World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00337
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sulfuric Acid 0.1600 卤 0.0008 N
Catalog Nu mber: 1438801
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M00337
Chemical Name: Not applicable.
Chemical Formula: Not applicable.
Chemical Family: Not applicable
Use of the substance/preparation: Alkalinity determination
CAS No.: Not applicable.
Hazard: May cause eye irritation.
Date of MSDS Preparation:
Day: 03
Month: May
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245,
France: +33 -(0)1 -40370404, Italy: +39 -02-66101029, Netherlands: +31 -(0)30 -2748888, Switzerland: +41 -
(0)1 -2515151
_____________________________ ________________________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Demineralized Water
EEC Number: 2317912
CAS No.: 7732 -18-5
Percent Range: >98
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Other components, each
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: 0,01 - 0,1
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occu pational Exposure Limits: Not established
Sulfuric Acid
EEC Number: 2316395
CAS No.: 7664 -93-9
Percent Range: 0,1 - 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given i n Heading 16): Not applicable
TLV: 1 mg/m鲁 (TWA); 3 mg/m鲁 (STEL)
PEL: 1 mg/m鲁
0,1 mg/m 3
EU Occupational Exposure Limits:
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: None
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): None reported
Skin Contact (EC): No effects a re anticipated
Skin Absorption (EC): None Reported
Target Organs (SA E): Not applicable
Ingestion (EC): Practically non -toxic
Target Organs (Ing E): None Reported
Inhalation: No data reported.
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: None reported
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
An ingredient of this mixture is: IARC Group 1: Recognized Carcinogen
Sulfuric Acid - The IARC evaluation was based o n exposure to the mist or vapor of concentrated sulfuric
acid generated during chemical processes.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water. Call phys ician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: None required.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: This product will not burn or explode.
Static Discharge: None reported.
Mechanical Impact: None reported
Ex tinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full
protective gear .
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond
to a spil l involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non -reactive sorbent material. Stop spilled material from
being released to the environment.
Clean -up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoop
up slurry into a large beaker. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium
bicarbonate. Dispose of material in an E.P.A. approved hazard ous waste facility. Decontaminate the area of
the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean -up. If conditions warrant, increase the size
of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes Wash thoroughly after handling. Maintain general industrial hygiene
practices when using this product.
Storage: Store between 10掳 and 25掳C.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Alkalinity determination
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Contro ls: Have an eyewash station nearby. Maintain general industrial hygiene practices when
using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes Wash thoroughly after handling. Use with adequate
ventilation. Protect from: heat
TLV: Not established.
PEL: Not established.
EU Occupa tional Exposure Limits: Not established
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: None
pH: 1,1
Vapor Pressu re: Not determined.
Vapor Density (air = 1): Not determined.
Boiling Point: ~ 100掳 C (~ 212掳 F)
Melting Point: Not determined.
Flash Point: Not applicable.
Method: Not applicable
Autoignition Temperature: Not applicable.
Flammability Limits:
Lower Explosion Limits: Not applicable.
Upper Explosion Limits: Not applicable.
Specific Gravity (water = 1): 0,990
Evaporation Rate (water = 1): 0,56
Volatile Organic Compounds Content: Not applicable.
Partition Coefficient (n -octanol / water): Not applicable.
Solubility:
Water: Miscible.
Acid: Miscible.
Other: Not determined.
Metal Corrosivity:
Steel: 0,027 in/yr (0,689 mm/yr)
Aluminum: 0,124 in/yr (3,150 mm/yr)
_____________________________________________________________________ ________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures Evaporation
Reactivity / Incompatibility: Incompatible with: caustics
Hazardous Decomposition: Non e reported
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported.
LC50: None reported.
Dermal Toxicity Data: None reported.
Skin and Eye Irritation Data: None reported.
Mutation Data: None reported.
Reproductive Effects Data: None reported.
--
Ingredient Toxicological Data: Sulfuric Acid: Oral rat LD = 2140 mg/kg; Inhalation r at LC 50 = 347 ppm/1
50
hr.
An ingredient of this mixture is: IARC Group 1: Recognized Carcinogen
Sulfuric Acid - The IARC evaluation was based on exposure to the mist or vapor of concentrated sulfuric acid
generated during chemical processes.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: No specific ecological information available for this product.
Ingredient Ecological Information: Sulfuric Acid: The 48 -Hour TLm in flounder is 100 -300 ppm.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be supersed ed by
more stringent state or local requirements. Please consult your local environmental regulators for more
information. In Europe: Chemical and analysis solutions must be disposed of in compliance with the
respective national regulations. Product pa ckaging must be disposed of in compliance with the country -specific
regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit Hazard Class: 9 UN Number 3316
_____________________________________________________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable.
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
___________________________________________ __________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). CCINFO RTECS. Canadian Centre
for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Fire Protectio n Guide on
Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Fire Protection Guide on Hazardous
Materials, 10th Ed. Quincy, MA: National Fire Protection Association, 1991. IARC Monographs on the
Evaluation of the Carcinogenic Risks to Humans. World Health Organization (Volumes 1 -42) Supplement 7.
France: 1987. List of Dangerous Substances Classified in Annex I of the EEC Directive (67/548) -
Classification, Packaging and Labeling of Dangerous Substances, Amended July 1992. Sixth A nnual Report
on Carcinogens, 1991. U.S. Department of Health and Human Services. Rockville, MD: Technical
Resources, Inc. 1991. Technical Judgment. TLV's Threshold Limit Values and Biological Exposure Indices
for 1992 -1993. American Conference of Go vernmental Industrial Hygienists, 1992. Verschueren, Karel.
Handbook of Environmental Data on Organic Chemicals. New York: Van Nostrand Reinhold Co., 1977.
R PHRASES: Not applicable
Use of the substance/preparation: Alkalinity determination
Revision Summary: Updates in Section(s) 15,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual
site safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DAT A CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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