World Headquarters
Hach Company
P.O.Box 389 MSDS No: M01203
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Chloride Titrant
Catalog Number: 2349432
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M01203
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substanc e/preparation: Titrant solution
CAS No.: Not applicable
Hazard: Harmful if swallowed Oxidizer. Causes burns.
Date of MSDS Preparation:
Day: 13
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31
- -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
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2. COMPOSITION / INFORMATION ON I NGREDIENTS
Silver Nitrate
EEC Number: 2318539
CAS No.: 7761888
--
Percent Range: 25,0 - 35,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 34
TLV: 0,01 mg/m鲁 (as Ag)
PEL: 0,01 mg/m鲁 as Ag
EU Occupational Exposure Limits: 0,01 mg/m鲁
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: 60,0 - 70,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not appli cable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Isopropanol
EEC Number: 2006617
CAS No.: 67630
--
Percent Range: 1,0- 10,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): R 67
TLV: 400 ppm (500 ppm STEL)
PEL: 400 ppm
200 ppm (500 mg/m 3)
EU Occupational Exposure Limits:
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Alcoholic
EU Symbols: C - CORROSIVE N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 34: Causes burns. R 67: Vapours may cause drowsiness and dizziness. R 50/53: Very toxic to
aquatic organisms, may cause long -term adverse effects in the aquatic environment.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes burns
Skin Cont act (EC): Causes burns
Skin Absorption (EC): Causes a slate -gray to bluish discoloration.
Target Organs (SA E): None Reported
Ingestion (EC): May cause: abdominal pain nausea vomiting diarrhea drowsiness headache incoordination
depression burns of the mouth and esophagus
Target Organs (Ing E): Central nervous system
Inhalation: May cause: respiratory tract irritation drowsinss incoordination headache
e
Target Organs (Inh E): Central nervous system
Medical Conditions Aggravated: Pre -existing: Skin conditions Respiratory conditions Eye conditions
Chronic Effects: Silver compounds may cause gray to black discolor ation of the eyes and skin.
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. an experimental
teratogen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Ca ll physician.
Skin Contact (First Aid): Wash skin with plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
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5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combustion Products: Toxic fumes of: silver oxides carbon monoxide, carbon dioxide.
Fire / Explosio n Hazards: Drying to completion may form explosive products. Strong Oxidizer: Contact with other
material may cause fire.
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surroundi ng fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full protective
gear.
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6. ACCIDENT AL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment. Absorb spilled liquid with non -
reactive sorbent material. Releases of this material may contaminate the environment.
Clean -up Technique: Absorb spilled liquid with non -reactive sorbent material. Sweep up material. Dispose of material
in an E.P.A. approved hazardous waste facility. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate general area (50 foot radius or as direct ed by your facility's emergency response plan)
when: a gallon or more of liquid is spilled. If conditions warrant, increase the size of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with ey es skin Do not breathe mist or vapors. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Protect from: exposure to direct sunlight. Do not allow product to dry out.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Titrant solution
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain adequate ventil ation to keep vapor level below TWA
for chemicals in this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: mist/vapor Wash thoroughly after handling.
Protect from: heat light
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Alcoholic
pH: 4,0
Vapor Pressure: Not available
Vapor Density (air = 1): Not available
Boiling Point: 98掳C; 208掳F
Melting Point: -9掳C; 16掳F
Flash Point: >99掳C; 210掳F
Method: Closed cup
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Spe cific Gravity (water = 1): 1,252
Evaporation Rate (water = 1): 0,66
Volatile Organic Compounds Content: Not available
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Miscible
Other: Not determined
Metal Corrosivity:
Steel: 0,00 in/yr
Aluminum: 0,39 in/yr
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heat Evaporation Exposure to direct sunlight.
Reactivity / Incompatibility: Incompatible with: organic materials oxidizable material combustible materials
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fume s of: silver oxides carbon
monoxide carbon dioxide
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal To xicity Data: Isopropanol: Skin rabbit LD50 = 12800 mg/kg
Skin and Eye Irritation Data: This product is corrosive to skin. (Packing Group III for transportation)(OECD Number
404, Acute Dermal Irritation/Corrosion)
Mutation Data: Silver Nitrate: DNA inhi bition in human lymphocytes @ 76 碌mol/l; Oncogenic transformation in
hamster embryo @ 60 碌mol/l; Isopropanol: Cytogenetic analysis rat inhalation 1030 碌g/m鲁/16W (Intermittent)
Reproductive Effects Data: Isopropanol: Oral rat TDLo = 11340 mg/kg - maternal effects - menstrual cycle changes or
disorders; Oral rat TDLo = 5040 mg/kg - Litter size; Oral rat TDLo = 20160 mg/kg - Pre -implantation mortality
Isopropanol: Inhalation rat TCLo = 3500 ppm/7H - Embryo or fetus death; Inhalation rat TCLo = 10000 ppm/7 H - Pre -
implantation mortality, post -implantation mortality, embryo or fetus death
Ingredient Toxicological Data: Isopropanol: Oral rat LD50 = 5045 mg/kg, Inhalation rat LCLo = 12000 ppm/8H; Silver
Nitrate: Oral rat LD50 = 50 mg/kg
This product do es NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecol ogical data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
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14. TR ANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Corrosive Liquid, N.O.S.
(Silver Nitrate Solution)
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1760
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Corrosive Liquid, N.O.S.
(Silver Nitrate Solution)
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1760
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Corrosive Liquid, N.O.S.
(Silver Nitrate Sol ution)
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: 1760
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
_________________________________ _____
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: C - CORROSIVE N - DANGEROUS FOR THE EN VIRONMENT
R PHRASES: R 34: Causes burns. R 67: Vapours may cause drowsiness and dizziness. R 50/53: Very toxic to aquatic
organisms, may cause long -term adverse effects in the aquatic environment.
S PHRASES: S 26: In case of contact with eyes , rinse immediately with plenty of water and seek medical advice. S 45:
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 60: This
material and / or its container must be disposed of as hazard ous waste.
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332 -2983. TLV's T hreshold Limit Values and Biological Exposure Indices for
1992 -1993. American Conference of Governmental Industrial Hygienists, 1992. CCINFO RTECS. Canadian Centre for
Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Vendor Inf ormation. In -house information.
Technical Judgment.
R PHRASES: R 34: Causes burns. R 67: Vapours may cause drowsiness and dizziness. R 50/53: Very toxic to aquatic
organisms, may cause long -term adverse effects in the aquatic environment.
Use of the substance/preparation: Titrant solution
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - vo lume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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