World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00047
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: DithiVer ® Metals Reagent
Catalog Number: 1261699
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00047
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Indicator of heavy metals
CAS No.: Not applicable
Hazard: May cause irritation. May cause allergic reaction.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Other components, each
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sodium Metabisulfite
EEC Number: 2316730
CAS No.: 7681574
--
Percent Range: > 99,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 22 R 31 R 36/37/38
TLV: 5 mg/m3 (ACGIH - TWA)
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Gray powder
Odor: Sulfur-like
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to
eyes, respiratory system and skin.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): Causes irritation
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): May cause: allergic respiratory reaction gastrointestinal tract irritation circulatory disturbances
central nervous system depression Very large doses may cause: colic diarrhea death Harmful
Target Organs (Ing E): None Reported
Inhalation: Causes: respiratory tract irritation May cause: allergic respiratory reaction difficult breathing sweating
rapid pulse and respirations blood pressure changes coughing flushing hives
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Sulfites are strong sensitizers. Inhalation and ingestion may cause allergic respiratory
reactions in asthmatics. Persons with respiratory conditions should take special care when working with products that
contain sulfites.
Chronic Effects: Chronic overexposure may cause allergic respiratory reactions
Cancer / Reproductive Toxicity Information:
An ingredient of this mixture is: IARC Group 3: Non-classifiable
Metabisulfites
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, corrosive and toxic gases may be generated by thermal decomposition.
Hazardous Combustion Products: Toxic fumes of: sodium monoxide sulfur oxides.
Fire / Explosion Hazards: May react violently with: strong acids strong oxidizers
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Protect from: moisture heat light Keep away from: oxidizers acids
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Indicator of heavy metals
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Protect from: heat moisture light
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Gray powder
Physical State: Solid
Odor: Sulfur-like
pH: 5% solution = 4,2
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 17°C; 338°F
0
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,32
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Not determined
Other: Not determined
Metal Corrosivity:
Steel: 0,004 in/yr
Aluminum: 0,019 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Exposure to light. Extreme temperatures Excess moisture
Reactivity / Incompatibility: Incompatible with: acids oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: sulfur oxides
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: Sodium metabisulfite: Cytogenic analysis hamster ovary 180 µg/l; Sister chromatid exchange on
hamster ovary at 200 µg/l
Reproductive Effects Data: Sodium metabisulfite: Oral rat TDLo = 20 g/kg effects on newborn - stillbirth; oral rat
TDLo = 40 g/kg effects on newborn - weaning or lactation index
--
Ingredient Toxicological Data: --
No toxicological data available for the ingredients of this product.
An ingredient of this mixture is: IARC Group 3: Non-classifiable
Metabisulfites
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to eyes,
respiratory system and skin.
S PHRASES: S 22: Do not breathe dust. S 26: In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice. S 37/39: Wear suitable gloves and eye / face protection.
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. In-house information. Vendor
Information. Technical Judgment. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989.
Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co.,
1984.
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to eyes,
respiratory system and skin.
Use of the substance/preparation: Indicator of heavy metals
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00153
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
_____________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Buffer Powder Pillows Citrate Type for Heavy Metals
Catalog Number: 1420299
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00153
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Buffer
CAS No.: Not applicable
Hazard: Causes irritation. Experimental carcinogen. May cause allergic reaction.
Date of MSDS Preparation:
Day: 23
Month: 10
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
_____________________________________________________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Citrate
EEC Number: 2006753
CAS No.: 68042
--
Percent Range: 10,0 - 20,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Hydrazine Sulfate
EEC Number: 2331104
CAS No.: 10034-93-2
Percent Range: 10,0 - 20,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: T - TOXIC
Ingredient R phrase(s) (R phrase details given in Heading 16): R 20/21/22 R 43 R 45
TLV: 0,1 ppm (N2H4)
PEL: 0,1 ppm as N2H4
EU Occupational Exposure Limits: None found. 3 mg/m3 Inhalable dust. For Hydrazine: 0,1 ppm (0,13 mg/m3).
