**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-18-9 |1,2-Bis(dimethylamino)ethane | 100 | 203-744-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 20/22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation and if swallowed. Causes
burns.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause eye injury.
Skin:
May be absorbed through the skin. May cause severe irritation and
possible burns.
Ingestion:
May cause severe digestive tract irritation with abdominal pain,
nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Irritation may lead to
chemical pneumonitis and pulmonary edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Combustion generates toxic fumes. Flammable Liquid. Can release
vapors that form explosive mixtures at temperatures above the
flashpoint.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Do not ingest or inhale. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Use only with adequate ventilation. Keep away
from heat, sparks and flame.
Storage:
Keep away from sources of ignition. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
CAS# 110-18-9:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: amine-like
pH: Alkaline in sol.
Vapor Pressure: 3 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 250 deg F
Freezing/Melting Point: -67 deg F
Autoignition Temperature: Not available.
Flash Point: 63 deg F ( 17.22 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 0.777 (water=1)
Molecular Formula: C6H16N2
Molecular Weight: 116.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-18-9: KV7175000
LD50/LC50:
CAS# 110-18-9: Draize test, rabbit, eye: 750 ug Severe; Inhalation,
rat: LC50 = 1318 ppm/4H; Oral, mouse: LD50 = 630 mg/kg; Oral, rat:
LD50 = 268 mg/kg; Skin, rabbit: LD50 = 5390 mg/kg.
Carcinogenicity:
1,2-Bis(dimethylamino)ethane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 1,2-Di-(dimethylamino)ethane
Hazard Class: 3
UN Number: 2372
Packing Group: II
IMO
Shipping Name: 1,2-DI-(DIMETHYLAMINO)ETHANE
Hazard Class: 3
UN Number: 2372
Packing Group: II
RID/ADR
Shipping Name: 1,2-DI-(DIMETHYLAMINO) ETHANE
Hazard Class: 3
UN Number: 2372
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 110-18-9: 1
Canada
CAS# 110-18-9 is listed on Canada's DSL List.
CAS# 110-18-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-18-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #6 Date: 10/18/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N,N'-Triethylethylenediamine, 99+%
| 105-04-4 |
|
Triethanolamine hydroiodide, 99%
| 7601-53-8 |
|
1-Methyl-5-mercaptotetrazole, sodium salt, dihydrate
| 51138-06-8 |
|
3-Octanone, 99%
| 106-68-3 |
|
4-Nitrochalcone, 99%
| 1222-98-6 |
|
Diphenyl-2-Pyridylmethane, 99+%
| 3678-70-4 |
|
3-Dimethylaminobenzoic Acid (Pract)
| 99-64-9 |
|
Ethyl 5-Nitroindole-2-Carboxylate, 95+%
| 16732-57-3 |
|
Fast red pdc salt
| 80-22-8 |
|
Copper(II) Chloride, Anhydrous, 98%
| 7447-39-4 |
|
4-Dimethylaminobenzoic acid, 98%
| 619-84-1 |
|
N,N,N',N'-Tetramethyl-1,3-propanediamine, 99+%
| 110-95-2 |
|
1-Butan(ol-d), 98+ atom % D
| 71-36-3 |
|
4-Heptanol, 99% (GC)
| 589-55-9 |
|
Thymolphthalein, Reagent ACS, 99% (UV-Vis)
| 125-20-2 |
|
Diphenyliodonium bromide
| 1483-73-4 |
|
Methyl formate-d, 98+ atom % d
| 23731-38-6 |
|
m-Nitrobenzoyl chloride
| 121-90-4 |
|
Acetaldehyde ammonia trimer, 98%
| 75-39-8 |
|
P-Amino-L-Phenylalanine Hydrochloride Hemihydrate, 99%
| 24286-13-3 |
|
3-Bromobenzoic Acid , 99%
| 585-76-2 |
|
N,N-Diethyl-p-phenylenediamine oxalate
| 62637-92-7 |
|
D-Gluconic Acid, Calcium Salt, 99%
| 299-28-5 |
|
Bis-Acrylamide
| 110-26-9 |
|
TEMED
| 110-18-9 |
|
N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride
| 637-01-4 |
|
BDCS Silylation Reagent
| 68-12-2 |
|
Nalidixic Acid
| 389-08-2 |
|
1-Nitroso-2-naphthol, 98%
| 131-91-9 |
|
Samarium, 99.9%, -40 Mesh
| 7440-19-9 |
|
Benzine
| 71-43-2 |
|
7-Nitroindole-2-Carboxylic Acid, 90-95% (HPLC)
| 6960-45-8 |
|
Naphthalene
| 91-20-3 |
|
Diphenylphosphoryl azide, 98%
| 26386-88-9 |
|
9,10-Dihydrophenanthrene, 95%
| 776-35-2 |
|
Ammonium Perrhenate(VII), 99.999%
| 13598-65-7 |
|
Methyl-2-Nitrobenzoate, 99%
| 606-27-9 |
|
Mixture of dichlorodimethylsilane and silicon(iv)chloride (86 and
| 75-78-5 |
|
Beta-Bromophenetole, 98%
| 589-10-6 |
|
Tri-n-butyltin hydride, 97%
| 688-73-3 |
|
Ethylene/propylene/diene terpolymer, high molecular weight
| 25038-36-2 |
|
Tetraethylammonium iodide, 98%
| 68-05-3 |
|
(4-Pyridylmethylamino)-acetaldehyde diethylacetal
| 35822-55-0 |
|
Glutathione, Reduced , 98%
| 70-18-8 |
|
Alloxan, Monohydrate
| 2244-11-3 |
|
Nickel Metal
| 7440-02-0 |
|
2-Acetylfluorene, 98%
| 781-73-7 |
|
Nickel (II) Acetate Tetrahydrate
| 6018-89-9 |
|
Gallium(III) perchlorate hydrate, 99%
| |
|
2-Nitrophenyl isocyanate, 99% (GC)
| 3220-86-3 |
|
|