitrate Solution)
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 1760
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit Hazard Class: 9 UN Number 3316
_____________________________________________________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: T+ - VERY TOXIC
R PHRASES: R 23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R 33: Danger of
cumulative effects. R 52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S PHRASES: S 28a: After contact with skin, wash immediately with plenty of water. S 45: In case of
accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 60: This
material and / or its container must be disposed of as hazardous waste.
_____________________________________________________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register,
Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological
Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June
1993. List of Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification,
Packaging and Labeling of Dangerous Substances, Amended July 1992. In-house information. The Merck
Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Technical Judgment.
R PHRASES: R 23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R 33: Danger of
cumulative effects. R 52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Use of the substance/preparation: Determination of chloride
Revision Summary: Updates in Section(s) 14,
_____________________________________________________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual
site safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00015
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Diphenylcarbazone Reagent
Catalog Number: 83699
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00015
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of chloride
CAS No.: Not applicable
Hazard: Causes severe eye irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Phthalic Acid
EEC Number: 2018732
CAS No.: 88993
--
Percent Range: 65,0 - 75,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 36/37/38
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Potassium Acid Phthalate
EEC Number: 2128894
CAS No.: 877-24-7
Percent Range: 25,0 - 35,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Light pink to yellow crystals
Odor: None
EU Symbols: Xi - IRRITATING
R PHRASES: R 36/37/38: Irritating to eyes, respiratory system and skin.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): Causes irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: nausea vomiting paresthesias (tingling or burning sensation) of the hands and feet
Target Organs (Ing E): Central nervous system
Inhalation: Causes: respiratory tract irritation May cause: drunkenness drowsiness
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: Chronic overexposure may cause adverse effects to the blood
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: May react violently with: nitric acid metal nitrites
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more of loose powder is spilled.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Protect from: heat Keep away from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of chloride
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Protect
from: heat Keep away from: oxidizers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Light pink to yellow crystals
Physical State: Solid
Odor: None
pH: 5% solution = 3,1
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 167掳C; 333掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not available
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,40
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heat
Reactivity / Incompatibility: Incompatible with: oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Phthalic acid Oral rat LD50 = 7900 mg/kg; Potassium Acid Phthalate Oral rat LDLo =
3200 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASES: R 36/37/38: Irritating to eyes, respiratory system and skin.
S PHRASES: S 24: Avoid contact with skin. S 25: Avoid contact with eyes.
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations- Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. CCINFO RTECS. Canadian Centre for
Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Inhouse information. List of Dangerous
-
Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous
Substances, Amended July 1992. Technical Judgment.
R PHRASES: R 36/37/38: Irritating to eyes, respiratory system and skin.
Use of the substance/preparation: Determination of chloride
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00378
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
_____________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Mercuric Nitrate 2,256 卤 0,005 N
Catalog Number: 92101
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00378
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of chloride
CAS No.: Not applicable
Hazard: Causes severe burns. Toxic. Oxidizer. Experimental teratogen.
Date of MSDS Preparation:
Day: 25
Month: March
Year: 2002
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245,
France: +33-(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-
(0)1-2515151
_____________________________________________________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Nitric Acid
EEC Number: 2317142
CAS No.: 7697-37-2
Percent Range: 10,0 - 20,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 35
TLV: 2 ppm
PEL: 2 ppm
EU Occupational Exposure Limits: 2 ppm (5,2 mg/m3)
Mercuric Nitrate
EEC Number: 2331523
CAS No.: 7783-34-8 Contains Mercury, Dispose Per Local, State or Federal Laws.
Percent Range: 20,0 - 30,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: T+ - VERY TOXIC N - Dangerous for the Environment
Ingredient R phrase(s) (R phrase details given in Heading 16): R 26/27/28 R 33 R 34 R 51/53
TLV: 0,025 mg(Hg)/m3 (skin)
PEL: 0,1 mg(Hg)/m3 (skin)
EU Occupational Exposure Limits: 0,1 mg/m3
Demineralized Water
EEC Number: 2317912
CAS No.: 7732-18-5
Percent Range: 60,0 - 70,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
_____________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless to light yellow liquid
Odor: Not determined
EU Symbols: T+ - VERY TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. R 33: Danger
of cumulative effects. R 34: Causes burns. R 51/53: Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe burns
Skin Contact (EC): Causes severe burns
Skin Absorption (EC): Very toxic Will be absorbed through the skin. Effects similar to those of ingestion
Target Organs (SA E): Central nervous system Kidneys Liver
Ingestion (EC): Very Toxic May cause: abdominal pain nausea vomiting diarrhea shock loosening of
the teeth toxic nephritis (inflammation of the kidneys) liver damage kidney damage
Target Organs (Ing E): Central nervous system Kidneys Liver
Inhalation: May cause: respiratory tract irritation
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Allergies or sensitivity to mercury. Pre-existing: Central nervous system
diseases Kidney conditions Liver conditions
Chronic Effects: Mercury is a general protoplasmic poison; it circulates in the blood and is stored in the
liver, kidneys, spleen and bones. Main symptoms are sore mouth, tremors and psychic disturbances.
