**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1070-89-9 |Sodium Bis-(Trimethylsilyl)-Amide | 98+% | 213-983-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 15 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Causes
burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause cardiac disturbances. May cause central nervous
system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause cardiac abnormalities. May cause
systemic effects. Central nervous system effects, which appear to
predominate in acute cases are characterized by abnormal fatigue,
memory difficulties and dizziness.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Contact
with metals may evolve flammable hydrogen gas. Containers may explode
when heated. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Use foam, dry chemical, or carbon dioxide.
Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Do not allow contact with water. Discard
contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Water free area. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 1070-89-9:
United Kingdom, WEL - TWA: (listed as silica, amorphous): 6 mg/m3
(inhalable dust); 2.4 mg/m3 TWA (respirable dust)
United Kingdom, WEL - STEL: (listed as silica, amorphous): 18 mg/
STEL (inhalable dust); 7.2 mg/m3 STEL (respirable dust)
Russia: (listed as silica, amorphous): 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 171.00 - 175.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H18NSi2Na
Molecular Weight: 183.38
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Dust generation, moisture, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Moisture, oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen, silicon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1070-89-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium Bis-(Trimethylsilyl)-Amide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1070-89-9: No information available.
Canada
CAS# 1070-89-9 is listed on Canada's NDSL List.
CAS# 1070-89-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1070-89-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tin, Granular, 0.1-0.8mm, P.A.
| 7440-31-5 |
|
Tin, 97.5%, foil 0.0125 mm thickness, 300 x 300mm
| 7440-31-5 |
|
Tin, 20 Mesh, Reagent ACS (Granular)
| 7440-31-5 |
|
Tin, 30 Mesh, Reagent ACS (Granular)
| 7440-31-5 |
|
Tin (Shot), Reagent ACS, 99.5% (Titr.)
| 7440-31-5 |
|
1-Bromohexadecane, 97%
| 112-82-3 |
|
Anthraquinone, 97%
| 84-65-1 |
|
2-(1-Piperazinyl)Pyrimidine, 98+%
| 0-01-1 |
|
Indocyanine Green, 99% (uv-vis)
| 3599-32-4 |
|
Sodium Carbonate Decahydrate, P.A.
| 6132-02-1 |
|
3-Phenylpropionaldehyde, 90-95%
| 104-53-0 |
|
Cesium Bicarbonate, 99.9%
| 15519-28-5 |
|
Methyl Acetoacetate, 99+%
| 105-45-3 |
|
2-Methoxyethylamine
| 109-85-3 |
|
3-Amino-1-Phenyl-2-Pyrazolin-5-One, 99+%
| 4149-06-8 |
|
Methyl 4-(1-Hydroxyethyl)Benzoate, Tech., 90% (GC)
| 79322-76-2 |
|
2,2,6-Trimethyl-4H-1,3-dioxin-4-one, 90-95% (GC)
| 67-64-1 |
|
P-Toluenesulfonic Acid,Sodium Salt, 99% (TLC)
| 657-84-1 |
|
Hexadecyltrimethylammonium hydroxide titrant (0.5M in water with 10%
| 67-56-1 |
|
P-Methoxycinnamic Acid, 99%, Predominantly Trans
| 830-09-1 |
|
Tetramethylammonium Acetate, 50% Aqueous Solution
| 7732-18-5 |
|
Sulfuryl Chloride, 98.5%
| 7791-25-5 |
|
4-Nitrophenyl Isocyanate, 99% (GC)
| 100-28-7 |
|
Chloromethylated polystyrene: 2% divinylbenzene copolymer beads
| 70024-51-0 |
|
Propionic anhydride, 97%
| 123-62-6 |
|
Propionic anhydride, 99% (gc)
| 123-62-6 |
|
Benzalkonium chloride, alkyl distribution from C8H17 to C16H33
| 7732-18-5 |
|
Cellulose Acetate, Average M.W. 61000
| 9004-35-7 |
|
Cellulose acetate trimellitate
| 52907-01-4 |
|
4,4'-Methylenedianiline
| 101-77-9 |
|
Platinum, powder, 99.99%
| 7440-06-4 |
|
Heptaldehyde, 95%, stabilized with 100 ppm hydroquinone
| 111-71-7 |
|
Methyl Chloroacetate, 98%
| 96-34-4 |
|
Chloroacetone, 96% stabilized with 0.5% CaCO3
| 78-95-5 |
|
4-Methoxy-1-Naphthonitrile
| 5961-55-7 |
|
(+)-2,3-O-Isopropylidene-L-threitol, 99%
| 50622-09-8 |
|
3,3' -Diaminobenzidine tetrahydrochloride, 97%
| 7411-49-6 |
|
9(10H)-Acridone
| 578-95-0 |
|
Polyvinylpyrrolidone K15 (average m.w.10.000)
| 9003-39-8 |
|
Polyvinylpyrrolidone, K30
| 9003-39-8 |
|
Polyvinylpyrrolidone K12
| 9003-39-8 |
|
Polyvinylpyrrolidone
| 9003-39-8 |
|
N,N-Diethyl-m-toluamide, 98%, min. 95% meta-isomer
| 134-62-3 |
|
Sodium Bis-(Trimethylsilyl)-Amide, 98+ %
| 1070-89-9 |
|
Linolenic acid, tech. 90% (remainder lino leic acid)
| 463-40-1 |
|
o-Toluidine, 99%
| 95-53-4 |
|
Polyethyleneglycol 300 Monodecylether (Fractionated, Fraction 5)
| 26183-52-8 |
|
4-Oxo-4-Phenylamino-2-Butenoic Acid
| 37902-58-2 |
|
Cesium Sulfate, 99+%
| 10294-54-9 |
|
Bilirubin, 99% (uv)
| 635-65-4 |
|
|