**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methyl alcohol | 8.5 | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 505-86-2 |Hexadecyltrimethylammonium hydroxide | 15 | 208-022-4 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 76.5 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F C
Risk Phrases: 11 20/22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation and if swallowed. Causes
burns.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the
digestive tract. Causes gastrointestinal tract burns. May cause
perforation of the digestive tract. May cause systemic effects.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid. Get medical aid immediately. Immediately flush skin
with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse. Destroy
contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Wash mouth out with
water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Use spark-proof tools and
explosion proof equipment. Do not breathe dust, vapor, mist, or gas.
Do not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Use only in a chemical fume hood.
Discard contaminated shoes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place. Keep
container closed when not in use. Store in a tightly closed
container. Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 67-56-1:
United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL
United States OSHA: 200 ppm TWA; 260 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE
France - VME: 200 ppm VME; 260 mg/m3 VME
France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE
Germany: 200 ppm TWA; 270 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 260 mg/m3 OEL
Malaysia: 200 ppm TWA; 262 mg/m3 TWA
Netherlands: 200 ppm MAC; 260 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC
CAS# 505-86-2:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: very slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: 11 deg C ( 51.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: CH3(CH2)15N(CH3)3OH
Molecular Weight: 301.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, excess heat.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-56-1: PC1400000
CAS# 505-86-2 unlisted.
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300
mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600
mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 505-86-2.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Methyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Hexadecyltrimethylammonium hydroxide -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3.2 (8)
UN Number: 2924
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3
UN Number: 2924
Packing group: II
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 24 Avoid contact with skin.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67-56-1: 1
CAS# 505-86-2: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 505-86-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 505-86-2 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 505-86-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R 34 Causes burns.
R 39/23/24/25 Toxic : danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed.
MSDS Creation Date: 7/08/1999 Revision #6 Date: 11/23/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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