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Product MSDS Distributor Format Language Quantity
2141299 N/A Hach Company EEC English 1
__________________________________________________________________________________________________________
Total Enclosures: 1
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00096
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Triazole Reagent
Catalog Number: 2141299
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00096
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of benzotriazole and tolyltriazole
CAS No.: Not applicable
Hazard: Allergen Causes irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Cyclohexanediaminetetraacetic Acid, Disodium Salt
EEC Number: 2273163
CAS No.: 57137-35-6
Percent Range: 1,0 - 10,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Disodium Succinate
EEC Number: 2057787
CAS No.: 6106214
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Percent Range: 45,0 - 55,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Metabisulfite
EEC Number: 2316730
CAS No.: 7681574
--
Percent Range: 25,0 - 35,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 22 R 36/37/38
TLV: 5 mg/m3 (ACGIH - TWA)
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Succinic Acid
EEC Number: 2037404
CAS No.: 110-15-6
Percent Range: 15,0 - 25,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: None
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to
eyes, respiratory system and skin.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe irritation
Skin Contact (EC): Causes irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: irritation of the mouth and esophagus nausea vomiting diarrhea weakness central
nervous system depression circulatory disturbances May cause allergic respiratory reaction if swallowed or inhaled.
Target Organs (Ing E): Cardiovascular system Central nervous system
Inhalation: Causes: respiratory tract irritation May cause: weakness central nervous system depression circulatory
disturbances
Target Organs (Inh E): Cardiovascular system Central nervous system
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions Asthma
Sulfites are strong sensitizers. Inhalation and ingestion may cause allergic respiratory reactions in asthmatics. Persons
with respiratory conditions should take special care when working with products that contain sulfites.
Chronic Effects: Chronic overexposure may cause allergic respiratory reactions
Cancer / Reproductive Toxicity Information:
An ingredient of this mixture is: IARC Group 3: Non-classifiable
Sulfites
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water for 15 minutes. Remove contaminated clothing. Call
physician immediately.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, irritating and highly toxic gases may be generated by thermal decomposition.
Hazardous Combustion Products: Toxic fumes of: sodium monoxide sulfur oxides. carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: May react violently with: oxidizers
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Alcohol foam. Carbon dioxide
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Store at 10 - 30掳C. Protect from: moisture Keep away from: acids
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of benzotriazole and tolyltriazole
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Use general ventilation to
minimize exposure to mist, vapor or dust. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Use with adequate ventilation. Protect from: heat moisture Keep away from: acids/acid fumes
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: None
pH: 5% solution = 4,9
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 215掳 C (419掳 F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,76
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: Not Applicable
Aluminum: Not Applicable
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Extreme temperatures Heating to decomposition.
Reactivity / Incompatibility: May react violently in contact with: oxidizers Incompatible with: acids
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: sulfur oxides carbon
dioxide carbon monoxide
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium Metabisulfate: Oral rat LD50 >2000 mg/kg; Succinic Acid: Oral rat LD50 =
2260 mg/kg
An ingredient of this mixture is: IARC Group 3: Non-classifiable
Sulfites
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: Sodium Metabisulfite: 120 ppm/24, 48 & 96 hours/mosquito fish / TLm / fresh water;
Succinic Acid: Degradability- BOD5 (g/g) - 0.42-0.57 Std. Dilution, sewage seed (acclimated)
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
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ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
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I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
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A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to eyes,
respiratory system and skin.
S PHRASES: S 22: Do not breathe dust. S 26: In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice. S 37/39: Wear suitable gloves and eye / face protection.
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16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,
1989. pp. 2332-2983. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans. World Health
Organization (Volumes 1-42) Supplement 7. France: 1987. In-house information. Technical Judgment. Vendor
Information.
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to eyes,
respiratory system and skin.
Use of the substance/preparation: Determination of benzotriazole and tolyltriazole
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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