World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00007
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
_____________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sulfamic Acid
Catalog Number: 105599
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00007
Chemical Name: Sulfamic Acid
Chemical Formula: H3NO3S
Chemical Family: Inorganic Acid
Use of the substance/preparation: Laboratory Reagent
CAS No.: 5329-14-6
Hazard: Causes eye burns.
Date of MSDS Preparation:
Day: 09
Month: July
Year: 2007
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245,
France: +33-(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-
(0)1-2515151
_____________________________________________________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sulfamic Acid
EEC Number: 2262188
CAS No.: 5329-14-6
Percent Range: > 99,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 36/38
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
_____________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White crystals
Odor: None
EU Symbols: Xi - IRRITATING
R PHRASES: R 36/38: Irritating to eyes and skin. R 52/53: Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe irritation
Skin Contact (EC): Causes severe irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: irritation of the mouth and esophagus gastrointestinal tract irritation
Target Organs (Ing E): None Reported
Inhalation: May cause: irritation of nose and throat
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
IARC Listed: No
Additional Cancer / Reproductive Toxicity Information: Not applicable
Toxicologically Synergistic Products: None reported
_____________________________________________________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Call physician immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately.
Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air.
_____________________________________________________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, irritating and highly toxic gases may be generated by thermal
decomposition.
Hazardous Combustion Products: Toxic fumes of: ammonia nitrogen oxides. sulfur oxides.
Fire / Explosion Hazards: May react violently with: chlorine / chlorine compounds metal nitrates metal
nitrites nitric acid
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Water.
Extinguishing Media NOT To Be Used: Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full
protective gear.
_____________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond
to a spill involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment. Cover spilled solid
material with sand or other inert material.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH
between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain
with a large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency
response plan) when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of
the evacuation.
_____________________________________________________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Maintain general industrial hygiene practices
when using this product.
Storage: Store away from: oxidizers alkalies chlorine/chlorinated metals Protect from: heat moisture
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
_____________________________________________________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when
using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after
handling. Keep away from: alkalies metals Protect from: heat moisture
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
_____________________________________________________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White crystals
Physical State: Solid
Odor: None
pH: 1% soln = 1,18
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: Product decomposes at 205 掳C; 401 掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,15
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): None reported
Solubility:
Water: 1:2 ratio @ 80 掳 C (176 掳F)
Acid: Soluble
Other: Slightly soluble in alcohol, methanol.
Metal Corrosivity:
Steel: 0,814 in/yr
Aluminum: 0,212 in/yr
_____________________________________________________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heating to decomposition. Excess moisture
Reactivity / Incompatibility: May react violently in contact with: chlorates metal nitrates metal nitrites
nitric acid Incompatible with: alkalies oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: ammonia
nitrogen oxides sulfur oxides
Hazardous Polymerization: Will not occur.
_____________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral rat LD50 = 3160 mg/kg.
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Skin Human 4%/5 days intermittent MILD, Skin rabbit 500 mg/24H
SEVERE, Eye rabbit 20mg MODERATE, Eye rabbit 250碌g/24H SEVERE.
Mutation Data: None Reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: --
Not applicable
IARC Listed: No
_____________________________________________________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
Not applicable
_____________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by
more stringent state or local requirements. Please consult your local environmental regulators for more
information. In Europe: Chemical and analysis solutions must be disposed of in compliance with the
respective national regulations. Product packaging must be disposed of in compliance with the country-specific
regulations or must be passed to a packaging return system.
_____________________________________________________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Sulphamic Acid
--
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN2967
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Sulphamic Acid
--
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN2967
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Sulphamic Acid
--
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 2967
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit Hazard Class: 9 UN Number 3316
_____________________________________________________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
EEC Number: 2262188
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASES: R 36/38: Irritating to eyes and skin. R 52/53: Harmful to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. S 28a: After contact with skin, wash immediately with plenty of water. S 61: Avoid release to the
environment. Refer to special instructions/Safety data sheets.
_____________________________________________________________________________
16. OTHER INFORMATION
References: Vendor Information. NIOSH Registry of Toxic Effects of Chemical Substances, 1985-86.
Cincinnati: U.S. Department of Health and Human Services, April, 1987. Gosselin, R. E. et al. Clinical
Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Fire Protection
Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Fire Protection Guide on
Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Association, 1991. Outside Testing.
Technical Judgment. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Sax, N.
Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989.
Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's
Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992.
R PHRASES: R 36/38: Irritating to eyes and skin. R 52/53: Harmful to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_____________________________________________________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual
site safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2007
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00011
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sulfite 1 Reagent
Catalog Number: 220399
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00011
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Sulfite determination
CAS No.: Not applicable
Hazard: Causes irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Potassium Iodide
EEC Number: 2316594
CAS No.: 7681110
--
Percent Range: >95,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Potassium Carbonate
EEC Number: 2095293
CAS No.: 584-08-7
Percent Range: < 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Starch
EEC Number: 2326864
CAS No.: 9005849
--
Percent Range: < 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 10 mg/m3 total dust
PEL: 15 mg/m3 total dust
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White to tan powder or crystals
Odor: None
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: abdominal pain May cause iodism, which symptoms include skin rash, conjunctivitis,
runny nose, sneezing, bronchitis, headache, fever and irritation of mucous membranes.
