World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00188
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Cyclohexanone
Catalog Number: 1403332
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00188
Chemical Name: Cyclohexanone
Chemical Formula: C6H10O
Chemical Family: Ketones
Use of the substance/preparation: Laboratory Reagent
CAS No.: 108-941-
Hazard: Combustible. Causes severe eye irritation. Experimental mutagen.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Cyclohexanone
EEC Number: 2036311
CAS No.: 108-94-1
Percent Range: 100,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 10 R 20/22 R 36
TLV: 25 ppm - skin
PEL: 25 ppm - skin
EU Occupational Exposure Limits: Recommended: 10 ppm (40,8 mg/m3); STEL 20 ppm (81,6 mg/m3), Skin notation
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Peppermint
EU Symbols: Xn - HARMFUL
R PHRASES: R 10: Flammable. R 20/22: Harmful by inhalation and if swallowed. R 36: Irritating to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe irritation
Skin Contact (EC): Causes mild irritation
Skin Absorption (EC): Harmful if absorbed through the skin Effects similar to those of inhalation
Target Organs (SA E): Liver Kidneys
Ingestion (EC): Harmful May cause: central nervous system depression diarrhea dizziness drowsiness headache
loss of coordination nausea vomiting weakness
Target Organs (Ing E): Liver Kidneys
Inhalation: May cause: respiratory tract irritation nausea vomiting diarrhea headache dizziness drowsiness
incoordination central nervous system depression loss of consciousness death
Target Organs (Inh E): Liver Kidneys
Medical Conditions Aggravated: Pre-existing: Kidney conditions Liver conditi ns
o
Chronic Effects: Chronic overexposure may cause liver damage kidney damage
Cancer / Reproductive Toxicity Information:
IARC Group 3: Non-classifiable
Cyclohexanone
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Never give anything by mouth to an
unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Combustible Liquid Vapors can travel to a source of ignition and flash back.
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: Combustible liquid Do not expose to flames. Do not expose to sparks or other ignition
sources. May react violently with: aldehydes strong acids strong bases strong oxidizers strong reducers
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Carbon dioxide Dry chemical. Alcohol foam.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: Containers can build up pressure if exposed to heat. As in any fire, wear self-contained
breathing apparatus pressure-demand and full protective gear. Evacuate area and fight fire from a safe distance.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Remove all combustible material
from spill area. Remove all ignition and spark-creating sources from the spill area. Cover spilled liquid with a
commercially available flammable liquid sorbent such as vapor barrier blanket or activated carbon to avoid evolution of
fumes. Vapors may travel to a source of ignition and flash back. May be ignited by: heat, sparks, or flames. Material will
float on water creating a fire hazard. Dike the material to create a barrier to combustibles.
Clean-up Technique: Eliminate all sources of ignition. Do not breathe the fumes. Cover with an inert material, such as
sand. Use only non-sparking tools. Sweep up material. Incinerate material at an E.P.A. approved hazardous waste facility.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling. Use
with adequate ventilation. Maintain general industrial hygiene practices when using this product.
Storage: Store between 10掳 and 25掳C. Protect from: heat light Keep away from: acids alkalies oxidizers reducers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Use a fume hood to avoid exposure to dust, mist or vapor. Maintain general industrial hygiene
practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Use with adequate ventilation. Protect from: heat light Keep away from: acids/acid fumes alkalies oxidizers
reducers
TLV: 25 ppm - skin
PEL: 25 ppm - skin
EU Occupational Exposure Limits: Recommended: 10 ppm (40,8 mg/m3); STEL 20 ppm (81,6 mg/m3), Skin notation
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Peppermint
pH: Not determined
Vapor Pressure: 136 mm at 100掳C
Vapor Density (air = 1): 3,4
Boiling Point: 155,6掳C (312,1掳F)
Melting Point: Not applicable
Flash Point: 44掳C (111掳F)
Method: Closed cup
Autoignition Temperature: 420掳C (788掳F)
Flammability Limits:
Lower Explosion Limits: 1,1 %
Upper Explosion Limits: 8,1 %
Specific Gravity (water = 1): 0,948
Evaporation Rate (water = 1): Not determined
Volatile Organic Compounds Content: 100 %
Partition Coefficient (n-octanol / water): Not determined
Solubility:
Water: Slightly soluble
Acid: Not determined
Other: Soluble in most organic solvents
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Contact with heat, sparks, open flames or other ignition sources. Exposure to light.
Reactivity / Incompatibility: Incompatible with: acids alkalies oxidizers reducers
Hazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral rat LD50 = 1535 mg/kg; Oral mouse LD50 = 1400 mg/kg; Oral rat LD50 = 1620 mg/kg; Oral rat LD50 =
1840 mg/kg.
LC50: Inhalation rat LC50 = 8000 ppm/4 hrs; Inhalation human TCLo = 75 ppm -nose, eye respiratory irritation.
