**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-94-5 |Trichlorovinylsilane | 96 | 200-917-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 34 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Causes burns. Harmful by inhalation.Corrosive.
Potential Health Effects
Eye:
Causes severe eye irritation and burns. May cause chemical
conjunctivitis and corneal damage.
Skin:
Contact with liquid is corrosive and causes severe burns and
ulceration. May cause skin discoloration. May be harmful if absorbed
through the skin. Substance is readily absorbed through the skin.
May cause cyanosis of the extremities. May cause skin rash (in
milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause nausea and vomiting. May be harmful if swallowed.
Ingestion of large amounts may cause CNS depression.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Aspiration may
lead to pulmonary edema. Vapors may cause dizziness or suffocation.
May cause burning sensation, coughing, wheezing, laryngitis,
shortness of breath, headache, nausea, and vomiting. Harmful if
inhaled.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. Contact with metals may evolve
flammable hydrogen gas. Water hydrolyzes material liberating acidic
gas which in contact with metal surfaces can generate flammable
and/or explosive hydrogen gas. Runoff from fire control or dilution
water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. DO NOT USE WATER!
Do NOT get water inside containers. Most foams will react with the
material and release corrosive/toxic gases. Use dry powder or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Remove all sources of ignition. Use
a spark-proof tool. Provide ventilation. Do not get water on spilled
substances or inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Keep away from heat, sparks and
flame. Do not get on skin or in eyes. Do not ingest or inhale. Use
with adequate ventilation. Use and store under nitrogen. Use only in
a chemical fume hood. Discard contaminated shoes. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 75-94-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear slight brown
Odor: sharp odor - hydrochloric odor
pH: Not available.
Vapor Pressure: 65.9 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 90 deg C @ 760.00mm Hg
Freezing/Melting Point: -95 deg C
Autoignition Temperature: 270 deg C ( 518.00 deg F)
Flash Point: 9 deg C ( 48.20 deg F)
Explosion Limits, lower: 3.00 vol %
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: reacts
Specific Gravity/Density: 1.2700g/cm3
Molecular Formula: C2H3Cl3Si
Molecular Weight: 161.49
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Reacts violently with water. Unstable if heated. Evolves hydrogen
gas on contact with metals.
Conditions to Avoid:
Incompatible materials, ignition sources, contact with water, metals,
excess heat, strong oxidants, moist air.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, strong acids, strong bases, water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen gas,
silicon dioxide, phosgene gas, chloride fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-94-5: VV6125000
LD50/LC50:
CAS# 75-94-5: Oral, rat: LD50 = 1280 mg/kg; Skin, rabbit: LD50 = 680
uL/kg.
Inhalation, rat: LCLo = 500
Carcinogenicity:
Trichlorovinylsilane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: VINYLTRICHLOROSILANE, INHIBITED
Hazard Class: 3 (8)
UN Number: 1305
Packing Group: I
IMO
Shipping Name: VINYLTRICHLOROSILANE, INHIBITED
Hazard Class: 3.2 (8)
UN Number: 1305
Packing Group: I
RID/ADR
Shipping Name: VINYLTRICHLOROSILANE, INHIBITED
Hazard Class: 3
UN Number: 1305
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 20 Harmful by inhalation.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
WGK (Water Danger/Protection)
CAS# 75-94-5: No information available.
Canada
CAS# 75-94-5 is listed on Canada's NDSL List.
CAS# 75-94-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-94-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/30/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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| 872-50-4 |
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1-Methyl-2-pyrrolidinone, 99%
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Sodium Iodide, 99.999%
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Guanidine Hydrochloride, 99% (Contains 0.2-0.4% SiO2 as Anti-Caking
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Guanidine Hydrochloride, 98%
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Phenoxy resin, average m.w. 70000
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N,N-Dimethylbenzylamine, 98%
| 103-83-3 |
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N,N-Dimethylformamide, 99%
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2-Methylbutane, 99+%
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2-Methylbutane, 99+%, spectrophotometric grade
| 78-78-4 |
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N,N-Dimethylformamide, P.A.
| 68-12-2 |
|
Polyethyleneglycol 300 Monononylether (Fractionated, Fraction 5)
| 39587-22-9 |
|
Polyethyleneglycol 300 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 300 Monooctylether (Fractionated, Fraction 2)
| 27252-75-1 |
|
6-Ketocholestanol, 99%
| 1175-06-0 |
|
Polyethyleneglycol 300 monooctylether (Fractionated, Fraction 5)
| 27252-75-1 |
|
Dicyandiamide, 99.5%
| 461-58-5 |
|
Nitrazine Yellow, Indicator Grade
| 5423-07-4 |
|
Polyethyleneglycol 400 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 600 Monooctylether
| 27252-75-1 |
|
N,N-Dimethylformamide for HPLC
| 68-12-2 |
|
N,N-Dimethylformamide, Reagent ACS
| 68-12-2 |
|
N,N-Dimethylformamide, Nonaqueous Titration Grade, 99+% (GC)
| 68-12-2 |
|
2-Isonitrosoacetophenone, 99%
| 532-54-7 |
|
N,N-Dimethylformamide, Reagent ACS, Spectro Grade, 99.8% (GC)
| 68-12-2 |
|
N,N-Dimethylformamide, 99+% Spectrophotometric Grade
| 68-12-2 |
|
R(+)-alpha-methylbenzyl isocyanate, 95%
| 33375-06-3 |
|
s-(-)-1-Phenylethylamine, 98% (uv-vis)
| 2627-86-3 |
|
r-(+)-1-Phenylethylamine, 98% (uv-vis)
| 3886-69-9 |
|
1,4-Dichlorobutane, 99+%
| 110-56-5 |
|
(-)-Taddol, 98%, (99% e.e.)
| 93379-48-7 |
|
3-Methyltetrahydrofuran, 99%
| 13423-15-9 |
|
Merrifield's peptide resin, 2% cross- linked, 2-2.5 meq cl/g, 200-400
| 9036-15-1 |
|
Cyclohexanone, 99.8%
| 108-94-1 |
|
1-Bromo-3-chloropropane, p.a.
| 109-70-6 |
|
2-Octenoic acid, 90-95% trans
| 1871-67-6 |
|
Fluorene (Techn), 90% (UV-Vis)
| 86-73-7 |
|
Chrysene, 98%
| 218-01-9 |
|
Aluminum chloride hexahydrate, 99%
| 7784-13-6 |
|
Carmine certified alum lake
| 1390-65-4 |
|
Carmine, high purity biological stain, (alum lake of carminic
| 1390-65-4 |
|
Trichlorovinylsilane, 96%
| 75-94-5 |
|
p-Xylene, 99%
| 106-42-3 |
|
p-Xylene, scintillation grade, 99%
| 106-42-3 |
|
Cyclooctanemethanol, 97%
| 3637-63-6 |
|
m-Xylene, spectro grade
| 108-38-3 |
|
2,3,3-Trichlorotetrahydrofuran, 98%
| 0-00-1 |
|
4-Chloro-1-(2,5-Dimethylphenyl)-1-Butanone
| 71526-84-6 |
|
4-Chloro-1-(2,4-Dimethylphenyl)-1-Butanone
| 74298-65-0 |
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Fast Green FCF, High Purity Biological Stain
| 2353-45-9 |
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|