**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-56-5 |1,4-Dichlorobutane | 99 | 203-778-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 10
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable.Flammable liquid.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation and possible burns.
Skin:
May cause skin irritation and possible burns.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. May cause respiratory tract
irritation. The toxicological properties of this substance have not
been fully investigated. Vapors may cause dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Use water spray to keep fire-exposed containers cool. Flammable
liquid and vapor. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Vapors may
form an explosive mixture with air. Containers may explode when
heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT use straight
streams of water. For small fires, use dry chemical, carbon dioxide,
water spray or regular foam. Cool containers with flooding
quantities of water until well after fire is out. For large fires,
use water spray, fog or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 110-56-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 5 hPa @ 20 C
Viscosity: 1.46 mPas 20 deg C
Boiling Point: 154 deg C
Freezing/Melting Point: -37 deg C
Autoignition Temperature: 220 deg C ( 428.00 deg F)
Flash Point: 126 deg F ( 52.22 deg C)
Explosion Limits, lower: 1.5 vol %
Explosion Limits, upper: 4.0 vol %
Decomposition Temperature: 120 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: 1.1600g/cm3
Molecular Formula: C4H8Cl2
Molecular Weight: 127.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, temperatures
above 40C.
Incompatibilities with Other Materials:
Oxidizing agents, alkalies.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-56-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,4-Dichlorobutane -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 4.14 mg/L; 96 Hr.; UnspecifiedFish:
Fathead Minnow: LC50 = 5.10 mg/L; 96 Hr.; UnspecifiedWater flea
Daphnia: LC50 = 3.87 mg/L; 48 Hr.; Unspecified
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 110-56-5: 2
Canada
CAS# 110-56-5 is listed on Canada's NDSL List.
CAS# 110-56-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-56-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/03/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Methyl-2-pyrrolidinone, 99+%, spectrophotometric grade
| 872-50-4 |
|
1-Methyl-2-pyrrolidinone, 99%
| 872-50-4 |
|
Sodium Iodide, 99.999%
| 7681-82-5 |
|
Guanidine Hydrochloride, 99% (Contains 0.2-0.4% SiO2 as Anti-Caking
| 50-01-1 |
|
Guanidine Hydrochloride, 98%
| 50-01-1 |
|
Phenoxy resin, average m.w. 70000
| 26402-79-9 |
|
N,N-Dimethylbenzylamine, 98%
| 103-83-3 |
|
N,N-Dimethylformamide, 99%
| 68-12-2 |
|
2-Methylbutane, 99+%
| 78-78-4 |
|
2-Methylbutane, 99+%, spectrophotometric grade
| 78-78-4 |
|
N,N-Dimethylformamide, P.A.
| 68-12-2 |
|
Polyethyleneglycol 300 Monononylether (Fractionated, Fraction 5)
| 39587-22-9 |
|
Polyethyleneglycol 300 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 300 Monooctylether (Fractionated, Fraction 2)
| 27252-75-1 |
|
6-Ketocholestanol, 99%
| 1175-06-0 |
|
Polyethyleneglycol 300 monooctylether (Fractionated, Fraction 5)
| 27252-75-1 |
|
Dicyandiamide, 99.5%
| 461-58-5 |
|
Nitrazine Yellow, Indicator Grade
| 5423-07-4 |
|
Polyethyleneglycol 400 Monooctylether
| 27252-75-1 |
|
Polyethyleneglycol 600 Monooctylether
| 27252-75-1 |
|
N,N-Dimethylformamide for HPLC
| 68-12-2 |
|
N,N-Dimethylformamide, Reagent ACS
| 68-12-2 |
|
N,N-Dimethylformamide, Nonaqueous Titration Grade, 99+% (GC)
| 68-12-2 |
|
2-Isonitrosoacetophenone, 99%
| 532-54-7 |
|
N,N-Dimethylformamide, Reagent ACS, Spectro Grade, 99.8% (GC)
| 68-12-2 |
|
N,N-Dimethylformamide, 99+% Spectrophotometric Grade
| 68-12-2 |
|
R(+)-alpha-methylbenzyl isocyanate, 95%
| 33375-06-3 |
|
s-(-)-1-Phenylethylamine, 98% (uv-vis)
| 2627-86-3 |
|
r-(+)-1-Phenylethylamine, 98% (uv-vis)
| 3886-69-9 |
|
1,4-Dichlorobutane, 99+%
| 110-56-5 |
|
(-)-Taddol, 98%, (99% e.e.)
| 93379-48-7 |
|
3-Methyltetrahydrofuran, 99%
| 13423-15-9 |
|
Merrifield's peptide resin, 2% cross- linked, 2-2.5 meq cl/g, 200-400
| 9036-15-1 |
|
Cyclohexanone, 99.8%
| 108-94-1 |
|
1-Bromo-3-chloropropane, p.a.
| 109-70-6 |
|
2-Octenoic acid, 90-95% trans
| 1871-67-6 |
|
Fluorene (Techn), 90% (UV-Vis)
| 86-73-7 |
|
Chrysene, 98%
| 218-01-9 |
|
Aluminum chloride hexahydrate, 99%
| 7784-13-6 |
|
Carmine certified alum lake
| 1390-65-4 |
|
Carmine, high purity biological stain, (alum lake of carminic
| 1390-65-4 |
|
Trichlorovinylsilane, 96%
| 75-94-5 |
|
p-Xylene, 99%
| 106-42-3 |
|
p-Xylene, scintillation grade, 99%
| 106-42-3 |
|
Cyclooctanemethanol, 97%
| 3637-63-6 |
|
m-Xylene, spectro grade
| 108-38-3 |
|
2,3,3-Trichlorotetrahydrofuran, 98%
| 0-00-1 |
|
4-Chloro-1-(2,5-Dimethylphenyl)-1-Butanone
| 71526-84-6 |
|
4-Chloro-1-(2,4-Dimethylphenyl)-1-Butanone
| 74298-65-0 |
|
Fast Green FCF, High Purity Biological Stain
| 2353-45-9 |
|
|