**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 61-82-5 |3-Amino-1H-1,2,4-triazole | 95 | 200-521-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 40 48/22 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Limited evidence of a carcinogenic effect. Harmful : danger of
serious damage to health by prolonged exposure if swallowed. Toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.Possible risks of irreversible effects.Dangerous for the
environment.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. Repeated doses may cause skin rashes.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression. May cause
thyroid abnormalities. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
May cause cancer according to animal studies. May cause reproductive
and fetal effects. Prolonged or repeated exposure may cause thyroid
damage. Effects may be delayed. Laboratory experiments have resulted
in mutagenic effects. Animal studies have reported the development
of tumors.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. This material in sufficient quantity and reduced particle
size is capable of creating a dust explosion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Do not breathe dust, vapor, mist, or gas. Keep container
tightly closed. Do not ingest or inhale. Store protected from light.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store in glass containers. Store protected
from light. Store at room temperature.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 61-82-5:
Belgium - TWA: 0.2 mg/m3 VLE
France - VME: 0.06 ppm VME; 0.2 mg/m3 VME
Germany: 0.2 mg/m3 TWA (inhalable fraction)
Malaysia: 0.2 mg/m3 TWA
Netherlands: 0.2 mg/m3 MAC
Spain: 0.2 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white to green or yellow
Odor: odorless
pH: 6.5-7.5 (neutral)
Vapor Pressure: 0.05 mm Hg @ 20C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 149 - 156 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C2H4N4
Molecular Weight: 84.08
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Decomposes on
exposure to light.
Conditions to Avoid:
Incompatible materials, light, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, acid chlorides, aluminum, copper, copper
alloys, iron, acid anhydrides, iron salts.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 61-82-5: XZ3850000
LD50/LC50:
CAS# 61-82-5: Oral, mouse: LD50 = 14700 mg/kg; Oral, rat: LD50 =
1100 mg/kg; Skin, rat: LD50 = >10 gm/kg.
Not available.
Carcinogenicity:
3-Amino-1H-1,2,4-triazole -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 7/1/87
NTP: Suspect carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 100 mg/L; 96 Hr; Static bioassay at
18CFish: Bluegill/Sunfish: LC50 = 100 mg/L; 48 Hr; UnspecifiedWater
flea Daphnia: EC50 = 30 mg/L; 48 Hr; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 180-582 mg/L; 5,15,30 min;
Microtox test at 15CBacteria: Channel catfish: LC50 > 160 mg/L; 96
Hr; Static bioassay at 18CIn natural waters, degradation of amitrole
may be possible by oxidation with photochemically produced peroxy
radicals or by photosensitized photolysis. It is persistent in
hydrosoil and pond water. Direct photolysis, hydrolysis, and
volatilization are not expected to be important processes. At the
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 61-82-5: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 40 Limited evidence of a carcinogenic effect.
R 48/22 Harmful : danger of serious damage to health
by prolonged exposure if swallowed.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 36 Wear suitable protective clothing.
S 37 Wear suitable gloves.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 61-82-5: 2
Canada
CAS# 61-82-5 is listed on Canada's DSL List.
CAS# 61-82-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 61-82-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/03/1999 Revision #5 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
8-Hydroxyjulolidine
| 41175-50-2 |
|
(R)-2-Hydroxybutyl p-tosylate, 98+%
| 103745-07-9 |
|
TETRACHLOROETHYLENE DENSITY STANDARD
| 127-18-4 |
|
Tetrachloroethylene, 98% (GC)
| 127-18-4 |
|
Tetraethylammonium Bromide, 98%
| 71-91-0 |
|
Tetrahydrofuran, P.A., Stabilized with 0.025% BHT
| 109-99-9 |
|
Tetrahydrofuran, anhydrous, 99.9% Packaged under nitrogen. Stabilized
| 109-99-9 |
|
Tetrahydrofuran, 99.5+%, spectrophotometric grade
| 109-99-9 |
|
Unpreserved Tetrahydrofuran
| 109-99-9 |
|
Tetrahydroxy-P-Quinone Monohydrate, 99% (Titr.)
| 319-89-1 |
|
Ethyl L-Lactate,95% (GC)
| 687-47-8 |
|
N,N'-Dicyclohexylcarbodiimide, 99%
| 538-75-0 |
|
Tetramethylammonium hydroxide pentahydrate , 97% (48-52 wt% tma-oh)
| 10424-65-4 |
|
Tetramethylammonium hydroxide, 10% in water
| 75-59-2 |
|
Triphenyl phosphate
| 115-86-6 |
|
Benzamide, 99%
| 55-21-0 |
|
Thiosalicylic Acid, 98%
| 147-93-3 |
|
4-Iodobenzoic acid, 98%
| 619-58-9 |
|
Thiamine Hydrochloride, 98.5-101.5% (on the Anhydrous Substance)
| 67-03-8 |
|
Mercaptoacetic Acid, 98%
| 68-11-1 |
|
Mercaptoacetic acid
| 68-11-1 |
|
P-Anisidine, 99%
| 104-94-9 |
|
Thiourea, 99%
| 62-56-6 |
|
Thiourea, Reagent ACS, 99+% (Titr.)
| 62-56-6 |
|
Sebacoyl Chloride, Tech. 90-95% Active Chlorine
| 111-19-3 |
|
Quinaldine, 97%
| 91-63-4 |
|
Toluene, 99%
| 108-88-3 |
|
Toluene, Scintillation Grade
| 108-88-3 |
|
Tetrapropylammonium Chloride, 94% (Titr.)
| 5810-42-4 |
|
Toluene, Reagent ACS, Spectro Grade, 99.5% (GC)
| 108-88-3 |
|
Toluene, Reagent ACS
| 108-88-3 |
|
Toluene for HPLC
| 108-88-3 |
|
Himic anhydride, 99%
| 826-62-0 |
|
Tributyl Phosphate, 99%
| 126-73-8 |
|
Tributylamine, 99%
| 102-82-9 |
|
4-Picoline, 98%
| 108-89-4 |
|
Trichloroethylene, 99+% (Stabilized)
| 79-01-6 |
|
Titanium Rod 6.35mm Diam. 99.97%
| 7440-32-6 |
|
3-Amino-1H-1,2,4-triazole
| 61-82-5 |
|
Alizarin Complexone Dihydrate, Indicator Grade
| 3952-78-1 |
|
Phenylphosphate, disodium salt dihydrate, 98%
| 3279-54-7 |
|
Toluene-d8, 99+ atom % D
| 2037-26-5 |
|
Toluene-d8, packaged in 0.50 ml ampules, 100.0 atom % D
| 2037-26-5 |
|
Farnesol, mixture of isomers, 96%
| 4602-84-0 |
|
2,4-Dihydroxybenzaldehyde, 98%
| 95-01-2 |
|
tris-(Hydroxymethyl)-aminomethane, 99+%
| 77-86-1 |
|
Tris(hydroxymethyl)aminomethane, reagent acs
| 77-86-1 |
|
Hexyl alcohol
| 111-27-3 |
|
Sodium phosphate, tribasic dodecahydrate, p.a.
| 7601-54-9 |
|
4-Nitro-1,2-Phenylenediamine, 98%
| 99-56-9 |
|
|