Citric Acid
EEC Number: 2010691
CAS No.: 77929
--
Percent Range: 65,0 - 75,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 36
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
_____________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: Odorless
EU Symbols: T - TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 45-20/21/22: May cause cancer. Also harmful by inhalation, in contact with skin and if swallowed. R
36: Irritating to eyes. R 43: May cause sensitization by skin contact. R 51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): May cause allergic reaction May cause irritation
Skin Absorption (EC): Harmful if absorbed through the skin
Target Organs (SA E): Central nervous system
Ingestion (EC): Harmful May cause: gastrointestinal disturbances central nervous system effects
Target Organs (Ing E): Central nervous system
Inhalation: Harmful May cause: respiratory tract irritation central nervous system effects
Target Organs (Inh E): Central nervous system
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions Central
nervous system diseases Liver conditions Kidney conditions
Chronic Effects: Citric acid chronic overexposure may cause effects due to the ability of citric acid to chelate metals,
which could impair the body's ability to absorb calcium and iron. Chronic overexposure may cause cancer liver damage
adverse effects to the blood lung damage kidney damage
Cancer / Reproductive Toxicity Information:
An ingredient of this mixture is: IARC Group 2B: Experimental Carcinogen
Hydrazine Sulfate
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
_____________________________________________________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Induce vomiting using syrup of ipecac or by sticking finger down throat. Never give anything by
mouth to an unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
_____________________________________________________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: nitrogen oxides. carbon monoxide, carbon dioxide. sulfur oxides.
ammonia
Fire / Explosion Hazards: May react violently with: strong oxidizers metal nitrates
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
_____________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Work in an approved fume
hood. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the
drain with a large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
_____________________________________________________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Protect from: heat Keep away from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Buffer
_____________________________________________________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Protect from: heat Keep away from: oxidizers Use with adequate ventilation.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
_____________________________________________________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: Odorless
pH: 1% solution = 2,4
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 153°C; 307°F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not available
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,74
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,23 in/yr
Aluminum: 0,005 in/yr
_____________________________________________________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heat Excess moisture
Reactivity / Incompatibility: Incompatible with: oxidizers metal nitrates metal nitrites
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: nitrogen oxides carbon
dioxide carbon monoxide sulfur oxides ammonia
Hazardous Polymerization: Will not occur.
_____________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Citric Acid: Eye rabbit 750 µg/24H - SEVERE, Skin rabbit 500 mg/24H - MODERATE;
Hydrazine Sulfate: Eye rabbit 20 mg/24H - MODERATE
Mutation Data: Hydrazine Sulfate: Sister Chromatid Exchange - hamster - lung - 100 nmol/l; DNA inhibition - mouse -
intraperitoneal - 180 mg/kg; More data available in RTECS
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Hydrazine Sulfate: Oral rat LD50 = 601 mg/kg; Citric Acid: Oral rat LD50 = 6730 mg/kg;
Sodium Citrate: Oral rat LD50 > 8 g/kg
An ingredient of this mixture is: IARC Group 2B: Experimental Carcinogen
Hydrazine Sulfate
_____________________________________________________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
_____________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
_____________________________________________________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Environmentally Hazardous Substance, Solid, nos
(Hydrazine sulfate)
A.D.R Hazard Class: 9
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number::
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316 ALSO NOTE: If the National Competent Authority
declares this product an environmental hazard by Special Provision 909 (IMDG) and Special Provision A97 (IATA) the
classification may be UN3077 or UN3082.
_____________________________________________________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: T - TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 45-20/21/22: May cause cancer. Also harmful by inhalation, in contact with skin and if swallowed. R
36: Irritating to eyes. R 43: May cause sensitization by skin contact. R 51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
S PHRASES: S 53: Avoid exposure - obtain special instructions before use. S 24/25: Avoid contact with skin and eyes.
S 35: This material and its container must be disposed of in a safe way. S 45: In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible).
Ingredients: Hydrazine Sulfate; Citric Acid;
_____________________________________________________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. IARC Monographs on the Evaluation of
the Carcinogenic Risks to Humans. World Health Organization (Volumes 1-42) Supplement 7. France: 1987. List of
Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of
Dangerous Substances, Amended July 1992. Sixth Annual Report on Carcinogens, 1991. U.S. Department of Health and
Human Services. Rockville, MD: Technical Resources, Inc. 1991. In-house information. Technical Judgment.
