**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 127-18-4 |TETRACHLOROETHYLENE DENSITY STANDARD | | 204-825-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Exposure may cause irritation and possible burns. May be absorbed
through the skin.
Ingestion:
Aspiration hazard. May cause central nervous system depression,
kidney damage, and liver damage. Symptoms may include: headache,
excitement, fatigue, nausea, vomiting, stupor, and coma. May cause
gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation. May
cause central nervous system effects including vertigo, anxiety,
depression, muscle incoordination, and emotional instability.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause respiratory tract cancer. May cause adverse
nervous system effects including muscle tremors and incoordination.
May cause liver and kidney damage. May cause reproductive and fetal
effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with
plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Flush down
the spill with a large amount of water. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not reuse this
container. Avoid prolonged or repeated contact with skin. Avoid
breathing vapors from heated material. Avoid contact with skin and
eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Keep away from flames and other sources of high temperatures that may
cause material to form vapors.
Storage:
Keep away from heat and flame. Store in a cool, dry place. Keep
containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 127-18-4:
United Kingdom, OES - TWA: 50 ppm TWA; 345 mg/m3 TWA
United Kingdom, OES - STEL: 100 ppm STEL; 689 mg/m3 STEL
United States OSHA: 100 ppm TWA; 200 ppm Ceiling
Belgium - TWA: 25 ppm VLE; 172 mg/m3 VLE
Belgium - STEL: 100 ppm VLE; 695 mg/m3 VLE
France - VME: 50 ppm VME; 335 mg/m3 VME
Germany: 50 ppm TWA; 345 mg/m3 TWA
Germany: Skin absorber
Malaysia: 25 ppm TWA; 170 mg/m3 TWA
Netherlands: 35 ppm MAC; 240 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 25 ppm VLA-ED; 172 mg/m3 VLA-ED
Spain: 100 ppm VLA-EC; 689 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear colourless liquid
Odor: Sweet odor.
pH: Not available.
Vapor Pressure: 15.8 mm Hg
Viscosity: Not available.
Boiling Point: 119 deg C
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.6000g/cm3
Molecular Formula: C2Cl4
Molecular Weight: 165.83
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong bases, metals, liquid oxygen, dinitrogen tetraoxide.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 127-18-4: KX3850000
LD50/LC50:
CAS# 127-18-4: Draize test, rabbit, eye: 162 mg Mild; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 810 mg/24H
Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation,
mouse: LC50 = 5200 ppm/4H; Inhalation, mouse: LC50 = 35000 mg/m3/4H;
Inhalation, mouse: LC50 = 20200 mg/m3/6H; Inhalation, rat: LC50 =
34200 mg/m3/8H; Inhalation, rat: LC50 = 4100 ppm/6H; Oral, mouse:
LD50 = 8100 mg/kg; Oral, mouse: LD50 = 6400 mg/kg; Oral, rat: LD50 =
2629 mg/kg.
Carcinogenicity:
TETRACHLOROETHYLENE DENSITY STANDARD -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 4/1/88
NTP: Suspect carcinogen
IARC: Group 2A carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TETRACHLOROETHYLENE
Hazard Class: 6.1
UN Number: 1897
Packing Group: III
IMO
Shipping Name: TETRACHLOROETHYLENE
Hazard Class: 6.1
UN Number: 1897
Packing Group: III
RID/ADR
Shipping Name: TETRACHLOROETHYLENE
Hazard Class: 6.1
UN Number: 1897
Packing group: III
USA RQ: CAS# 127-18-4: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 127-18-4: 3
Canada
CAS# 127-18-4 is listed on Canada's DSL List.
