**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 26386-88-9 |Diphenylphosphoryl azide | 98 | 247-644-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause central nervous system effects.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with
flooding quantities of water until well after fire is out. Use water
spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.) Storage under a nitrogen
blanket has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 26386-88-9:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow to amber
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 157 deg C @ .17mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.270 g/ml
Molecular Formula: C12H10N3O3P
Molecular Weight: 275.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat, heating in a confined space.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of phosphorus, irritating
and toxic fumes and gases, carbon dioxide, phosphine.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 26386-88-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Diphenylphosphoryl azide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Organophosphorus Compound, Liquid, Toxic, N.O.S.
Hazard Class: 6.1
UN Number: 3278
Packing Group: II
IMO
Shipping Name: Organophosphorus Compound, Liquid, Toxic, N.O.S.
Hazard Class: 6.1
UN Number: 3278
Packing Group: II
RID/ADR
Shipping Name: Organophosphorus Compound, Liquid, Toxic, N.O.S.
Hazard Class: 6.1
UN Number: 3278
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 26386-88-9: No information available.
Canada
CAS# 26386-88-9 is listed on Canada's DSL List.
CAS# 26386-88-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 26386-88-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/01/1999 Revision #3 Date: 8/24/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N,N'-Triethylethylenediamine, 99+%
| 105-04-4 |
|
Triethanolamine hydroiodide, 99%
| 7601-53-8 |
|
1-Methyl-5-mercaptotetrazole, sodium salt, dihydrate
| 51138-06-8 |
|
3-Octanone, 99%
| 106-68-3 |
|
4-Nitrochalcone, 99%
| 1222-98-6 |
|
Diphenyl-2-Pyridylmethane, 99+%
| 3678-70-4 |
|
3-Dimethylaminobenzoic Acid (Pract)
| 99-64-9 |
|
Ethyl 5-Nitroindole-2-Carboxylate, 95+%
| 16732-57-3 |
|
Fast red pdc salt
| 80-22-8 |
|
Copper(II) Chloride, Anhydrous, 98%
| 7447-39-4 |
|
4-Dimethylaminobenzoic acid, 98%
| 619-84-1 |
|
N,N,N',N'-Tetramethyl-1,3-propanediamine, 99+%
| 110-95-2 |
|
1-Butan(ol-d), 98+ atom % D
| 71-36-3 |
|
4-Heptanol, 99% (GC)
| 589-55-9 |
|
Thymolphthalein, Reagent ACS, 99% (UV-Vis)
| 125-20-2 |
|
Diphenyliodonium bromide
| 1483-73-4 |
|
Methyl formate-d, 98+ atom % d
| 23731-38-6 |
|
m-Nitrobenzoyl chloride
| 121-90-4 |
|
Acetaldehyde ammonia trimer, 98%
| 75-39-8 |
|
P-Amino-L-Phenylalanine Hydrochloride Hemihydrate, 99%
| 24286-13-3 |
|
3-Bromobenzoic Acid , 99%
| 585-76-2 |
|
N,N-Diethyl-p-phenylenediamine oxalate
| 62637-92-7 |
|
D-Gluconic Acid, Calcium Salt, 99%
| 299-28-5 |
|
Bis-Acrylamide
| 110-26-9 |
|
TEMED
| 110-18-9 |
|
N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride
| 637-01-4 |
|
BDCS Silylation Reagent
| 68-12-2 |
|
Nalidixic Acid
| 389-08-2 |
|
1-Nitroso-2-naphthol, 98%
| 131-91-9 |
|
Samarium, 99.9%, -40 Mesh
| 7440-19-9 |
|
Benzine
| 71-43-2 |
|
7-Nitroindole-2-Carboxylic Acid, 90-95% (HPLC)
| 6960-45-8 |
|
Naphthalene
| 91-20-3 |
|
Diphenylphosphoryl azide, 98%
| 26386-88-9 |
|
9,10-Dihydrophenanthrene, 95%
| 776-35-2 |
|
Ammonium Perrhenate(VII), 99.999%
| 13598-65-7 |
|
Methyl-2-Nitrobenzoate, 99%
| 606-27-9 |
|
Mixture of dichlorodimethylsilane and silicon(iv)chloride (86 and
| 75-78-5 |
|
Beta-Bromophenetole, 98%
| 589-10-6 |
|
Tri-n-butyltin hydride, 97%
| 688-73-3 |
|
Ethylene/propylene/diene terpolymer, high molecular weight
| 25038-36-2 |
|
Tetraethylammonium iodide, 98%
| 68-05-3 |
|
(4-Pyridylmethylamino)-acetaldehyde diethylacetal
| 35822-55-0 |
|
Glutathione, Reduced , 98%
| 70-18-8 |
|
Alloxan, Monohydrate
| 2244-11-3 |
|
Nickel Metal
| 7440-02-0 |
|
2-Acetylfluorene, 98%
| 781-73-7 |
|
Nickel (II) Acetate Tetrahydrate
| 6018-89-9 |
|
Gallium(III) perchlorate hydrate, 99%
| |
|
2-Nitrophenyl isocyanate, 99% (GC)
| 3220-86-3 |
|
|