**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 102-82-9 |Tributylamine | 99 | 203-058-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23/24/25 34 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Causes
burns. Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.Corrosive.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes eye burns. Low vapor concentrations may cause a temporary
visual disturbance known as 'blue haze' or 'halo vision'. Causes
redness and pain. May cause tearing, conjunctivitis and corneal
edema when vapor is absorbed into the tissue of the eye.
Skin:
Harmful if absorbed through the skin. Causes skin burns. Causes
redness and pain. Chronic exposure may result in sensitization. May
cause skin rash (in milder cases), and cold and clammy skin with
cyanosis or pale color.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the
digestive tract. May cause perforation of the digestive tract. May
cause central nervous system effects. May cause systemic effects.
Inhalation:
May cause severe irritation of the upper respiratory tract with
pain, burns, and inflammation. Aspiration may lead to pulmonary
edema. May cause systemic effects. In rare instances, exposure may
cause sensitization, resulting in inflammation of the mucous
membranes and in eczematous eruptions.
Chronic:
Effects may be delayed. Repeated or prolonged exposure may cause CNS
stimulation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure. SPEEDY ACTION IS CRITICAL! Destroy contaminated
shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. Use water spray to keep fire-exposed containers cool.
Water may be ineffective. Material is lighter than water and a fire
may be spread by the use of water. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. May polymerize explosively when involved in a fire. Contact
with metals may evolve flammable hydrogen gas. Containers may
explode when heated. Combustible material; may burn but does not
ignite readily.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Use
spark-proof tools and explosion proof equipment. Do not get in eyes,
on skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 102-82-9:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: amine-like
pH: 11.5
Vapor Pressure: 0.7 mm Hg @ 20 deg C
Viscosity: 1.35 cP @ 25 deg C
Boiling Point: 216-217 deg C
Freezing/Melting Point: -70 deg C
Autoignition Temperature: 245 deg C ( 473.00 deg F)
Flash Point: 71 deg C ( 159.80 deg F)
Explosion Limits, lower: 1.4 vol %
Explosion Limits, upper: 6.0 vol %
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.7780
Molecular Formula: (CH3CH2CH2CH2)3N
Molecular Weight: 185.1957
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 102-82-9: YA0350000
LD50/LC50:
CAS# 102-82-9: Oral, mouse: LD50 = 114 mg/kg; Oral, rabbit: LD50 =
615 mg/kg; Oral, rat: LD50 = 114 mg/kg; Skin, rabbit: LD50 = 250
uL/kg.
Oral, rat: LD50 = 114
Carcinogenicity:
Tributylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TRIBUTYLAMINE
Hazard Class: 6.1
UN Number: 2542
Packing Group: II
IMO
Shipping Name: TRIBUTYLAMINE
Hazard Class: 6.1
UN Number: 2542
Packing Group: II
RID/ADR
Shipping Name: TRIBUTYLAMINE
Hazard Class: 6.1
UN Number: 2542
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 34 Causes burns.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 102-82-9: 2
Canada
CAS# 102-82-9 is listed on Canada's DSL List.
CAS# 102-82-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-82-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/24/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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