**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 33375-06-3 |R-(+)-alpha-Methylbenzyl isocyanate | 95 | 251-485-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 26 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation. Irritating to eyes, respiratory system and
skin.Moisture sensitive.Lachrymator (substance which increases the
flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities. May
cause sensitization by skin contact.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May be fatal if inhaled. Aspiration may lead to pulmonary edema.
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals. Prolonged or repeated exposure may cause lung
irritation, chest pain, and pulmonary edema.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. In case of fire, use carbon dioxide or dry
chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Remove all sources of ignition. Absorb spill using an absorbent,
non-combustible material such as earth, sand, or vermiculite. Do not
use combustible materials such as sawdust. Use a spark-proof tool.
Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Do not ingest
or inhale. Use and store under nitrogen. Do not allow contact with
water. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.) Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 33375-06-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear, colorless - slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 55.0 - 56.0 deg C @ 2.50mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 65 deg C ( 149.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: decomposes
Specific Gravity/Density: 1.0500g/cm3
Molecular Formula: C9H9NO
Molecular Weight: 147.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
moist air.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, strong bases, alcohols, amines, heat,
moisture, water.
Hazardous Decomposition Products:
Hydrogen chloride, hydrogen cyanide, nitrogen oxides, carbon
monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 33375-06-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
R-(+)-alpha-Methylbenzyl isocyanate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOCYANATES, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2206
Packing Group: II
IMO
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing Group: II
RID/ADR
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26 Very toxic by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 33375-06-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 33375-06-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 33375-06-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Methyl-2-pyrrolidinone, 99+%, spectrophotometric grade
| 872-50-4 |
|
1-Methyl-2-pyrrolidinone, 99%
| 872-50-4 |
|
Sodium Iodide, 99.999%
| 7681-82-5 |
|
Guanidine Hydrochloride, 99% (Contains 0.2-0.4% SiO2 as Anti-Caking
| 50-01-1 |
|
Guanidine Hydrochloride, 98%
| 50-01-1 |
|
Phenoxy resin, average m.w. 70000
| 26402-79-9 |
|
N,N-Dimethylbenzylamine, 98%
| 103-83-3 |
|
N,N-Dimethylformamide, 99%
| 68-12-2 |
|
2-Methylbutane, 99+%
| 78-78-4 |
|
2-Methylbutane, 99+%, spectrophotometric grade
| 78-78-4 |
|
N,N-Dimethylformamide, P.A.
| 68-12-2 |
|
Polyethyleneglycol 300 Monononylether (Fractionated, Fraction 5)
| 39587-22-9 |
|
Polyethyleneglycol 300 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 300 Monooctylether (Fractionated, Fraction 2)
| 27252-75-1 |
|
6-Ketocholestanol, 99%
| 1175-06-0 |
|
Polyethyleneglycol 300 monooctylether (Fractionated, Fraction 5)
| 27252-75-1 |
|
Dicyandiamide, 99.5%
| 461-58-5 |
|
Nitrazine Yellow, Indicator Grade
| 5423-07-4 |
|
Polyethyleneglycol 400 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 600 Monooctylether
| 27252-75-1 |
|
N,N-Dimethylformamide for HPLC
| 68-12-2 |
|
N,N-Dimethylformamide, Reagent ACS
| 68-12-2 |
|
N,N-Dimethylformamide, Nonaqueous Titration Grade, 99+% (GC)
| 68-12-2 |
|
2-Isonitrosoacetophenone, 99%
| 532-54-7 |
|
N,N-Dimethylformamide, Reagent ACS, Spectro Grade, 99.8% (GC)
| 68-12-2 |
|
N,N-Dimethylformamide, 99+% Spectrophotometric Grade
| 68-12-2 |
|
R(+)-alpha-methylbenzyl isocyanate, 95%
| 33375-06-3 |
|
s-(-)-1-Phenylethylamine, 98% (uv-vis)
| 2627-86-3 |
|
r-(+)-1-Phenylethylamine, 98% (uv-vis)
| 3886-69-9 |
|
1,4-Dichlorobutane, 99+%
| 110-56-5 |
|
(-)-Taddol, 98%, (99% e.e.)
| 93379-48-7 |
|
3-Methyltetrahydrofuran, 99%
| 13423-15-9 |
|
Merrifield's peptide resin, 2% cross- linked, 2-2.5 meq cl/g, 200-400
| 9036-15-1 |
|
Cyclohexanone, 99.8%
| 108-94-1 |
|
1-Bromo-3-chloropropane, p.a.
| 109-70-6 |
|
2-Octenoic acid, 90-95% trans
| 1871-67-6 |
|
Fluorene (Techn), 90% (UV-Vis)
| 86-73-7 |
|
Chrysene, 98%
| 218-01-9 |
|
Aluminum chloride hexahydrate, 99%
| 7784-13-6 |
|
Carmine certified alum lake
| 1390-65-4 |
|
Carmine, high purity biological stain, (alum lake of carminic
| 1390-65-4 |
|
Trichlorovinylsilane, 96%
| 75-94-5 |
|
p-Xylene, 99%
| 106-42-3 |
|
p-Xylene, scintillation grade, 99%
| 106-42-3 |
|
Cyclooctanemethanol, 97%
| 3637-63-6 |
|
m-Xylene, spectro grade
| 108-38-3 |
|
2,3,3-Trichlorotetrahydrofuran, 98%
| 0-00-1 |
|
4-Chloro-1-(2,5-Dimethylphenyl)-1-Butanone
| 71526-84-6 |
|
4-Chloro-1-(2,4-Dimethylphenyl)-1-Butanone
| 74298-65-0 |
|
Fast Green FCF, High Purity Biological Stain
| 2353-45-9 |
|
|