**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7784-13-6 |Aluminum chloride hexahydrate | 99 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects. Aluminum may be readily absorbed
from the gastrointestinal tract.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed. Chronic ingestion of aluminum oxide may
produce loss of appetite, hemolysis, renal deposition and bone
marrow damage
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before reuse. Destroy contaminated
shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use
extinguishing media appropriate to the surrounding fire. Substance is
noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from water. Corrosives area. Keep away from strong bases.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: white
Odor: pungent odor
pH: Acidic in solution.
Vapor Pressure: 1 mm Hg @ 100 C
Viscosity: Not available.
Boiling Point: 360 deg F
Freezing/Melting Point: 212 deg F
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 100 C
Solubility in water: 111%
Specific Gravity/Density: 2.398 (water=1)
Molecular Formula: AlCl3.6H2O
Molecular Weight: 241.4209
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, contact with water, excess
heat, alkaline materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, aluminum
oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7784-13-6: BD0530000
LD50/LC50:
CAS# 7784-13-6: Oral, mouse: LD50 = 1990 mg/kg; Oral, rat: LD50 =
3311 mg/kg.
Carcinogenicity:
Aluminum chloride hexahydrate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Dangerous Goods Code:
UN Number:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7784-13-6: 1
United Kingdom Occupational Exposure Limits
CAS# 7784-13-6: OES-United Kingdom, TWA (listed as ** undefined
**): total inhalable dust: 10 mg/m3 TWA; respirable dust: 4 mg/m3
TWA
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7784-13-6 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7784-13-6: OEL-AUSTRALIA:TWA 2 mg(Al)/m3
OEL-BELGIUM:TWA 2 mg(Al)/m3
OEL-DENMARK:TWA 2 mg(Al)/m3
OEL-FRANCE:TWA 2 mg(Al)/m3
OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3
OEL-RUSSIA:TWA 2 mg(Al)/m3
OEL-SWEDEN:TWA 2 mg(Al)/m3
OEL-SWITZERLAND:TWA 2 mg(Al)/m3
OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7784-13-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/08/2001
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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1-Methyl-2-pyrrolidinone, 99+%, spectrophotometric grade
| 872-50-4 |
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1-Methyl-2-pyrrolidinone, 99%
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Sodium Iodide, 99.999%
| 7681-82-5 |
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Guanidine Hydrochloride, 99% (Contains 0.2-0.4% SiO2 as Anti-Caking
| 50-01-1 |
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Guanidine Hydrochloride, 98%
| 50-01-1 |
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Phenoxy resin, average m.w. 70000
| 26402-79-9 |
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N,N-Dimethylbenzylamine, 98%
| 103-83-3 |
|
N,N-Dimethylformamide, 99%
| 68-12-2 |
|
2-Methylbutane, 99+%
| 78-78-4 |
|
2-Methylbutane, 99+%, spectrophotometric grade
| 78-78-4 |
|
N,N-Dimethylformamide, P.A.
| 68-12-2 |
|
Polyethyleneglycol 300 Monononylether (Fractionated, Fraction 5)
| 39587-22-9 |
|
Polyethyleneglycol 300 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 300 Monooctylether (Fractionated, Fraction 2)
| 27252-75-1 |
|
6-Ketocholestanol, 99%
| 1175-06-0 |
|
Polyethyleneglycol 300 monooctylether (Fractionated, Fraction 5)
| 27252-75-1 |
|
Dicyandiamide, 99.5%
| 461-58-5 |
|
Nitrazine Yellow, Indicator Grade
| 5423-07-4 |
|
Polyethyleneglycol 400 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 600 Monooctylether
| 27252-75-1 |
|
N,N-Dimethylformamide for HPLC
| 68-12-2 |
|
N,N-Dimethylformamide, Reagent ACS
| 68-12-2 |
|
N,N-Dimethylformamide, Nonaqueous Titration Grade, 99+% (GC)
| 68-12-2 |
|
2-Isonitrosoacetophenone, 99%
| 532-54-7 |
|
N,N-Dimethylformamide, Reagent ACS, Spectro Grade, 99.8% (GC)
| 68-12-2 |
|
N,N-Dimethylformamide, 99+% Spectrophotometric Grade
| 68-12-2 |
|
R(+)-alpha-methylbenzyl isocyanate, 95%
| 33375-06-3 |
|
s-(-)-1-Phenylethylamine, 98% (uv-vis)
| 2627-86-3 |
|
r-(+)-1-Phenylethylamine, 98% (uv-vis)
| 3886-69-9 |
|
1,4-Dichlorobutane, 99+%
| 110-56-5 |
|
(-)-Taddol, 98%, (99% e.e.)
| 93379-48-7 |
|
3-Methyltetrahydrofuran, 99%
| 13423-15-9 |
|
Merrifield's peptide resin, 2% cross- linked, 2-2.5 meq cl/g, 200-400
| 9036-15-1 |
|
Cyclohexanone, 99.8%
| 108-94-1 |
|
1-Bromo-3-chloropropane, p.a.
| 109-70-6 |
|
2-Octenoic acid, 90-95% trans
| 1871-67-6 |
|
Fluorene (Techn), 90% (UV-Vis)
| 86-73-7 |
|
Chrysene, 98%
| 218-01-9 |
|
Aluminum chloride hexahydrate, 99%
| 7784-13-6 |
|
Carmine certified alum lake
| 1390-65-4 |
|
Carmine, high purity biological stain, (alum lake of carminic
| 1390-65-4 |
|
Trichlorovinylsilane, 96%
| 75-94-5 |
|
p-Xylene, 99%
| 106-42-3 |
|
p-Xylene, scintillation grade, 99%
| 106-42-3 |
|
Cyclooctanemethanol, 97%
| 3637-63-6 |
|
m-Xylene, spectro grade
| 108-38-3 |
|
2,3,3-Trichlorotetrahydrofuran, 98%
| 0-00-1 |
|
4-Chloro-1-(2,5-Dimethylphenyl)-1-Butanone
| 71526-84-6 |
|
4-Chloro-1-(2,4-Dimethylphenyl)-1-Butanone
| 74298-65-0 |
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Fast Green FCF, High Purity Biological Stain
| 2353-45-9 |
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|