**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7411-49-6 |3,3'-Diaminobenzidine tetrahydrochlori| 97 | 231-018-9 |
| |de | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 33 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Danger of cumulative effects. Irritating to eyes, respiratory system
and skin.Cancer suspect agent.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
May cause cancer in humans.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation. Wash clothing before reuse.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7411-49-6:
United States OSHA: (Cancer suspect agent - see 29 CFR 1910.1010)
(listed under Benzidine).
France - VME: (listed as benzidine): 0.001 ppm VME; 0.008 mg/m3 V
Germany: (listed as benzidine): 0.001 ppm VME; 0.008 mg/m3 VME
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: gray to purple-brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 300 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density:
Molecular Formula: C12H14N4.4HCl
Molecular Weight: 360.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and
toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7411-49-6: DV8753000
LD50/LC50:
Not available.
Carcinogenicity:
3,3'-Diaminobenzidine tetrahydrochloride -
California: carcinogen, initial date 2/27/87 (listed as Benzidine).
NTP: Known carcinogen (listed as Benzidine).
IARC: Group 1 carcinogen (listed as Benzidine).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 33 Danger of cumulative effects.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7411-49-6: No information available.
Canada
CAS# 7411-49-6 is listed on Canada's DSL List.
CAS# 7411-49-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7411-49-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/09/1998 Revision #3 Date: 7/09/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tin, Granular, 0.1-0.8mm, P.A.
| 7440-31-5 |
|
Tin, 97.5%, foil 0.0125 mm thickness, 300 x 300mm
| 7440-31-5 |
|
Tin, 20 Mesh, Reagent ACS (Granular)
| 7440-31-5 |
|
Tin, 30 Mesh, Reagent ACS (Granular)
| 7440-31-5 |
|
Tin (Shot), Reagent ACS, 99.5% (Titr.)
| 7440-31-5 |
|
1-Bromohexadecane, 97%
| 112-82-3 |
|
Anthraquinone, 97%
| 84-65-1 |
|
2-(1-Piperazinyl)Pyrimidine, 98+%
| 0-01-1 |
|
Indocyanine Green, 99% (uv-vis)
| 3599-32-4 |
|
Sodium Carbonate Decahydrate, P.A.
| 6132-02-1 |
|
3-Phenylpropionaldehyde, 90-95%
| 104-53-0 |
|
Cesium Bicarbonate, 99.9%
| 15519-28-5 |
|
Methyl Acetoacetate, 99+%
| 105-45-3 |
|
2-Methoxyethylamine
| 109-85-3 |
|
3-Amino-1-Phenyl-2-Pyrazolin-5-One, 99+%
| 4149-06-8 |
|
Methyl 4-(1-Hydroxyethyl)Benzoate, Tech., 90% (GC)
| 79322-76-2 |
|
2,2,6-Trimethyl-4H-1,3-dioxin-4-one, 90-95% (GC)
| 67-64-1 |
|
P-Toluenesulfonic Acid,Sodium Salt, 99% (TLC)
| 657-84-1 |
|
Hexadecyltrimethylammonium hydroxide titrant (0.5M in water with 10%
| 67-56-1 |
|
P-Methoxycinnamic Acid, 99%, Predominantly Trans
| 830-09-1 |
|
Tetramethylammonium Acetate, 50% Aqueous Solution
| 7732-18-5 |
|
Sulfuryl Chloride, 98.5%
| 7791-25-5 |
|
4-Nitrophenyl Isocyanate, 99% (GC)
| 100-28-7 |
|
Chloromethylated polystyrene: 2% divinylbenzene copolymer beads
| 70024-51-0 |
|
Propionic anhydride, 97%
| 123-62-6 |
|
Propionic anhydride, 99% (gc)
| 123-62-6 |
|
Benzalkonium chloride, alkyl distribution from C8H17 to C16H33
| 7732-18-5 |
|
Cellulose Acetate, Average M.W. 61000
| 9004-35-7 |
|
Cellulose acetate trimellitate
| 52907-01-4 |
|
4,4'-Methylenedianiline
| 101-77-9 |
|
Platinum, powder, 99.99%
| 7440-06-4 |
|
Heptaldehyde, 95%, stabilized with 100 ppm hydroquinone
| 111-71-7 |
|
Methyl Chloroacetate, 98%
| 96-34-4 |
|
Chloroacetone, 96% stabilized with 0.5% CaCO3
| 78-95-5 |
|
4-Methoxy-1-Naphthonitrile
| 5961-55-7 |
|
(+)-2,3-O-Isopropylidene-L-threitol, 99%
| 50622-09-8 |
|
3,3' -Diaminobenzidine tetrahydrochloride, 97%
| 7411-49-6 |
|
9(10H)-Acridone
| 578-95-0 |
|
Polyvinylpyrrolidone K15 (average m.w.10.000)
| 9003-39-8 |
|
Polyvinylpyrrolidone, K30
| 9003-39-8 |
|
Polyvinylpyrrolidone K12
| 9003-39-8 |
|
Polyvinylpyrrolidone
| 9003-39-8 |
|
N,N-Diethyl-m-toluamide, 98%, min. 95% meta-isomer
| 134-62-3 |
|
Sodium Bis-(Trimethylsilyl)-Amide, 98+ %
| 1070-89-9 |
|
Linolenic acid, tech. 90% (remainder lino leic acid)
| 463-40-1 |
|
o-Toluidine, 99%
| 95-53-4 |
|
Polyethyleneglycol 300 Monodecylether (Fractionated, Fraction 5)
| 26183-52-8 |
|
4-Oxo-4-Phenylamino-2-Butenoic Acid
| 37902-58-2 |
|
Cesium Sulfate, 99+%
| 10294-54-9 |
|
Bilirubin, 99% (uv)
| 635-65-4 |
|
|