World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00099
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Phthalate-Phosphate Reagent Powder Pillows
Catalog Number: 2150166
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00099
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of nickel Determination of cobalt
CAS No.: Not applicable
Hazard: Causes irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
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(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Pyrophosphate
EEC Number: 2317671
CAS No.: 13472-36-1
Percent Range: 20,0 - 30,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 mg/m3
PEL: 5 mg/m3
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Potassium Acid Phthalate
EEC Number: 2128894
CAS No.: 877-24-7
Percent Range: 70,0 - 80,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: Not determined
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): Very large doses may cause: nausea vomiting paresthesias (tingling or burning sensation) of the
hands and feet diarrhea abdominal cramps abdominal pain irritation of the mouth and esophagus
Target Organs (Ing E): None Reported
Inhalation: May cause: coughing choking respiratory tract irritation
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: phosphorus oxides sodium monoxide carbon monoxide, carbon
dioxide.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Protect from: heat Keep away from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of nickel Determination of cobalt
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Protect
from: heat Keep away from: oxidizers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: Not determined
pH: 5% solution = 4,9
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 230掳C; 446掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not available
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,74
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,009 in/year
Aluminum: 0,014 in/year
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Extreme temperatures
Reactivity / Incompatibility: None reported
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: phosphorus oxides
carbon monoxide carbon dioxide
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium Pyrophosphate Oral rat LD50 = 4000 mg/kg; Potassium Acid Phthalate Oral rat
LDLo = 3200 mg/kg
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
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ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. In-houseinformation. Technical
Judgment.
R PHRASES: Not applicable
Use of the substance/preparation: Determination of nickel Determination of cobalt
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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