**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-70-6 |1-Bromo-3-chloropropane, p.a. | 100 % | 203-697-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to eyes,
respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. Causes redness and pain.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Prolonged or repeated exposure may cause nausea, dizziness, and
headache.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Do
not get on skin or in eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 109-70-6:
Russia: 3 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Sweet, chloroform-like odor.
pH: Not available.
Vapor Pressure: 6.6 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 144 - 145 deg C @ 760.00mm Hg
Freezing/Melting Point: -59 deg C
Autoignition Temperature: Not available.
Flash Point: 113 deg F ( 45.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.5920g/cm3
Molecular Formula: C3H6BrCl
Molecular Weight: 157.44
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents, magnesium, zinc, and aluminum.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide,
hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-70-6: TX4113000
LD50/LC50:
CAS# 109-70-6: Inhalation, rat: LC50 = 5668 mg/m3; Inhalation, rat:
LC50 = 6500 mg/m3/4H; Oral, mouse: LD50 = 1290 mg/kg; Oral, rat:
LD50 = 930 mg/kg.
Carcinogenicity:
1-Bromo-3-chloropropane, p.a. -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
LC50 (24hr) goldfish:75 mg/l
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 1-BROMO-3-CHLOROPROPANE
Hazard Class: 6.1
UN Number: 2688
Packing Group: III
IMO
Shipping Name: 1-BROMO-3-CHLOROPROPANE
Hazard Class: 6.1
UN Number: 2688
Packing Group: III
RID/ADR
Shipping Name: 1-BROMO-3-CHLOROPROPANE
Hazard Class: 6.1
UN Number: 2688
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 109-70-6: 3
Canada
CAS# 109-70-6 is listed on Canada's DSL List.
CAS# 109-70-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-70-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Methyl-2-pyrrolidinone, 99+%, spectrophotometric grade
| 872-50-4 |
|
1-Methyl-2-pyrrolidinone, 99%
| 872-50-4 |
|
Sodium Iodide, 99.999%
| 7681-82-5 |
|
Guanidine Hydrochloride, 99% (Contains 0.2-0.4% SiO2 as Anti-Caking
| 50-01-1 |
|
Guanidine Hydrochloride, 98%
| 50-01-1 |
|
Phenoxy resin, average m.w. 70000
| 26402-79-9 |
|
N,N-Dimethylbenzylamine, 98%
| 103-83-3 |
|
N,N-Dimethylformamide, 99%
| 68-12-2 |
|
2-Methylbutane, 99+%
| 78-78-4 |
|
2-Methylbutane, 99+%, spectrophotometric grade
| 78-78-4 |
|
N,N-Dimethylformamide, P.A.
| 68-12-2 |
|
Polyethyleneglycol 300 Monononylether (Fractionated, Fraction 5)
| 39587-22-9 |
|
Polyethyleneglycol 300 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 300 Monooctylether (Fractionated, Fraction 2)
| 27252-75-1 |
|
6-Ketocholestanol, 99%
| 1175-06-0 |
|
Polyethyleneglycol 300 monooctylether (Fractionated, Fraction 5)
| 27252-75-1 |
|
Dicyandiamide, 99.5%
| 461-58-5 |
|
Nitrazine Yellow, Indicator Grade
| 5423-07-4 |
|
Polyethyleneglycol 400 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 600 Monooctylether
| 27252-75-1 |
|
N,N-Dimethylformamide for HPLC
| 68-12-2 |
|
N,N-Dimethylformamide, Reagent ACS
| 68-12-2 |
|
N,N-Dimethylformamide, Nonaqueous Titration Grade, 99+% (GC)
| 68-12-2 |
|
2-Isonitrosoacetophenone, 99%
| 532-54-7 |
|
N,N-Dimethylformamide, Reagent ACS, Spectro Grade, 99.8% (GC)
| 68-12-2 |
|
N,N-Dimethylformamide, 99+% Spectrophotometric Grade
| 68-12-2 |
|
R(+)-alpha-methylbenzyl isocyanate, 95%
| 33375-06-3 |
|
s-(-)-1-Phenylethylamine, 98% (uv-vis)
| 2627-86-3 |
|
r-(+)-1-Phenylethylamine, 98% (uv-vis)
| 3886-69-9 |
|
1,4-Dichlorobutane, 99+%
| 110-56-5 |
|
(-)-Taddol, 98%, (99% e.e.)
| 93379-48-7 |
|
3-Methyltetrahydrofuran, 99%
| 13423-15-9 |
|
Merrifield's peptide resin, 2% cross- linked, 2-2.5 meq cl/g, 200-400
| 9036-15-1 |
|
Cyclohexanone, 99.8%
| 108-94-1 |
|
1-Bromo-3-chloropropane, p.a.
| 109-70-6 |
|
2-Octenoic acid, 90-95% trans
| 1871-67-6 |
|
Fluorene (Techn), 90% (UV-Vis)
| 86-73-7 |
|
Chrysene, 98%
| 218-01-9 |
|
Aluminum chloride hexahydrate, 99%
| 7784-13-6 |
|
Carmine certified alum lake
| 1390-65-4 |
|
Carmine, high purity biological stain, (alum lake of carminic
| 1390-65-4 |
|
Trichlorovinylsilane, 96%
| 75-94-5 |
|
p-Xylene, 99%
| 106-42-3 |
|
p-Xylene, scintillation grade, 99%
| 106-42-3 |
|
Cyclooctanemethanol, 97%
| 3637-63-6 |
|
m-Xylene, spectro grade
| 108-38-3 |
|
2,3,3-Trichlorotetrahydrofuran, 98%
| 0-00-1 |
|
4-Chloro-1-(2,5-Dimethylphenyl)-1-Butanone
| 71526-84-6 |
|
4-Chloro-1-(2,4-Dimethylphenyl)-1-Butanone
| 74298-65-0 |
|
Fast Green FCF, High Purity Biological Stain
| 2353-45-9 |
|
|