Dermal Toxicity Data: Skin rabbit LD50 = 948 mg/kg.
Skin and Eye Irritation Data: Skin irritation rabbit: 500 mg = MILD; Eye irritation rabbit: 20 mg = SEVERE; Eye
irritation rabbit: 250 碌g/24 hrs = SEVERE.
Mutation Data: Cytogenetic analysis in human leukocytes @ 100 碌mol/l; Cytogenetic analysis in human lymphocytes
@ 5 碌g/l; Sister chromatid exchange in hamster ovary @ 7500 碌l/l; Mutation in mammalian somatic cells in hamster
ovary @ 7500 碌l/l.
Reproductive Effects Data: Inhalation rat (female) TCLo = 105 mg/m鲁/4 hrs (Fertility: pre-implantation mortality); Oral
mouse (female) TDLo = 11 g/kg (Effects on newborn: growth statistics).
--
Ingredient Toxicological Data: --
Not applicable
IARC Group 3: Non-classifiable
Cyclohexanone
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: Aquatic toxicity: Golden ides LC50 = 536 mg/l/48 hrs; No inhibition of bacteria in
effluent if properly introduced into acclimated biological treatment facility.
Ingredient Ecological Information: --
Not applicable
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Cyclohexanone
--
ICAO Hazard Class: 3
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1915
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Cyclohexanone
--
I.M.O. Hazard Class: 3
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1915
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Cyclohexanone
--
A.D.R Hazard Class: 3
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 1915
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
EEC Number: 2036311
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL
R PHRASES: R 10: Flammable. R 20/22: Harmful by inhalation and if swallowed. R 36: Irritating to eyes.
S PHRASES: S 25: Avoid contact with eyes. S 46: If swallowed, seek medical advice immediately and show this
container or label.
______________________________________
16. OTHER INFORMATION
References: CCINFO MSDS/FTSS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada:
30 June 1993. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Fire
Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Association, 1991. NIOSH
Registry of Toxic Effects of Chemical Substances, 1985-86. Cincinnati: U.S. Department of Health and Human Services,
April, 1987. Patty, Frank A. Industrial Hygiene and Toxicology, 3rd Revised Edition. Volume 2. New York: A Wiley-
Interscience Publication, 1981. Technical Judgment. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed.
New York: Van Nostrand Reinhold Co., 1989. TLV's Threshold Limit Values and Biological Exposure Indices for 1992-
1993. American Conference of Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway, New
Jersey: Merck and Co., Inc., 1989. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp.
2332-2983. 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). IARC Monographs on the Evaluation of the
Carcinogenic Risks to Humans. World Health Organization (Volumes 1-42) Supplement 7. France: 1987. List of
Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of
Dangerous Substances, Amended July 1992. Sixth Annual Report on Carcinogens, 1991. U.S. Department of Health and
Human Services. Rockville, MD: Technical Resources, Inc. 1991. Vendor Information. EU Occupational Exposure
Limits On Line.
R PHRASES: R 10: Flammable. R 20/22: Harmful by inhalation and if swallowed. R 36: Irritating to eyes.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00048
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
_____________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: ZincoVer 庐 5 Zinc Reagent
Catalog Number: 2106669
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00048
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of zinc
CAS No.: Not applicable
Hazard: Toxic.
Date of MSDS Preparation:
Day: 23
Month: 10
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
_____________________________________________________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Potassium Borate
EEC Number: 2155755
CAS No.: 1332770
--
Percent Range: 50,0 - 60,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: 0,01 - 0,1
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Boron Oxide
EEC Number: 2151258
CAS No.: 1303862
--
Percent Range: 15,0 - 25,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 10 mg/m鲁
PEL: 15 mg/m鲁
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Ascorbate
EEC Number: 2051261
CAS No.: 134-03-2
Percent Range: 20,0 - 30,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Potassium Cyanide
EEC Number: 2057923
CAS No.: 151-50-8
Percent Range: 1,0 - 10,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL N - Dangerous for the Environment
Ingredient R phrase(s) (R phrase details given in Heading 16): R 20/21/22 R 32 R 51/53
TLV: 5 mg/m鲁 (skin)
PEL: 5 mg/m鲁 (skin)
EU Occupational Exposure Limits: None found. Cyanides are on the Priority List for OELs.
_____________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Purple
Odor: Not determined
EU Symbols: Xn - HARMFUL N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R 32: Contact with acids
liberates very toxic gas. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Emergency responseto cyanide exposure should be planned and practiced prior to work with cyanides. First
responders should start treatment and get medical attention immediately. Antidote: break an amyl nitrite pearl in cloth
and hold lightly under nose for 15 seconds. Repeat 5 times at 15 second intervals. Transport to hospital immediately.