Chronic overexposure may cause central nervous system effects brain damage kidney damage liver
damage
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental teratogen.
Toxicologically Synergistic Products: None reported
_____________________________________________________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing.
Call physician immediately.
Ingestion (First Aid): Give 1-2 glasses of water. Induce vomiting using syrup of ipecac or by sticking finger
down throat. Never give anything by mouth to an unconscious person. Call physician immediately.
Inhalation: Remove to fresh air.
_____________________________________________________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, corrosive and toxic gases may be generated by thermal decomposition.
Hazardous Combustion Products: Toxic fumes of: mercury nitrogen oxides.
Fire / Explosion Hazards: STRONG OXIDIZER CONTACT WITH OTHER MATERIAL MAY CAUSE
FIRE OR EXPLOSION
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Alcohol foam. Carbon dioxide
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full
protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire.
_____________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond
to a spill involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Absorb spilled liquid
with non-reactive sorbent material. Stop spilled material from being released to the environment. Dike the
spill to contain material for later disposal.
Clean-up Technique: Mercury and its compounds are extremely toxic! Be extremely careful not to contact
the spill or breathe any vapors. Absorb spilled liquid with non-reactive sorbent material. Dispose of all
mercury contaminated material at an E.P.A. hazardous waste facility. Dispose of material in an E.P.A.
approved hazardous waste facility. Decontaminate area with commercially available mercury absorbing
compounds.
Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency
response plan) when: any quantity is spilled.
_____________________________________________________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after
handling. Maintain general industrial hygiene practices when using this product.
Storage: Protect from: heat freezing light Keep away from: oxidizable materials alkalies
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of chloride
_____________________________________________________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have a safety shower nearby. Have an eyewash station nearby. Use a fume hood to
avoid exposure to dust, mist or vapor. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: neoprene latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash
thoroughly after handling. Protect from: heat freezing light Keep away from: alkalies oxidizable materials
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
_____________________________________________________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless to light yellow liquid
Physical State: Liquid
Odor: Not determined
pH: 0,6
Vapor Pressure: Not available
Vapor Density (air = 1): Not available
Boiling Point: Not available
Melting Point: Not available
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,34
Evaporation Rate (water = 1): 0,86
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,004 in/yr
Aluminum: Not determined
_____________________________________________________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Exposure to direct sunlight. Extreme temperatures
Reactivity / Incompatibility: Incompatible with: alcohols alkalies oxidizable material
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: mercury
nitrogen oxides
Hazardous Polymerization: Will not occur.
_____________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral rat LD50 = 174 mg/kg
LC50: None reported
Dermal Toxicity Data: Mercuric Nitrate - Skin rat LD50 = 75 mg/kg
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Mercuric Nitrate - Oral rat LD50 = 26 mg/kg; Nitric acid - Oral human LDLo
= 430 mg/kg
This product does NOT contain any IARC listed chemicals.
_____________________________________________________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
_____________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by
more stringent state or local requirements. Please consult your local environmental regulators for more
information. In Europe: Chemical and analysis solutions must be disposed of in compliance with the
respective national regulations. Product packaging must be disposed of in compliance with the country-specific
regulations or must be passed to a packaging return system.
_____________________________________________________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.
(Nitric Acid/Mercuric Nitrate Solution)
ICAO Hazard Class: 8
ICAO Subsidiary Risk: 6,1
ICAO UN/ID Number: UN2922
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.
(Nitric Acid/Mercuric Nitrate Solution)
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: 6,1
I.M.O. UN Number: UN2922
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.
(Nitric Acid/Mercuric Nitrate Solution)
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: 6,1
A.D.R. UN-Number:: 2922
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit Hazard Class: 9 UN Number 3316
_____________________________________________________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: T+ - VERY TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. R 33: Danger of
cumulative effects. R 34: Causes burns. R 51/53: Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. S 28a: After contact with skin, wash immediately with plenty of water. S 36: Wear suitable
protective clothing. S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible). S 60: This material and / or its container must be disposed of as hazardous waste.
_____________________________________________________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register,
Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological
Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June
1993. List of Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification,
Packaging and Labeling of Dangerous Substances, Amended July 1992. Outside Testing. In-house
information. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Technical
Judgment.
R PHRASES: R 26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. R 33: Danger of
cumulative effects. R 34: Causes burns. R 51/53: Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Use of the substance/preparation: Determination of chloride
Revision Summary: Updates in Section(s) 14,
_____________________________________________________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual
site safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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