R PHRASES: R 45-20/21/22: May cause cancer. Also harmful by inhalation, in contact with skin and if swallowed. R
36: Irritating to eyes. R 43: May cause sensitization by skin contact. R 51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Use of the substance/preparation: Buffer
Revision Summary: Updates in Section(s) 14,
_____________________________________________________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00190
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Chloroform
Catalog Number: 1445853
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00190
Chemical Name: Methane, trichloro-
Chemical Formula: CHCl3
Chemical Family: Halogenated Hydrocarbons
Use of the substance/preparation: Laboratory Reagent
CAS No.: 67-66-3
Hazard: Toxic. Vapors harmful. Experimental carcinogen.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chloroform
EEC Number: 2006638
CAS No.: 67663
--
Percent Range: 100,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 48/20/22 R 22 R 38 R 40
TLV: TWA = 10 ppm (49 mg/m³)
PEL: C: 50 ppm (C: 240 mg/m3)
EU Occupational Exposure Limits: 2 ppm (10 mg/m3) Skin notation (Recommended)
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless
Odor: Ether-like
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed. R 38: Irritating to skin. R 40: Limited evidence of a carcinogenic effect.
R 48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): Causes moderate irritation
Skin Absorption (EC): Causes central nervous system depression Causes kidney damage Causes liver damage
Target Organs (SA E): Central nervous system Kidneys Liver
Ingestion (EC): Causes: central nervous system depression kidney damage liver damage
Target Organs (Ing E): Central nervous system Kidneys Liver
Inhalation: Causes: central nervous system depression kidney damage liver damage
Target Organs (Inh E): Central nervous system Kidneys Liver
Medical Conditions Aggravated: Pre-existing: Central nervous system diseases Kidney conditions Liver conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
IARC Group 2B: Experimental Carcinogen
Chloroform
Additional Cancer / Reproductive Toxicity Information: Contains: a recognized teratogen. an experimental
mutagen.
Toxicologically Synergistic Products: Exposure to and/or consumption of alcohol may increase toxic effects of this
product.
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water.
Ingestion (First Aid): Do not induce vomiting. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn. During a fire, corrosive and toxic gases may be generated by thermal
decomposition.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: May react violently with: alkali metals aluminum / aluminum compounds strong bases
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Carbon dioxide Alcohol foam. Dry chemical.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Evacuate area and fight fire from a safe distance. Water runoff can cause environmental damage. Dike and collect
water used to fight fire.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Absorb spilled liquid with non-
reactive sorbent material. Stop spilled material from being released to the environment. Dike the spill to contain material
for later disposal.
Clean-up Technique: Cover with an inert material, such as sand. Sweep up material. Incinerate material at an E.P.A.
approved hazardous waste facility. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. Deny access to unnecessary and unprotected personnel. If conditions warrant, increase the
size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling. Use
with adequate ventilation. Maintain general industrial hygiene practices when using this product.
Storage: Protect from: light air Store in a cool, well-ventilated place. Keep away from: alkali metals alkalies
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Use a fume hood to avoid
exposure to dust, mist or vapor. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: lab coat pva (polyvinyl alcohol) gloves
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Use with adequate ventilation. Keep away from: alkali metals alkalies
TLV: TWA = 10 ppm (49 mg/m³)
PEL: C: 50 ppm (C: 240 mg/m3)
EU Occupational Exposure Limits: 2 ppm (10 mg/m3) Skin notation (Recommended)
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless
Physical State: Liquid
Odor: Ether-like
pH: Not determined.
Vapor Pressure: 159 mm Hg @ 20°C (68°F).
Vapor Density (air = 1): 4,1 (at boiling point of chloroform).
Boiling Point: 61°C (142°F).
Melting Point: -64°C (-83,2°F).
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,49 @ 20°C (68°F).
Evaporation Rate (water = 1): Not determined. The evaporation rate where: (ether=1) = 0,6; (butyl acetate=1) = 11,6.
Volatile Organic Compounds Content: 100%.
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: 1ml in 200ml water @ 25°C (77°F).
Acid: Not determined.
Other: Alcohol, Benzene, Ether, Carbon Tetrachloride, Carbon Disulfide.
Metal Corrosivity:
Steel: Not determined.
Aluminum: Not determined.
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Exposure to air. Exposure to light. Extreme temperatures Heating to decomposition.
Reactivity / Incompatibility: Incompatible with: alkali metals alkalies aluminum caustics coatings (such as paint,
varnish, wax, lacquer, etc.) plastics rubber
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: phosgene chlorides
carbon monoxide
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral rat LD50 = 695 mg/kg; Oral mouse LD50 = 36 mg/kg.
LC50: Inhalation rat LC50 = 47702 mg/m³/4hrs.
Dermal Toxicity Data: Skin rabbit LD50 = >20g/kg.
Skin and Eye Irritation Data: Skin rabbit (Standard Draize test) 500 mg/24hrs = MILD; Skin rabbit (Open Draize test)
10 mg/24hrs = MILD; Eye rabbit (Standard Draize test) 20 mg/24hrs = MODERATE.
