**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 71-43-2 |Benzene | 0.015 | 200-753-7 |
|----------------|--------------------------------------|----------|-----------|
| 100-41-4 |Ethylbenzene | 0.03 | 202-849-4 |
|----------------|--------------------------------------|----------|-----------|
| 108-38-3 |m-Xylene | 0.05 | 203-576-3 |
|----------------|--------------------------------------|----------|-----------|
| 108-88-3 |Toluene | 0.0118 | 203-625-9 |
|----------------|--------------------------------------|----------|-----------|
| 111-65-9 |Octane | 1.5 | 203-892-1 |
|----------------|--------------------------------------|----------|-----------|
| 142-82-5 |n-Heptane | 1.16 | 205-563-8 |
|----------------|--------------------------------------|----------|-----------|
| 1330-20-7 |Xylenes (o-, m-, p- isomers) | 0.13 | 215-535-7 |
|----------------|--------------------------------------|----------|-----------|
| 64742-89-8 |Solvent naphtha (petroleum), light ali| 100 | 265-192-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F
Risk Phrases: 11 65 67
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful: may cause lung damage if swallowed.
Vapours may cause drowsiness and dizziness.
Potential Health Effects
Eye:
May cause eye irritation. Vapors may cause eye irritation.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause
defatting of the skin and dermatitis. Not expected to cause an
allergic skin reaction.
Ingestion:
May cause central nervous system depression, characterized by
excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and
possible death due to respiratory failure. Aspiration of material
into the lungs may cause chemical pneumonitis, which may be fatal.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation.
Inhalation of vapors may cause drowsiness and dizziness.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Prolonged or repeated exposure affects the nervous
system. This material has caused kidney effects in male rats which
are not considered relevant to humans. Chronic hydrocarbon abuse (for
example, sniffing glue or light hydrocarbons such as contained in
this material) has been associated with irregular heart rhythms and
potential cardiac arrest.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately.
Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Use water spray to keep fire-exposed containers
cool. Liquid will float and may reignite on the surface of water.
Flammable liquid and vapor. Vapors are heavier than air and may
travel to a source of ignition and flash back. Vapors can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Do NOT use straight streams of water. For large fires, use water
spray, fog or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Remove all sources of ignition. Use
a spark-proof tool. Provide ventilation. A vapor suppressing foam
may be used to reduce vapors. Water spray may reduce vapor but may
not prevent ignition in closed spaces. Approach spill from upwind.
Control runoff and isolate discharged material for proper disposal.
Under Section 311 of the Clean Water Act (CWA) this material is
considered an oil. As such, spills into surface waters must be
reported to the National Response Centre at 800-424-8802.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Take precautionary measures against static discharges.
Keep container tightly closed. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Use only with adequate ventilation. Keep away from heat,
sparks and flame. Avoid breathing vapor.
Storage:
Keep away from sources of ignition. Keep from contact with oxidizing
materials. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible
exposure limits.
Exposure Limits
CAS# 71-43-2:
United Kingdom, WEL - TWA: 1 ppm TWA
United Kingdom, WEL - STEL: 3 ppm STEL
United States OSHA: 10 ppm TWA (apply only to exempt industry
segments); 25 ppm Ceiling; 1 ppm PEL; 5 ppm STEL; 0.5 ppm Action
Level (Cancer hazard, Flammable - see 29 C FR 1910.1028)
Belgium - TWA: 1 ppm VLE; 3.25 mg/m3 VLE
France - VME: 1 ppm VME; 3.25 mg/m3 VME
Germany: 1 ppm TWA; 3.25 mg/m3 TWA
Germany: Skin absorber
Japan: 1 ppm OEL (reference value)
Malaysia: 0.5 ppm TWA; 1.6 mg/m3 TWA
Netherlands: 1 ppm MAC; 3.25 mg/m3 MAC
Russia: 15 mg/m3 TWA
Russia: 5 mg/m3 STEL
Spain: 1 ppm VLA-ED; 3.25 mg/m3 VLA-ED
CAS# 100-41-4:
United Kingdom, WEL - TWA: 100 ppm TWA; 441 mg/m3 TWA
United Kingdom, WEL - STEL: 125 ppm STEL; 552 mg/m3 STEL
United States OSHA: 100 ppm TWA; 435 mg/m3 TWA
Belgium - TWA: 100 ppm VLE; 442 mg/m3 VLE
Belgium - STEL: 125 ppm VLE; 551 mg/m3 VLE
France - VME: 100 ppm VME; 435 mg/m3 VME
Germany: 100 ppm TWA; 440 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 217 mg/m3 OEL
Malaysia: 100 ppm TWA; 434 mg/m3 TWA
Netherlands: 50 ppm MAC; 215 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 100 ppm VLA-ED; 441 mg/m3 VLA-ED
Spain: 200 ppm VLA-EC; 884 mg/m3 VLA-EC
CAS# 108-38-3:
United Kingdom, WEL - TWA: 50 ppm TWA; 220 mg/m3 TWA
United Kingdom, WEL - STEL: 100 ppm STEL; 441 mg/m3 STEL
United States OSHA: 100 ppm TWA; 435 mg/m3 TWA (listed under Xyl
(o-, m-, p- isomers)).
