**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6018-89-9 |Nickel (II) Acetate Tetrahydrate | 100.0 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 40 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Limited evidence of a carcinogenic effect. May
cause sensitization by skin contact.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause dermatitis. Causes "nickel itch"
which is a dermatitis resulting from sensitization to nickel, which
is characterized by skin eruptions, followed by discrete ulcers that
may discharge and become crusted, or by eczema.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause allergic respiratory
reaction. In rare instances, exposure may cause sensitization,
resulting in inflammation of the mucous membranes and in eczematous
eruptions.
Chronic:
May cause respiratory tract cancer. May cause cancer according to
animal studies. Symptoms of overexposure to nickel can cause
sensitization, dermatitis, allergic asthma and pneumonitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose
upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Minimize dust generation and accumulation.
Avoid contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 6018-89-9:
United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol
compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL
(as Ni)
Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA
(inhalable fraction, as Ni)
Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC
Ni)
Spain: (listed as nickel soluble compounds): 0.1 mg/m3 VLA-ED (as
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: green
Odor: acetic odor - weak odor
pH: Not available.
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not available.
Freezing/Melting Point: 482 deg F
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 27% @ 0 C
Specific Gravity/Density: 1.744
Molecular Formula: NiC4H6O4.4H2O
Molecular Weight: 248.7832
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic gases, carbon dioxide, nickel
oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6018-89-9: QR6126000
LD50/LC50:
CAS# 6018-89-9: Oral, mouse: LD50 = 410 mg/kg; Oral, rat: LD50 = 350
mg/kg.
Carcinogenicity:
Nickel (II) Acetate Tetrahydrate -
California: carcinogen, initial date 5/7/04 (listed as Nickel compound
NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 6018-89-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6018-89-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6018-89-9 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/17/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N,N'-Triethylethylenediamine, 99+%
| 105-04-4 |
|
Triethanolamine hydroiodide, 99%
| 7601-53-8 |
|
1-Methyl-5-mercaptotetrazole, sodium salt, dihydrate
| 51138-06-8 |
|
3-Octanone, 99%
| 106-68-3 |
|
4-Nitrochalcone, 99%
| 1222-98-6 |
|
Diphenyl-2-Pyridylmethane, 99+%
| 3678-70-4 |
|
3-Dimethylaminobenzoic Acid (Pract)
| 99-64-9 |
|
Ethyl 5-Nitroindole-2-Carboxylate, 95+%
| 16732-57-3 |
|
Fast red pdc salt
| 80-22-8 |
|
Copper(II) Chloride, Anhydrous, 98%
| 7447-39-4 |
|
4-Dimethylaminobenzoic acid, 98%
| 619-84-1 |
|
N,N,N',N'-Tetramethyl-1,3-propanediamine, 99+%
| 110-95-2 |
|
1-Butan(ol-d), 98+ atom % D
| 71-36-3 |
|
4-Heptanol, 99% (GC)
| 589-55-9 |
|
Thymolphthalein, Reagent ACS, 99% (UV-Vis)
| 125-20-2 |
|
Diphenyliodonium bromide
| 1483-73-4 |
|
Methyl formate-d, 98+ atom % d
| 23731-38-6 |
|
m-Nitrobenzoyl chloride
| 121-90-4 |
|
Acetaldehyde ammonia trimer, 98%
| 75-39-8 |
|
P-Amino-L-Phenylalanine Hydrochloride Hemihydrate, 99%
| 24286-13-3 |
|
3-Bromobenzoic Acid , 99%
| 585-76-2 |
|
N,N-Diethyl-p-phenylenediamine oxalate
| 62637-92-7 |
|
D-Gluconic Acid, Calcium Salt, 99%
| 299-28-5 |
|
Bis-Acrylamide
| 110-26-9 |
|
TEMED
| 110-18-9 |
|
N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride
| 637-01-4 |
|
BDCS Silylation Reagent
| 68-12-2 |
|
Nalidixic Acid
| 389-08-2 |
|
1-Nitroso-2-naphthol, 98%
| 131-91-9 |
|
Samarium, 99.9%, -40 Mesh
| 7440-19-9 |
|
Benzine
| 71-43-2 |
|
7-Nitroindole-2-Carboxylic Acid, 90-95% (HPLC)
| 6960-45-8 |
|
Naphthalene
| 91-20-3 |
|
Diphenylphosphoryl azide, 98%
| 26386-88-9 |
|
9,10-Dihydrophenanthrene, 95%
| 776-35-2 |
|
Ammonium Perrhenate(VII), 99.999%
| 13598-65-7 |
|
Methyl-2-Nitrobenzoate, 99%
| 606-27-9 |
|
Mixture of dichlorodimethylsilane and silicon(iv)chloride (86 and
| 75-78-5 |
|
Beta-Bromophenetole, 98%
| 589-10-6 |
|
Tri-n-butyltin hydride, 97%
| 688-73-3 |
|
Ethylene/propylene/diene terpolymer, high molecular weight
| 25038-36-2 |
|
Tetraethylammonium iodide, 98%
| 68-05-3 |
|
(4-Pyridylmethylamino)-acetaldehyde diethylacetal
| 35822-55-0 |
|
Glutathione, Reduced , 98%
| 70-18-8 |
|
Alloxan, Monohydrate
| 2244-11-3 |
|
Nickel Metal
| 7440-02-0 |
|
2-Acetylfluorene, 98%
| 781-73-7 |
|
Nickel (II) Acetate Tetrahydrate
| 6018-89-9 |
|
Gallium(III) perchlorate hydrate, 99%
| |
|
2-Nitrophenyl isocyanate, 99% (GC)
| 3220-86-3 |
|
|