**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 62637-92-7 |N,N-Diethyl-p-phenylenediamine oxalate| >85 | 263-662-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 36/37/38 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Harmful by
inhalation.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Dust is irritating to the respiratory tract. The toxicological
properties of this substance have not been fully investigated. Can
produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of calcium gluconate to precipitate the oxalate should be
determined by only qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Handle under an inert atmosphere.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 62637-92-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to off-white
Odor: weak odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 159 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 160 deg C
Solubility in water: 3.3% in water.
Specific Gravity/Density: Not available.
Molecular Formula: C22H34N4O4
Molecular Weight: 418.54
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat, prolonged exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 62637-92-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N-Diethyl-p-phenylenediamine oxalate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20 Harmful by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 62637-92-7: No information available.
Canada
CAS# 62637-92-7 is listed on Canada's DSL List.
CAS# 62637-92-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 62637-92-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/23/1998 Revision #6 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N,N'-Triethylethylenediamine, 99+%
| 105-04-4 |
|
Triethanolamine hydroiodide, 99%
| 7601-53-8 |
|
1-Methyl-5-mercaptotetrazole, sodium salt, dihydrate
| 51138-06-8 |
|
3-Octanone, 99%
| 106-68-3 |
|
4-Nitrochalcone, 99%
| 1222-98-6 |
|
Diphenyl-2-Pyridylmethane, 99+%
| 3678-70-4 |
|
3-Dimethylaminobenzoic Acid (Pract)
| 99-64-9 |
|
Ethyl 5-Nitroindole-2-Carboxylate, 95+%
| 16732-57-3 |
|
Fast red pdc salt
| 80-22-8 |
|
Copper(II) Chloride, Anhydrous, 98%
| 7447-39-4 |
|
4-Dimethylaminobenzoic acid, 98%
| 619-84-1 |
|
N,N,N',N'-Tetramethyl-1,3-propanediamine, 99+%
| 110-95-2 |
|
1-Butan(ol-d), 98+ atom % D
| 71-36-3 |
|
4-Heptanol, 99% (GC)
| 589-55-9 |
|
Thymolphthalein, Reagent ACS, 99% (UV-Vis)
| 125-20-2 |
|
Diphenyliodonium bromide
| 1483-73-4 |
|
Methyl formate-d, 98+ atom % d
| 23731-38-6 |
|
m-Nitrobenzoyl chloride
| 121-90-4 |
|
Acetaldehyde ammonia trimer, 98%
| 75-39-8 |
|
P-Amino-L-Phenylalanine Hydrochloride Hemihydrate, 99%
| 24286-13-3 |
|
3-Bromobenzoic Acid , 99%
| 585-76-2 |
|
N,N-Diethyl-p-phenylenediamine oxalate
| 62637-92-7 |
|
D-Gluconic Acid, Calcium Salt, 99%
| 299-28-5 |
|
Bis-Acrylamide
| 110-26-9 |
|
TEMED
| 110-18-9 |
|
N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride
| 637-01-4 |
|
BDCS Silylation Reagent
| 68-12-2 |
|
Nalidixic Acid
| 389-08-2 |
|
1-Nitroso-2-naphthol, 98%
| 131-91-9 |
|
Samarium, 99.9%, -40 Mesh
| 7440-19-9 |
|
Benzine
| 71-43-2 |
|
7-Nitroindole-2-Carboxylic Acid, 90-95% (HPLC)
| 6960-45-8 |
|
Naphthalene
| 91-20-3 |
|
Diphenylphosphoryl azide, 98%
| 26386-88-9 |
|
9,10-Dihydrophenanthrene, 95%
| 776-35-2 |
|
Ammonium Perrhenate(VII), 99.999%
| 13598-65-7 |
|
Methyl-2-Nitrobenzoate, 99%
| 606-27-9 |
|
Mixture of dichlorodimethylsilane and silicon(iv)chloride (86 and
| 75-78-5 |
|
Beta-Bromophenetole, 98%
| 589-10-6 |
|
Tri-n-butyltin hydride, 97%
| 688-73-3 |
|
Ethylene/propylene/diene terpolymer, high molecular weight
| 25038-36-2 |
|
Tetraethylammonium iodide, 98%
| 68-05-3 |
|
(4-Pyridylmethylamino)-acetaldehyde diethylacetal
| 35822-55-0 |
|
Glutathione, Reduced , 98%
| 70-18-8 |
|
Alloxan, Monohydrate
| 2244-11-3 |
|
Nickel Metal
| 7440-02-0 |
|
2-Acetylfluorene, 98%
| 781-73-7 |
|
Nickel (II) Acetate Tetrahydrate
| 6018-89-9 |
|
Gallium(III) perchlorate hydrate, 99%
| |
|
2-Nitrophenyl isocyanate, 99% (GC)
| 3220-86-3 |
|
|