Note to Physician: Have a cyanide first aid kit available. If patient has not responded to amyl nitrite, inject
intraveneously 10 ml of a 3% solution of sodium nitrite at a rate not greater than 2,5 - 5 ml/min. Follow directly with 50
ml of a 25 % solution of sodium thiosulfate at the same rate by the same route. Keep patient under observation. If signs
of poisoning persist or reappear, repeat nitrite and thiosulfate injections 1 hour later in one-half the original doses.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): Harmful if absorbed through the skin
Target Organs (SA E): Brain
Ingestion (EC): Harmful May cause: confusion gastrointestinal tract irritation irregular heartbeat
Target Organs (Ing E): Brain
Inhalation: Harmful May cause: irritation of nose and throat confusion irregular heartbeat
Target Organs (Inh E): Brain
Medical Conditions Aggravated: Pre-existing: Respiratory conditions Skin conditions
Chronic Effects: Chronic overexposure may cause brain damage
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. an experimental
teratogen.
Toxicologically Synergistic Products: None reported
_____________________________________________________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water for 15 minutes. Remove contaminated clothing. Call
physician immediately.
Ingestion (First Aid): Break an amyl nitrite pearl in cloth and hold lightly under nose for 15 seconds. Repeat every five
minutes. Administer artificial respiration with 100% oxygen. Transport to hospital immediately.
Inhalation: Break an amyl nitrite pearl in cloth and hold lightly under nose for 15 seconds. Repeat 5 times at 15 second
intervals. Transport to hospital immediately.
_____________________________________________________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Combustion generates toxic fumes. Dusts at sufficient concentrations can form explosive
mixtures with air.
Hazardous Combustion Products: Toxic fumes of: cyanide compounds nitrogen oxides. potassium oxides boron
compounds
Fire / Explosion Hazards: High concentrations of dust may form an explosive mixture with air.
Static Discharge: None reported.
Mehanical Impact: None reported
c
Extinguishing Media: Alkali dry chemical. Do NOT use carbon dioxide.
Extinguishing Media NOT To Be Used: Not applicable Do NOT use carbon dioxide.
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Evacuate area and fight fire from a safe distance. Water runoff can cause environmental damage. Dike and collect
water used to fight fire.
_____________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Stop spilled material from being
released to the environment.
Clean-up Technique: Carefully mist spill with bleach until saturated. Scoop up slurry into a large beaker. Oxidize spilled
material with a 50% excess of bleach containing at least 5% sodium hypochlorite. Allow to react for 24 hours in a fume
hood. Flush reacted material to the drain with a large excess of water. Decontaminate area with bleach solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
_____________________________________________________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Protect from: moisture Keep away from: acids
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of zinc
_____________________________________________________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use a fume hood to avoid exposure to dust, mist or vapor.
Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Keep away from: acids/acid fumes Protect from: moisture
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
_____________________________________________________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Purple
Physical State: Solid
Odor: Not determined
pH: of 5% solution = 8,7
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 155掳C 311掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,83
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): Not determined
Solubility:
Water: Soluble
Acid: Generates HCN
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
_____________________________________________________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Heating to decomposition.
Reactivity / Incompatibility: Incompatible with: acids
Hazardous Decomposition: Toxic fumes of: cyanide boron compounds nitrogen oxides potassium oxide Contact with
acids/acid fumes releases toxic cyanide gas.
Hazardous Polymerization: Will not occur.
_____________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral rat LD50 = 383 mg/kg
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Boron Oxide: Oral mouse LD50 = 3163 mg/kg, Potassium Cyanide: Oral human LDLo =
2,857 mg/kg, Oral rat LD50 = 5mg/kg, Potassium Borate: Oral rat LD50 = 3690 mg/kg
This product does NOT contain any IARC listed chemicals.
_____________________________________________________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
_____________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
_____________________________________________________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Environmentally Hazardous Substance, Solid, nos
(Potassium cyanide mixture)
A.D.R Hazard Class: 9
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 30
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316 ALSO NOTE: If the National Competent Authority
declares this product an environmental hazard by Special Provision 909 (IMDG) and Special Provision A97 (IATA) the
classification may be UN3077 or UN3082.
_____________________________________________________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R 32: Contact with acids
liberates very toxic gas. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 28a:
After contact with skin, wash immediately with plenty of water. S 35: This material and its container must be disposed of
in a safe way. S 36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S 45: In case of accident or if
you feel unwell, seek medical advice immediately (show the label where possible).
Ingredients: Potassium Cyanide;
_____________________________________________________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. CCINFO RTECS. Canadian Centre for Occupational Health and
Safety. Hamilton, Ontario Canada: 30 June 1993. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA:
National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection
Association, 1991. In-house information. Technical Judgment. TLV's Threshold Limit Values and Biological Exposure
Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
R PHRASES: R 20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R 32: Contact with acids
liberates very toxic gas. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Use of the substance/preparation: Determination of zinc
Revision Summary: Updates in Section(s) 14,
_____________________________________________________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
|