Mutation Data: Sister chromatid exchange in human lymphocytes @ 10 mmol/l; Cytogenetic analysis of rat @ 597
mg/kg/5D (intermittent oral administration); DNA damage in mammalian lymphocytes @ 1 mmol/l; More data
reported in RTECS.
Reproductive Effects Data: Oral rat TDLo (female) = 1260 mg/kg (Fetotoxicity; Musculoskeletal abnormalities);
Inhalation rat TCLo (female) = 30 ppm/7H (Fertility effects; Fetotoxicity; Musculoskeletal abnormalities);
Oral mouse TDLo (male) = 2177 mg/kg (Reduced weight gain in newborn; Biochemical and metabolic effects on
newborn); More data reported in RTECS.
Ingredient Toxicological Data: --
Not applicable
IARC Group 2B: Experimental Carcinogen
Chloroform
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
Not applicable
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Chloroform
--
ICAO Hazard Class: 6,1
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1888
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Chloroform
--
I.M.O. Hazard Class: 6,1
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1888
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Chloroform
--
A.D.R Hazard Class: 6,1
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 1888
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
EEC Number: 2006638
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed. R 38: Irritating to skin. R 40: Limited evidence of a carcinogenic effect. R
48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
S PHRASES: S 36/37: Wear suitable protective clothing and gloves.
______________________________________
16. OTHER INFORMATION
References: Vendor Information. TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993.
American Conference of Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway, New Jersey:
Merck and Co., Inc., 1989. Technical Judgment. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed.
New York: Van Nostrand Reinhold Co., 1989. Sixth Annual Report on Carcinogens, 1991. U.S. Department of Health
and Human Services. Rockville, MD: Technical Resources, Inc. 1991. NIOSH/OSHA Occupational Health Guidelines
for Chemical Hazards. Cincinnati: Department of Health and Human Services, 1981. List of Dangerous Substances
Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances,
Amended July 1992. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans. World Health
Organization (Volumes 1-42) Supplement 7. France: 1987. Fire Protection Guide on Hazardous Materials, 10th Ed.
Quincy, MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire
Protection Association, 1991. CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario
Canada: 30 June 1993. Cassaret and Doull's Toxicology, 3rd Ed. New York: Macmillan Publishing Co., Inc., 1986. Air
Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. 29 CFR 1900 - 1910 (Code
of Federal Regulations - Labor). EU Occupational Exposure Limits On Line.
R PHRASES: R 22: Harmful if swallowed. R 38: Irritating to skin. R 40: Limited evidence of a carcinogenic effect. R
48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00571
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sodium Hydroxide Solution 50% (w/w)
Catalog Number: 218049
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00571
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Laboratory Reagent
CAS No.: Not applicable
Hazard: Causes burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Hydroxide
EEC Number: 2151855
CAS No.: 1310732
--
Percent Range: 45,0 - 55,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 35
TLV: 2 mg/m³
PEL: 2 mg/m³
EU Occupational Exposure Limits: 2 mg/m3
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: 45,0 - 55,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Pungent
EU Symbols: C - CORROSIVE
R PHRASES: R 35: Causes severe burns.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes burns
Skin Contact (EC): Causes burns
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Causes: burns Can cause: abdominal pain collapse vomiting death
Target Organs (Ing E): None Reported
Inhalation: Causes: burns May cause: chemical pneumonitis
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Respiratory conditions Eye conditions Skin conditions
Chronic Effects: Chronic overexposure may cause destruction of any tissue contacted
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Do not induce vomiting. Give large quantities of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Not Flammable, but reacts with most metals to form flammable hydrogen gas.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: May react violently with: acids
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Absorb spilled liquid with non-
reactive sorbent material. Stop spilled material from being released to the environment. Dike the spill to contain material
for later disposal.
Clean-up Technique: Cover spilled material with a dry acid, such as citric or boric. Scoop up slurry into a large beaker.
