World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00135
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: FerroVer 庐 Iron Reagent
Catalog Number: 2105769
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00135
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Iron determination
CAS No.: Not applicable
Hazard: May cause allergic reaction. May cause irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Thiosulfate
EEC Number: 2318675
CAS No.: 10102-17-7
Percent Range: 45,0 - 55,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
1,10-Phenanthroline-p-toluenesulfonic Acid Salt
EEC Number: None assigned
CAS No.: 92798-16-8
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Hydrosulfite
EEC Number: 231800
9
CAS No.: 7775146
--
Percent Range: 15,0 - 25,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 7 R 22 R 31
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Citrate
EEC Number: 2006753
CAS No.: 68042
--
Percent Range: 1,0 - 10,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Metabisulfite
EEC Number: 2316730
CAS No.: 7681574
--
Percent Range: 20,0 - 30,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 22
TLV: 5 mg/m3 (ACGIH - TWA)
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White to light yellow crystals
Odor: Sulfur-like
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to
eyes, respiratory system and skin.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): Causes irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: allergic respiratory reaction gastrointestinal tract irritation circulatory disturbances
central nervous system depression Very large doses may cause: abdominal pain diarrhea vomiting depression
Target Organs (Ing E): None Reported
Inhalation: Causes: respiratory tract irritation May cause: allergic respiratory reaction difficult breathing coughing
rapid pulse and respirations blood pressure changes chest pain sweating flushing hives
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Sulfites are strong sensitizers. Inhalation and ingestion may cause allergic respiratory
reactions in asthmatics. Persons with respiratory conditions should take special care when working with products that
contain sulfites.
Chronic Effects: Chronic overexposure may cause allergic respiratory reactions
Cancer / Reproductive Toxicity Information:
An ingredient of this mixture is: IARC Group 3: Non-classifiable
Metabisulfites
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water.
Ingestion (First Aid): Give 1-2 glasses of water. Do not induce vomiting. Call physician immediately.
Inhalation: Give artificial respiration if necessary. Remove to fresh air. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: sulfur oxides. sodium monoxide carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: May react violently with: organic materials aluminum / aluminum compounds strong
oxidizers combustible materials strong acids water
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Carbon dioxide Alcohol foam. Dry chemical.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment. Cover spilled solid material with
sand or other inert material.
Clean-up Technique: Sweep up material. Dilute with a large excess of water. Adjust to a pH between 6 and 9 with an
alkali, such as soda ash or sodium bicarbonate. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Store between 10掳 and 25掳C. Protect from: heat moisture light Keep away from: acids / acid fumes.
combustible materials organic material oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Iron determination
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use general ventilation to minimize exposure to mist, vapor or
dust. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation and / or dust / mist mask
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Use with adequate ventilation. Protect from: heat Keep away from: acids/acid fumes organic materials combustible
material oxidizers water
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White to light yellow crystals
Physical State: Solid
Odor: Sulfur-like
pH: 5% solution = 5,29
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: decomposes at 192掳 C
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,27
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): Not determined
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,106 in/yr
Aluminum: 0,003 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Exposure to light. Excess moisture Extreme temperatures
Reactivity / Incompatibility: Incompatible with: combustible materials organic materials oxidizers aluminum acids
sodium nitrite sodium chlorite
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: sulfur oxides carbon
monoxide carbon dioxide
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Erythema at 3 minutes, 1 hour, 4 hours, 24 hours, 48 hours, 72 hours = 0. Edema at 3
minutes, 1 hour, 4 hours, 24 hours, 48 hours, 72 hours = 0.
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium Hydrosulfite Oral rat LD50 > 500 mg/kg; Sodium Thiosulfate Oral rat LD50 > 8
g/kg; Sodium Citrate Oral rat LD50 > 8 g/kg
An ingredient of this mixture is: IARC Group 3: Non-classifiable
Metabisulfites
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: Sodium Metabisulfite: 120 ppm / 24, 48 & 96 hours / mosquito fish / TLm / fresh
water (converting bisulfite figure to metabisulfite); Sodium Thiosulfate: Aquatic toxicity: 24,000 mg / 1 / 96 hours /
mosquito-fish / TLm / turbid water at 22 掳 - 24掳 C.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS or are placed on the
market in quantities less than 10 kg per year.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to eyes,
respiratory system and skin.
S PHRASES: S 22: Do not breathe dust. S 25: Avoid contact with eyes. S 39: Wear eye / face protection.
______________________________________
16. OTHER INFORMATION
References: CCINFO MSDS/FTSS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada:
30 June 1993. NIOSH Registry of Toxic Effects of Chemical Substances, 1985-86. Cincinnati: U.S. Department of Health
and Human Services, April, 1987. Outside Testing. Vendor Information. Gosselin, R. E. et al. Clinical Toxicology of
Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Sax, N. Irving. Dangerous Properties of
Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. Fire Protection Guide on Hazardous
Materials, 10th Ed. Quincy, MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed.
Quincy, MA: National Fire Protection Association, 1991. Technical Judgment. In-house information. TLV's Threshold
Limit Values and Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial
Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983.
R PHRASES: R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 36/37/38: Irritating to eyes,
respiratory system and skin.
Use of the substance/preparation: Iron determination
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
|