Target Organs (Ing E): None Reported
Inhalation: May cause: respiratory tract irritation
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Skin conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Does not burn, but may melt in a fire, releasing toxic fumes.
Hazardous Combustion Products: Toxic fumes of: potassium oxides iodine iodine compounds
Fire / Explosion Hazards: May react violently with: bromine trifluoride
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Carbon dioxide Alcohol foam.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Flush the spilled material to
the drain with a large excess of water. Decontaminate the area of the spill with a weak acid solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the
evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Protect from: moisture Keep container tightly closed when not in use.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Sulfite determination
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Protect
from: moisture
TLV: Not applicable
PEL: Not applicable
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White to tan powder or crystals
Physical State: Solid
Odor: None
pH: 5% soln = 9,4
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: Decomposes at 130掳C (266掳F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,97
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,007 in/yr
Aluminum: 0,002 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Exposure to air. Heating to decomposition.
Reactivity / Incompatibility: Incompatible with: alkaloidal salts metalic salts bromine trifluoride chlorine trifluoride
Hazardous Decomposition: Toxic fumes of: potassium oxide iodine iodine compounds
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Potassium Iodide: Oral mouse LDLo = 1862 mg/kg; Potassium Carbonate: Oral rat LD50 =
1870 mg/kg
No toxicological data available for the ingredients of this product.
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. In-house
information. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989.
R PHRASES: Not applicable
Use of the substance/preparation: Sulfite determination
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00371
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
_____________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sodium Thiosulfate Standard Solution, Stabilized, 0,00246 N
Catalog Number: 2408532
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00371
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Titrant solution
CAS No.: Not applicable
Hazard: May cause irritation.
Date of MSDS Preparation:
Day: 29
Month: May
Year: 2007
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245,
France: +33-(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-
(0)1-2515151
_____________________________________________________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Propylene Glycol
EEC Number: 2003380
CAS No.: 57-55-6
Percent Range: 20,0 - 30,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Demineralized Water
EEC Number: 2317912
CAS No.: 7732-18-5
Percent Range: 70,0 - 80,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sodium Thiosulfate
EEC Number: 2318675
CAS No.: 10102-17-7
Percent Range: < 1,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Sulfate
EEC Number: 2318209
CAS No.: 7757-82-6
Percent Range: 1,0 - 5,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
_____________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Sweet
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): Very large doses may cause: central nervous system depression kidney damage rapid
pulse and respirations
Target Organs (Ing E): None Reported
Inhalation: No effects anticipated
Target Organs (Inh E): Not applicable
Medical Conditions Aggravated: None reported
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
_____________________________________________________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
_____________________________________________________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combustion Products: Toxic fumes of: sodium oxides carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full
protective gear.
_____________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond
to a spill involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non-reactive sorbent material. Stop spilled material from
being released to the environment.
Clean-up Technique: Absorb spilled liquid with non-reactive sorbent material. Sweep up material. Place
material in a plastic bag. Mark bag 'Non-hazardous trash', and dispose of as normal refuse. Decontaminate the
area of the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size
of the evacuation.
_____________________________________________________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Protect from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Titrant solution
_____________________________________________________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when
using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: mist/vapor Wash thoroughly after
handling.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
_____________________________________________________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Sweet
pH: 9,9
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: 99掳C (210掳F)
Melting Point: -5掳C (23掳F)
Flash Point: > 100掳C (212掳F)
Method: Open cup
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not determined
Upper Explosion Limits: Not determined
Specific Gravity (water = 1): 1,05
Evaporation Rate (water = 1): 0,91
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,006 in/yr
Aluminum: 0,003 in/yr
_____________________________________________________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heat Evaporation
Reactivity / Incompatibility: Incompatible with: oxidizers
Hazardous Decomposition: Toxic fumes of: sodium oxides carbon monoxide carbon dioxide
Hazardous Polymerization: Will not occur.
_____________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Propylene Glycol: Oral rat LD50 = 20 g/kg, Sodium Sulfate: Oral mouse
LD50 = 5989 mg/kg, Sodium Thiosulfate: Oral rat LD50 > 8 g/kg
This product does NOT contain any IARC listed chemicals.
_____________________________________________________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
_____________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by
more stringent state or local requirements. Please consult your local environmental regulators for more
information. In Europe: Chemical and analysis solutions must be disposed of in compliance with the
respective national regulations. Product packaging must be disposed of in compliance with the country-specific
regulations or must be passed to a packaging return system.
_____________________________________________________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit Hazard Class: 9 UN Number 3316
_____________________________________________________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
_____________________________________________________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register,
Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological
Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
Technical Judgment. In-house information. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy,
MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National
Fire Protection Association, 1991.
R PHRASES: Not applicable
Use of the substance/preparation: Titrant solution
Revision Summary: Updates in Section(s) 14,
_____________________________________________________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual
site safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2007
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