Dilute with a large excess of water. Adjust to a pH between 6 and 9. Use sulfuric or citric acid to lower pH. Use soda ash or
sodium bicarbonate to increase pH. Flush reacted material to the drain with a large excess of water. Decontaminate the
area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Keep container tightly closed when not in use. Store away from: acids halogenated hydrocarbons metals
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Maintain general industrial
hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: lab coat disposable latex gloves
Inhalation Protection: laboratory fume hood and / or dust / mist mask
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Keep away from: acids/acid fumes halogenated hydrocarbons
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Pungent
pH: 14
Vapor Pressure: 13mm Hg @ 60°C
Vapor Density (air = 1): Not determined
Boiling Point: 145°C (293°F)
Melting Point: Not determined
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,530
Evaporation Rate (water = 1): Not determined
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Soluble in methanol and glycerol
Metal Corrosivity:
Steel: Corrosive
Aluminum: Corrosive
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: Incompatible with: acids halogenated organic compounds nitro compounds metals zinc
tin aluminum
Hazardous Decomposition: None reported
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Sodium hydroxide: Eye irritation rabbit: 50 µg/24H - SEVERE; 1 mg/24H - SEVERE;
100 mg rinse - SEVERE; Skin irritlation rabbit: 500 mg/24H - SEVERE
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium hydroxide: Oral rat LDLo = 500 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Sodium Hydroxide Solution
--
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1824
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Sodium Hydroxide Solution
--
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1824
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Sodium Hydroxide Solution
--
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 1824
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: C - CORROSIVE
R PHRASES: R 35: Causes severe burns.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 27:
Take off immediately all contaminated clothing. S 37/39: Wear suitable gloves and eye / face protection.
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. Fire Protection
Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Fire Protection Guide on Hazardous
Materials, 10th Ed. Quincy, MA: National Fire Protection Association, 1991. In-house information. Vendor Information.
The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. List of Dangerous Substances Classified in
Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances, Amended July
1992.
R PHRASES: R 35: Causes severe burns.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00264
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Potassium Cyanide
Catalog Number: 76714
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00264
Chemical Name: Potassium Cyanide
Chemical Formula: KCN
Chemical Family: Cyanides
Use of the substance/preparation: Laboratory reagent
CAS No.: 151-508-
Hazard: Fast-acting poison.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Potassium Cyanide
EEC Number: 2057923
CAS No.: 151-50-8
Percent Range: 100,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: T+ - VERY TOXIC N - Dangerous for the Environment
Ingredient R phrase(s) (R phrase details given in Heading 16): R 26/27/28 R 32 R 50/53
TLV: 5 mg/m³ (skin)
PEL: 5 mg/m³ (skin)
EU Occupational Exposure Limits: None found. Cyanides are on the Priority List for OELs.
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: Bitter Almonds
EU Symbols: T+ - VERY TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. R 32: Contact with acids
liberates very toxic gas. R 50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Emergency response to cyanide exposure should be planned and practiced prior to work with cyanides. First
responders should start treatment and get medical attention immediately. Antidote: break an amyl nitrite pearl in cloth
and hold lightly under nose for 15 seconds. Repeat 5 times at 15 second intervals. Transport to hospital immediately.
Note to Physician: Have a cyanide first aid kit available. If patient has not responded to amyl nitrite, inject
intraveneously 10 ml of a 3% solution of sodium nitrite at a rate not greater than 2,5 - 5 ml/min. Follow directly with 50
ml of a 25 % solution of sodium thiosulfate at the same rate by the same route. Keep patient under observation. If signs
of poisoning persist or reappear, repeat nitrite and thiosulfate injections 1 hour later in onehalf the original doses.
-
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation May cause: ataxia - loss of muscular coordination respiratory stimulation
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): Harmful if absorbed through the skin Effects similar to those of ingestion
Target Organs (SA E): Central nervous system
Ingestion (EC): Very Toxic May be rapidly fatal. Causes: cyanosis ( a reduction of the blood's ability to carry
oxygen, giving a bluish discoloration) May cause: anxiety headache confusion irregular heartbeat coma death
Target Organs (Ing E): Brain Central nervous system
Inhalation: Effects similar to those of ingestion.
Target Organs (Inh E): Brain Central nervous system
Medical Conditions Aggravated: Pre-existing: Skin conditions
Chronic Effects: Chronic overexposure may cause central nervous system effects
Cancer / Reproductive Toxicity Information:
IARC Listed: No
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. an experimental
teratogen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Break an amyl nitrite pearl in cloth and hold lightly under nose for 15 seconds. Repeat every five
minutes. Administer artificial respiration with 100% oxygen. Transport to hospital immediately.
Inhalation: Break an amyl nitrite pearl in cloth and hold lightly under nose for 15 seconds. Repeat 5 times at 15 second
intervals. Transport to hospital immediately.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Reacts with water or any acid to form flammable hydrogen cyanide gas.
