**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7440-31-5 |TIN | ca 100 | 231-141-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may
cause irritation and/or dermatitis. Low hazard for usual industrial
handling.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Low hazard for usual industrial handling. Ingested
inorganic tin exhibits only moderate toxicity due to poor absorption
and rapid tissue turnover. Ingestion of large amounts may cause
gastrointestinal irritation, nausea, cramps, vomiting and diarrhea.
May interfere with various enzyme systems. Inorganic tin salts may
cause systemic effects on the central nervous system, heart and
liver.
Inhalation:
Dust is irritating to the respiratory tract. Inhalation of fumes may
cause metal fume fever, which is characterized by flu-like symptoms
with metallic taste, fever, chills, cough, weakness, chest pain,
muscle pain and increased white blood cell count. When inhaled as a
dust or fume, may cause benign pneumoconiosis.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
exposure to tin oxide dusts and fumes may result in stannosis (benign
pneumoconiosis).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Get medical aid if irritation develops or persists. Wash clothing
before reuse. Flush skin with plenty of soap and water.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid if irritation or symptoms
occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT use carbon dioxide. If water is the only media available, use
in flooding amounts. Use dry sand, dry chemical, soda ash or lime.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7440-31-5:
United States OSHA: 2 mg/m3 TWA
Belgium - TWA: 2 mg/m3 VLE
Germany: 2 mg/m3 TWA (inhalable fraction)
Malaysia: 2 mg/m3 TWA
Netherlands: 2 mg/m3 MAC
Spain: 2 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: silver white
Odor: none reported
pH: Not applicable.
Vapor Pressure: 1 mm Hg @ 1492 deg
Viscosity: Not applicable.
Boiling Point: 2507 deg C
Freezing/Melting Point: 231.9 deg C
Autoignition Temperature: 806 deg F ( 430.00 deg C)
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: 0.19
Decomposition Temperature: Not applicable.
Solubility in water: Slightly soluble in hot water.
Specific Gravity/Density: 7.31
Molecular Formula: Sn
Molecular Weight: 118.69
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Oxidizes when
exposed to air.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Halogens, nitric acid, sodium peroxide, sulfur, copper nitrate,
hydrochloric acid, tin chloride, potassium peroxide.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, tin/tin oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-31-5: XP7320000
LD50/LC50:
Not available.
Carcinogenicity:
TIN -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7440-31-5: No information available.
Canada
CAS# 7440-31-5 is listed on Canada's DSL List.
CAS# 7440-31-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-31-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/04/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tin, Granular, 0.1-0.8mm, P.A.
| 7440-31-5 |
|
Tin, 97.5%, foil 0.0125 mm thickness, 300 x 300mm
| 7440-31-5 |
|
Tin, 20 Mesh, Reagent ACS (Granular)
| 7440-31-5 |
|
Tin, 30 Mesh, Reagent ACS (Granular)
| 7440-31-5 |
|
Tin (Shot), Reagent ACS, 99.5% (Titr.)
| 7440-31-5 |
|
1-Bromohexadecane, 97%
| 112-82-3 |
|
Anthraquinone, 97%
| 84-65-1 |
|
2-(1-Piperazinyl)Pyrimidine, 98+%
| 0-01-1 |
|
Indocyanine Green, 99% (uv-vis)
| 3599-32-4 |
|
Sodium Carbonate Decahydrate, P.A.
| 6132-02-1 |
|
3-Phenylpropionaldehyde, 90-95%
| 104-53-0 |
|
Cesium Bicarbonate, 99.9%
| 15519-28-5 |
|
Methyl Acetoacetate, 99+%
| 105-45-3 |
|
2-Methoxyethylamine
| 109-85-3 |
|
3-Amino-1-Phenyl-2-Pyrazolin-5-One, 99+%
| 4149-06-8 |
|
Methyl 4-(1-Hydroxyethyl)Benzoate, Tech., 90% (GC)
| 79322-76-2 |
|
2,2,6-Trimethyl-4H-1,3-dioxin-4-one, 90-95% (GC)
| 67-64-1 |
|
P-Toluenesulfonic Acid,Sodium Salt, 99% (TLC)
| 657-84-1 |
|
Hexadecyltrimethylammonium hydroxide titrant (0.5M in water with 10%
| 67-56-1 |
|
P-Methoxycinnamic Acid, 99%, Predominantly Trans
| 830-09-1 |
|
Tetramethylammonium Acetate, 50% Aqueous Solution
| 7732-18-5 |
|
Sulfuryl Chloride, 98.5%
| 7791-25-5 |
|
4-Nitrophenyl Isocyanate, 99% (GC)
| 100-28-7 |
|
Chloromethylated polystyrene: 2% divinylbenzene copolymer beads
| 70024-51-0 |
|
Propionic anhydride, 97%
| 123-62-6 |
|
Propionic anhydride, 99% (gc)
| 123-62-6 |
|
Benzalkonium chloride, alkyl distribution from C8H17 to C16H33
| 7732-18-5 |
|
Cellulose Acetate, Average M.W. 61000
| 9004-35-7 |
|
Cellulose acetate trimellitate
| 52907-01-4 |
|
4,4'-Methylenedianiline
| 101-77-9 |
|
Platinum, powder, 99.99%
| 7440-06-4 |
|
Heptaldehyde, 95%, stabilized with 100 ppm hydroquinone
| 111-71-7 |
|
Methyl Chloroacetate, 98%
| 96-34-4 |
|
Chloroacetone, 96% stabilized with 0.5% CaCO3
| 78-95-5 |
|
4-Methoxy-1-Naphthonitrile
| 5961-55-7 |
|
(+)-2,3-O-Isopropylidene-L-threitol, 99%
| 50622-09-8 |
|
3,3' -Diaminobenzidine tetrahydrochloride, 97%
| 7411-49-6 |
|
9(10H)-Acridone
| 578-95-0 |
|
Polyvinylpyrrolidone K15 (average m.w.10.000)
| 9003-39-8 |
|
Polyvinylpyrrolidone, K30
| 9003-39-8 |
|
Polyvinylpyrrolidone K12
| 9003-39-8 |
|
Polyvinylpyrrolidone
| 9003-39-8 |
|
N,N-Diethyl-m-toluamide, 98%, min. 95% meta-isomer
| 134-62-3 |
|
Sodium Bis-(Trimethylsilyl)-Amide, 98+ %
| 1070-89-9 |
|
Linolenic acid, tech. 90% (remainder lino leic acid)
| 463-40-1 |
|
o-Toluidine, 99%
| 95-53-4 |
|
Polyethyleneglycol 300 Monodecylether (Fractionated, Fraction 5)
| 26183-52-8 |
|
4-Oxo-4-Phenylamino-2-Butenoic Acid
| 37902-58-2 |
|
Cesium Sulfate, 99+%
| 10294-54-9 |
|
Bilirubin, 99% (uv)
| 635-65-4 |
|
|