**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 115-86-6 |Triphenyl phosphate | 98-100 | 204-112-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: N
Risk Phrases: 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin. May cause an allergic reaction in certain individuals.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
May cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use carbon dioxide or dry chemical. Use agent most appropriate to
extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 115-86-6:
United Kingdom, WEL - TWA: 3 mg/m3 TWA
United Kingdom, WEL - STEL: 6 mg/m3 STEL
United States OSHA: 3 mg/m3 TWA
Belgium - TWA: 3 mg/m3 VLE
France - VME: 3 mg/m3 VME
Germany: 3 mg/m3 TWA (inhalable fraction)
Malaysia: 3 mg/m3 TWA
Netherlands: 3 mg/m3 MAC
Russia: 1 mg/m3 TWA
Spain: 3 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Flakes
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: 1.3 hPa @ 193 C
Viscosity: Not available.
Boiling Point: 245 deg C
Freezing/Melting Point: 49 deg C
Autoignition Temperature: 500 deg C ( 932.00 deg F)
Flash Point: 428 deg F ( 220.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble in water.
Specific Gravity/Density: 1.3
Molecular Formula: C18 H15 O4 P
Molecular Weight: 326.30
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 115-86-6: TC8400000
LD50/LC50:
CAS# 115-86-6: Dermal, guinea pig: LD50 = >4 gm/kg; Oral, mouse:
LD50 = 1320 mg/kg; Oral, rat: LD50 = 3500 mg/kg; Skin, rabbit: LD50 =
>7900 mg/kg.
Carcinogenicity:
Triphenyl phosphate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 0.3 mg/L; 96 Hr.; UnspecifiedFish:
Fathead Minnow: LC50 = 0.87 mg/L; 96 Hr.; Flow-throughFish:
Bluegill/Sunfish: LC50 = 290.0 mg/L; 96 Hr.; Static ConditionWater
flea Daphnia: EC50 = 1.0 mg/L; 48 Hr.; Unspecified
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE
Hazard Class: 9
UN Number: 3077
Packing Group: III
IMO
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE
Hazard Class: 9
UN Number: 3077
Packing Group: III
RID/ADR
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE
Hazard Class: 9
UN Number: 3077
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: N
Risk Phrases:
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 115-86-6: 2
Canada
CAS# 115-86-6 is listed on Canada's DSL List.
CAS# 115-86-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 115-86-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/10/1999 Revision #3 Date: 5/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
8-Hydroxyjulolidine
| 41175-50-2 |
|
(R)-2-Hydroxybutyl p-tosylate, 98+%
| 103745-07-9 |
|
TETRACHLOROETHYLENE DENSITY STANDARD
| 127-18-4 |
|
Tetrachloroethylene, 98% (GC)
| 127-18-4 |
|
Tetraethylammonium Bromide, 98%
| 71-91-0 |
|
Tetrahydrofuran, P.A., Stabilized with 0.025% BHT
| 109-99-9 |
|
Tetrahydrofuran, anhydrous, 99.9% Packaged under nitrogen. Stabilized
| 109-99-9 |
|
Tetrahydrofuran, 99.5+%, spectrophotometric grade
| 109-99-9 |
|
Unpreserved Tetrahydrofuran
| 109-99-9 |
|
Tetrahydroxy-P-Quinone Monohydrate, 99% (Titr.)
| 319-89-1 |
|
Ethyl L-Lactate,95% (GC)
| 687-47-8 |
|
N,N'-Dicyclohexylcarbodiimide, 99%
| 538-75-0 |
|
Tetramethylammonium hydroxide pentahydrate , 97% (48-52 wt% tma-oh)
| 10424-65-4 |
|
Tetramethylammonium hydroxide, 10% in water
| 75-59-2 |
|
Triphenyl phosphate
| 115-86-6 |
|
Benzamide, 99%
| 55-21-0 |
|
Thiosalicylic Acid, 98%
| 147-93-3 |
|
4-Iodobenzoic acid, 98%
| 619-58-9 |
|
Thiamine Hydrochloride, 98.5-101.5% (on the Anhydrous Substance)
| 67-03-8 |
|
Mercaptoacetic Acid, 98%
| 68-11-1 |
|
Mercaptoacetic acid
| 68-11-1 |
|
P-Anisidine, 99%
| 104-94-9 |
|
Thiourea, 99%
| 62-56-6 |
|
Thiourea, Reagent ACS, 99+% (Titr.)
| 62-56-6 |
|
Sebacoyl Chloride, Tech. 90-95% Active Chlorine
| 111-19-3 |
|
Quinaldine, 97%
| 91-63-4 |
|
Toluene, 99%
| 108-88-3 |
|
Toluene, Scintillation Grade
| 108-88-3 |
|
Tetrapropylammonium Chloride, 94% (Titr.)
| 5810-42-4 |
|
Toluene, Reagent ACS, Spectro Grade, 99.5% (GC)
| 108-88-3 |
|
Toluene, Reagent ACS
| 108-88-3 |
|
Toluene for HPLC
| 108-88-3 |
|
Himic anhydride, 99%
| 826-62-0 |
|
Tributyl Phosphate, 99%
| 126-73-8 |
|
Tributylamine, 99%
| 102-82-9 |
|
4-Picoline, 98%
| 108-89-4 |
|
Trichloroethylene, 99+% (Stabilized)
| 79-01-6 |
|
Titanium Rod 6.35mm Diam. 99.97%
| 7440-32-6 |
|
3-Amino-1H-1,2,4-triazole
| 61-82-5 |
|
Alizarin Complexone Dihydrate, Indicator Grade
| 3952-78-1 |
|
Phenylphosphate, disodium salt dihydrate, 98%
| 3279-54-7 |
|
Toluene-d8, 99+ atom % D
| 2037-26-5 |
|
Toluene-d8, packaged in 0.50 ml ampules, 100.0 atom % D
| 2037-26-5 |
|
Farnesol, mixture of isomers, 96%
| 4602-84-0 |
|
2,4-Dihydroxybenzaldehyde, 98%
| 95-01-2 |
|
tris-(Hydroxymethyl)-aminomethane, 99+%
| 77-86-1 |
|
Tris(hydroxymethyl)aminomethane, reagent acs
| 77-86-1 |
|
Hexyl alcohol
| 111-27-3 |
|
Sodium phosphate, tribasic dodecahydrate, p.a.
| 7601-54-9 |
|
4-Nitro-1,2-Phenylenediamine, 98%
| 99-56-9 |
|
|