Hazardous Combustion Products: Toxic fumes of: cyanide compounds nitrogen oxides.
Fire / Explosion Hazards: Not combustible. Reaction with water or any acid releases toxic and flammable hydrogen
cyanide gas.
Static Discharge: None reported.
Mehanical Impact: None reported
c
Extinguishing Media: Alkali dry chemical. Do NOT use carbon dioxide. Do NOT use water.
Extinguishing Media NOT To Be Used: Not applicable Do NOT use carbon dioxide. Do NOT use water.
Fire Fighting Instruction: Evacuate area and fight fire from a safe distance. As in any fire, wear self-contained breathing
apparatus pressure-demand and full protective gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Stop spilled material from being
released to the environment.
Clean-up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Carefully mist spill
with bleach until saturated. Scoop up slurry into a large beaker. Oxidize spilled material with a 50% excess of bleach
containing at least 5% sodium hypochlorite. Allow to react for 24 hours in a fume hood. Flush reacted material to the drain
with a large excess of water. Decontaminate area with bleach solution.
Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation. Deny access to unnecessary and
unprotected personnel.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Store away from: acids / acid fumes. oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Use a fume hood to avoid
exposure to dust, mist or vapor.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: lab coat disposable latex gloves
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Keep away from: acids/acid fumes
TLV: 5 mg/m³ (skin)
PEL: 5 mg/m³ (skin)
EU Occupational Exposure Limits: None found. Cyanides are on the Priority List for OELs.
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: Bitter Almonds
pH: 11,0 (0,1% solution)
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 634° C; 1173° F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,52
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not available
Solubility:
Water: Soluble
Acid: Soluble; Generates toxic hydrogen cyanide gas
Other: Soluble in glycerol, methanol
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Heating to decomposition.
Reactivity / Incompatibility: Reacts with water or any acid to form toxic and flammable hydrogen cyanide gas.
Incompatible with: oxidizers metalic salts alkaloidal salts
Hazardous Decomposition: Contact with acids/acid fumes releases toxic cyanide gas. Heating to decomposition releases:
cyanide nitrogen oxides
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral human LD Lo = 2,857 mg/kg; Oral rat LD50 = 5 mg/kg; Ocular rabbit LD50 = 7.87 mg/kg.
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: DNA Inhibition in mouse lymphocytes @ 1 mmol/l; Cytogenic analysis in mouse mammary gland @ 1
mmol/l/48hr.
Reproductive Effects Data: Oral mammal - domestic animal TD Lo = 1767 mg/kg: effects on newborn.
--
Ingredient Toxicological Data: --
Not applicable
IARC Listed: No
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
Not applicable
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Potassium Cyanide, Solid
--
ICAO Hazard Class: 6,1
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1680
ICAO Packing Group: I
I.M.O.:
I.M.O. Proper Shipping Name: Potassium Cyanide, Solid
--
I.M.O. Hazard Class: 6,1
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1680
I.M.O. Packing Group: I
A.D.R.:
A.D.R. Proper Shipping Name: Potassium Cyanide, Solid
--
A.D.R Hazard Class: 6,1
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 1680
A.D.R. Packing Group: I
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
EEC Number: 2057923
EEC LABEL COPY:
EU Symbols: T+ - VERY TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. R 32: Contact with acids
liberates very toxic gas. R 50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S PHRASES: S 7: Keep container tightly closed. S 28a: After contact with skin, wash immediately with plenty of water.
S 29: Do not empty into drains. S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible). S 60: This material and / or its container must be disposed of as hazardous waste. S 61: Avoid
release to the environment. Refer to special instructions/Safety data sheets.
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. CCINFO RTECS. Canadian Centre for Occupational Health and
Safety. Hamilton, Ontario Canada: 30 June 1993. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA:
National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection
Association, 1991. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams
and Wilkins Co., 1984. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans. World Health
Organization (Volumes 1-42) Supplement 7. France: 1987. In-house information. List of Dangerous Substances
Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances,
Amended July 1992. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand
Reinhold Co., 1989. Sixth Annual Report on Carcinogens, 1991. U.S. Department of Health and Human Services.
Rockville, MD: Technical Resources, Inc. 1991. Technical Judgment. TLV's Threshold Limit Values and Biological
Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992. Vendor Information.
The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989.
R PHRASES: R 26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. R 32: Contact with acids
liberates very toxic gas. R 50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Use of the substance/preparation: Laboratory reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
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