World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00444
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: DEHA 2 Reagent
Catalog Number: 2168042
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M00444
Chemical Name: Not applicable.
Chemical Formula: Not applicable.
Chemical Family: Not applicable
Use of the substance/preparation: Determination of N,N -diethylhydroxylamine
CAS No.: Not applicable.
Hazard: Causes burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -02
-66101029, Netherlands: +31 -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Ferric Nitrate
EEC Number: 2338995
CAS No.: 7782 -8-61
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 1 mg/m鲁 (as Fe)
PEL: 1 mg/m鲁 (as Fe)
Limits: 3 mg/m 3 , Inhalable dust
EU Occupational Exposure
Nitric Acid
EEC Number: 2317142
CAS No.: 7697 -2-37
Percent Range: 5,0 - 15,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 1 6): R 34
TLV: 2 ppm
PEL: 2 ppm
3
EU Occupational Exposure Limits: 2 ppm (5,2 mg/m )
Demineralized Water
EEC Number: 2317912
CAS No.: 7732 -5
-18
Percent Range: 85,0 - 95,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not appl icable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless
Odor: None
EU Symbols: C - CORROSIVE
R PHRASES: R 34: Causes burns.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes burns
Skin Contact (EC): Causes burns
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Causes: burns Iron poisoning is indicated by pink urine discoloration. Very large doses may cause:
abdominal cramps black stool diarrhea gastrointest inal tract irritation vomiting liver damage coma
Target Organs (Ing E): Liver
Inhalation: Causes: burns May cause: bronchitis pneumonitis teeth erosion
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre -existing: Eye conditions Kidney conditions Liver conditions Respiratory
conditions Skin conditions
Chronic Effects: Chronic overexposure may cause adverse effects to the blood erosion of the teeth
Cancer / Reproductive Toxicity Informati on:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
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4. FIRST AID M EASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1 -2 glasses of water. Never give anything by mouth to an
unconscious person. Call physician immediately.
Inhalation: Remove to fresh air.
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5. FIRE FIGHTING MEASURES
Flammable Prperties:
o Not Flammable, but reacts with most metals to form flammable hydrogen gas. Strong oxidizer.
Contact with combustible materials may cause a fire.
Hazardous Combustion Products: Toxic fumes of: nitrogen oxides.
Fire / Explosion Hazards: Contact with metals gives off hydrogen gas which is flammable May react violently with:
combustible materials
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Water.
Extinguishing Media NOT To Be Used: N ot applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full protective
gear. Evacuate area and fight fire from a safe distance.
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6. ACCIDENTAL RELEA SE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non -reactive sorbent material. Stop spilled material from being
released to the environment.
Clean -up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoop up slurry into
a large beaker. Dilute with a large excess of water. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or
sodium bicarbonate. Flush reacted material to the drain with a large excess of water. Decontaminate the area of the s pill
with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Store in a cool, dry place. Keep away from: combustible materials metals
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of N,N -diethylhydroxylamine
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8. EXPO SURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Use a fume hood to avoid
exposure to dust, mist or vapor.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
han dling.
TLV: Not established.
PEL: Not established.
EU Occupational Exposure Limits: Not established
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless
Physical State: Liquid
Odor: None
pH: < 0,5
Vapor Pressure: Not determined.
Vapor Density (air = 1): Not determined.
Boiling Point: ~ 100掳C (~212掳F)
Melting Point: Not determined.
Flash Point: Not applicable.
Method: Not applicable
Autoignition Temperature: Not applicable.
Flammability Limits:
Lower Explosion Limits: Not applicable.
Upper Explosion Limits: Not applicable.
Specific Gravity (water = 1): 1,062
Evaporation Rate (water = 1): Not determined.
Volatile Organic Compounds Content: None.
Partition Coefficie nt (n -octanol / water): Not applicable.
Solubility:
Water: Miscible.
Acid: Miscible.
Other: Not determined.
Metal Corrosivity:
Steel: 52,2 in/yr (1325,9 mm/yr)
Aluminum: 0,12 in/yr (3,048 mm/yr)
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10. S TABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture
Reactivity / Incompatibility: May react violently in contact with: combustible materials organic materials reducers
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: hydrogen nitrate nitrogen
oxides
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported.
LC50: None reported.
Dermal Toxicity Data: None reported.
Skin and Eye Irritation Data: None reported.
Mutation Data: None reported.
Reproductive Effects Data: None reported.
--
Ingredient Toxicolog ical Data: Nitric Acid: Oral rat LD = 430 mg/kg; Inhalation rat LC = 625 ppm/4 hours. Ferric
50 50
Nitrate: Oral rat LD 50 = 3250 mg/kg.
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGI CAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(<15% Nitric Acid/<5% Ferric Nitrate Solution)
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN3264
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(<15% Nitric Acid/<5% Ferric Nitrate Solution)
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Nu mber: UN3264
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(<15% Nitric Acid/<5% Ferric Nitrate Solution)
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: 3264
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable.
EEC LABEL COPY:
EU Symbols: C - CORROSIVE
R PHRASES: R 34: Causes burns.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S
36/37/39: Wear suitable protective clothing, gloves and eye/face protecti on. S 45: In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible).
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor) . Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332 -2983. CCINFO RTECS. Canadian Centre for Occupational Health and
Safety. Hamilton, Ontario Canada: 30 June 1993. IARC Monographs on the Evaluation of the Car cinogenic Risks to
Humans. World Health Organization (Volumes 1 -42) Supplement 7. France: 1987. In -house information. List of
Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of
Dangerou s Substances, Amended July 1992. Sixth Annual Report on Carcinogens, 1991. U.S. Department of Health and
Human Services. Rockville, MD: Technical Resources, Inc. 1991. Technical Judgment. TLV's Threshold Limit Values
and Biological Exposure Indices for 1992 -1993. American Conference of Governmental Industrial Hygienists, 1992.
Vendor Information.
R PHRASES: R 34: Causes burns.
Use of the substance/preparation: Determination of N,N -diethylhydroxylamine
Revision Summary: Updates in Secti on(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each use r should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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