CAS# 127-18-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 127-18-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/17/1999 Revision #3 Date: 9/20/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
8-Hydroxyjulolidine
| 41175-50-2 |
|
(R)-2-Hydroxybutyl p-tosylate, 98+%
| 103745-07-9 |
|
TETRACHLOROETHYLENE DENSITY STANDARD
| 127-18-4 |
|
Tetrachloroethylene, 98% (GC)
| 127-18-4 |
|
Tetraethylammonium Bromide, 98%
| 71-91-0 |
|
Tetrahydrofuran, P.A., Stabilized with 0.025% BHT
| 109-99-9 |
|
Tetrahydrofuran, anhydrous, 99.9% Packaged under nitrogen. Stabilized
| 109-99-9 |
|
Tetrahydrofuran, 99.5+%, spectrophotometric grade
| 109-99-9 |
|
Unpreserved Tetrahydrofuran
| 109-99-9 |
|
Tetrahydroxy-P-Quinone Monohydrate, 99% (Titr.)
| 319-89-1 |
|
Ethyl L-Lactate,95% (GC)
| 687-47-8 |
|
N,N'-Dicyclohexylcarbodiimide, 99%
| 538-75-0 |
|
Tetramethylammonium hydroxide pentahydrate , 97% (48-52 wt% tma-oh)
| 10424-65-4 |
|
Tetramethylammonium hydroxide, 10% in water
| 75-59-2 |
|
Triphenyl phosphate
| 115-86-6 |
|
Benzamide, 99%
| 55-21-0 |
|
Thiosalicylic Acid, 98%
| 147-93-3 |
|
4-Iodobenzoic acid, 98%
| 619-58-9 |
|
Thiamine Hydrochloride, 98.5-101.5% (on the Anhydrous Substance)
| 67-03-8 |
|
Mercaptoacetic Acid, 98%
| 68-11-1 |
|
Mercaptoacetic acid
| 68-11-1 |
|
P-Anisidine, 99%
| 104-94-9 |
|
Thiourea, 99%
| 62-56-6 |
|
Thiourea, Reagent ACS, 99+% (Titr.)
| 62-56-6 |
|
Sebacoyl Chloride, Tech. 90-95% Active Chlorine
| 111-19-3 |
|
Quinaldine, 97%
| 91-63-4 |
|
Toluene, 99%
| 108-88-3 |
|
Toluene, Scintillation Grade
| 108-88-3 |
|
Tetrapropylammonium Chloride, 94% (Titr.)
| 5810-42-4 |
|
Toluene, Reagent ACS, Spectro Grade, 99.5% (GC)
| 108-88-3 |
|
Toluene, Reagent ACS
| 108-88-3 |
|
Toluene for HPLC
| 108-88-3 |
|
Himic anhydride, 99%
| 826-62-0 |
|
Tributyl Phosphate, 99%
| 126-73-8 |
|
Tributylamine, 99%
| 102-82-9 |
|
4-Picoline, 98%
| 108-89-4 |
|
Trichloroethylene, 99+% (Stabilized)
| 79-01-6 |
|
Titanium Rod 6.35mm Diam. 99.97%
| 7440-32-6 |
|
3-Amino-1H-1,2,4-triazole
| 61-82-5 |
|
Alizarin Complexone Dihydrate, Indicator Grade
| 3952-78-1 |
|
Phenylphosphate, disodium salt dihydrate, 98%
| 3279-54-7 |
|
Toluene-d8, 99+ atom % D
| 2037-26-5 |
|
Toluene-d8, packaged in 0.50 ml ampules, 100.0 atom % D
| 2037-26-5 |
|
Farnesol, mixture of isomers, 96%
| 4602-84-0 |
|
2,4-Dihydroxybenzaldehyde, 98%
| 95-01-2 |
|
tris-(Hydroxymethyl)-aminomethane, 99+%
| 77-86-1 |
|
Tris(hydroxymethyl)aminomethane, reagent acs
| 77-86-1 |
|
Hexyl alcohol
| 111-27-3 |
|
Sodium phosphate, tribasic dodecahydrate, p.a.
| 7601-54-9 |
|
4-Nitro-1,2-Phenylenediamine, 98%
| 99-56-9 |
|
|