**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-27-3 |Hexyl alcohol | >96 | 203-852-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
Causes skin irritation. Not expected to cause an allergic skin
reaction.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation.
Chronic:
Prolonged exposure may produce a narcotic effect.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Flammable liquid and
vapor. Runoff from fire control or dilution water may cause
pollution. Vapors are heavier than air and may travel to a source of
ignition and flash back. Vapors can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Use water spray, alcohol foam, CO2, dry chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Avoid breathing
vapor or mist. Do not get in eyes. Avoid contact with skin and
clothing.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 111-27-3:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colourless
Odor: fruity odor
pH: Not available.
Vapor Pressure: 0.75 mm Hg @ 20 deg C
Viscosity: 5.3mPas @ 20C
Boiling Point: 156 deg C
Freezing/Melting Point: -52 deg C
Autoignition Temperature: 292 deg C ( 557.60 deg F)
Flash Point: 60 deg C ( 140.00 deg F)
Explosion Limits, lower: 1.2%
Explosion Limits, upper: 7.7%
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.8136
Molecular Formula: C6H14O
Molecular Weight: 102.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-27-3: MQ4025000
LD50/LC50:
CAS# 111-27-3: Oral, mouse: LD50 = 1950 mg/kg; Oral, mouse: LD50 =
1950 mg/kg; Oral, rat: LD50 = 720 mg/kg; Oral, rat: LD50 = 710 mg/kg;
Skin, rabbit: LD50 = 3100 uL/kg.
Carcinogenicity:
Hexyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HEXANOLS
Hazard Class: 3
UN Number: 2282
Packing Group: III
IMO
Shipping Name: HEXANOLS
Hazard Class: 3.3
UN Number: 2282
Packing Group: III
RID/ADR
Shipping Name: HEXANOLS
Hazard Class: 3
UN Number: 2282
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-27-3: 1
Canada
CAS# 111-27-3 is listed on Canada's DSL List.
CAS# 111-27-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-27-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/05/1998 Revision #3 Date: 1/04/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
8-Hydroxyjulolidine
| 41175-50-2 |
|
(R)-2-Hydroxybutyl p-tosylate, 98+%
| 103745-07-9 |
|
TETRACHLOROETHYLENE DENSITY STANDARD
| 127-18-4 |
|
Tetrachloroethylene, 98% (GC)
| 127-18-4 |
|
Tetraethylammonium Bromide, 98%
| 71-91-0 |
|
Tetrahydrofuran, P.A., Stabilized with 0.025% BHT
| 109-99-9 |
|
Tetrahydrofuran, anhydrous, 99.9% Packaged under nitrogen. Stabilized
| 109-99-9 |
|
Tetrahydrofuran, 99.5+%, spectrophotometric grade
| 109-99-9 |
|
Unpreserved Tetrahydrofuran
| 109-99-9 |
|
Tetrahydroxy-P-Quinone Monohydrate, 99% (Titr.)
| 319-89-1 |
|
Ethyl L-Lactate,95% (GC)
| 687-47-8 |
|
N,N'-Dicyclohexylcarbodiimide, 99%
| 538-75-0 |
|
Tetramethylammonium hydroxide pentahydrate , 97% (48-52 wt% tma-oh)
| 10424-65-4 |
|
Tetramethylammonium hydroxide, 10% in water
| 75-59-2 |
|
Triphenyl phosphate
| 115-86-6 |
|
Benzamide, 99%
| 55-21-0 |
|
Thiosalicylic Acid, 98%
| 147-93-3 |
|
4-Iodobenzoic acid, 98%
| 619-58-9 |
|
Thiamine Hydrochloride, 98.5-101.5% (on the Anhydrous Substance)
| 67-03-8 |
|
Mercaptoacetic Acid, 98%
| 68-11-1 |
|
Mercaptoacetic acid
| 68-11-1 |
|
P-Anisidine, 99%
| 104-94-9 |
|
Thiourea, 99%
| 62-56-6 |
|
Thiourea, Reagent ACS, 99+% (Titr.)
| 62-56-6 |
|
Sebacoyl Chloride, Tech. 90-95% Active Chlorine
| 111-19-3 |
|
Quinaldine, 97%
| 91-63-4 |
|
Toluene, 99%
| 108-88-3 |
|
Toluene, Scintillation Grade
| 108-88-3 |
|
Tetrapropylammonium Chloride, 94% (Titr.)
| 5810-42-4 |
|
Toluene, Reagent ACS, Spectro Grade, 99.5% (GC)
| 108-88-3 |
|
Toluene, Reagent ACS
| 108-88-3 |
|
Toluene for HPLC
| 108-88-3 |
|
Himic anhydride, 99%
| 826-62-0 |
|
Tributyl Phosphate, 99%
| 126-73-8 |
|
Tributylamine, 99%
| 102-82-9 |
|
4-Picoline, 98%
| 108-89-4 |
|
Trichloroethylene, 99+% (Stabilized)
| 79-01-6 |
|
Titanium Rod 6.35mm Diam. 99.97%
| 7440-32-6 |
|
3-Amino-1H-1,2,4-triazole
| 61-82-5 |
|
Alizarin Complexone Dihydrate, Indicator Grade
| 3952-78-1 |
|
Phenylphosphate, disodium salt dihydrate, 98%
| 3279-54-7 |
|
Toluene-d8, 99+ atom % D
| 2037-26-5 |
|
Toluene-d8, packaged in 0.50 ml ampules, 100.0 atom % D
| 2037-26-5 |
|
Farnesol, mixture of isomers, 96%
| 4602-84-0 |
|
2,4-Dihydroxybenzaldehyde, 98%
| 95-01-2 |
|
tris-(Hydroxymethyl)-aminomethane, 99+%
| 77-86-1 |
|
Tris(hydroxymethyl)aminomethane, reagent acs
| 77-86-1 |
|
Hexyl alcohol
| 111-27-3 |
|
Sodium phosphate, tribasic dodecahydrate, p.a.
| 7601-54-9 |
|
4-Nitro-1,2-Phenylenediamine, 98%
| 99-56-9 |
|
|