Belgium - TWA: 50 ppm VLE; 221 mg/m3 VLE
Belgium - STEL: 150 ppm VLE; 442 mg/m3 VLE
France - VME: (listed as xylenes (o-, m-, p- isomers)): 100 ppm V
435 mg/m3 VME
France - VLE: (listed as xylenes (o-, m-, p- isomers)): 150 ppm V
650 mg/m3 VLE
Germany: (listed as xylenes (o-, m-, p- isomers)): 100 ppm VME; 4
mg/m3 VME
Germany: (listed as xylenes (o-, m-, p- isomers)): Skin absorber
Japan: 50 ppm OEL; 217 mg/m3 OEL
Malaysia: 199 ppm TWA; 434 mg/m3 TWA
Netherlands: (listed as xylenes (o-, m-, p- isomers)): 50 ppm MAC
210 mg/m3 MAC
Russia: (listed as xylenes (o-, m-, p- isomers)): 50 mg/m3 TWA
Spain: 50 ppm VLA-ED; 221 mg/m3 VLA-ED
Spain: 100 ppm VLA-EC; 442 mg/m3 VLA-EC
CAS# 108-88-3:
United Kingdom, WEL - TWA: 50 ppm TWA; 191 mg/m3 TWA
United Kingdom, WEL - STEL: 150 ppm STEL; 574 mg/m3 STEL
United States OSHA: 200 ppm TWA; 300 ppm Ceiling
Belgium - TWA: 50 ppm VLE; 191 mg/m3 VLE
France - VME: 100 ppm VME; 375 mg/m3 VME
France - VLE: 150 ppm VLE; 550 mg/m3 VLE
Germany: 50 ppm TWA; 190 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 188 mg/m3 OEL
Malaysia: 50 ppm TWA; 188 mg/m3 TWA
Netherlands: 40 ppm MAC; 150 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 50 ppm VLA-ED; 191 mg/m3 VLA-ED
CAS# 111-65-9:
United States OSHA: 500 ppm TWA; 2350 mg/m3 TWA
Belgium - TWA: 300 ppm VLE; 1420 mg/m3 VLE
Belgium - STEL: 375 ppm VLE; 1775 mg/m3 VLE
France - VME: 300 ppm VME; 1450 mg/m3 VME
Germany: 500 ppm TWA; 2400 mg/m3 TWA
Japan: 300 ppm OEL; 1400 mg/m3 OEL
Malaysia: 300 ppm TWA; 11400 mg/m3 TWA
Netherlands: 300 ppm MAC; 1450 mg/m3 MAC
Spain: 300 ppm VLA-ED; 1420 mg/m3 VLA-ED
CAS# 142-82-5:
United Kingdom, WEL - TWA: 500 ppm TWA
United Kingdom, WEL - STEL: 1500 ppm STEL
United States OSHA: 500 ppm TWA; 2000 mg/m3 TWA
Belgium - TWA: 400 ppm VLE; 1664 mg/m3 VLE
Belgium - STEL: 500 ppm VLE; 2085 mg/m3 VLE
France - VME: 400 ppm VME; 1600 mg/m3 VME
Germany: 500 ppm TWA; 2100 mg/m3 TWA
Japan: 200 ppm OEL; 820 mg/m3 OEL
Malaysia: 400 ppm TWA; 1640 mg/m3 TWA
Netherlands: 400 ppm STEL; 1600 mg/m3 STEL
Netherlands: 300 ppm MAC; 1200 mg/m3 MAC
Spain: 500 ppm VLA-ED; 2085 mg/m3 VLA-ED
CAS# 1330-20-7:
United Kingdom, WEL - TWA: 50 ppm TWA; 220 mg/m3 TWA
United Kingdom, WEL - STEL: 100 ppm STEL; 441 mg/m3 STEL
United States OSHA: 100 ppm TWA; 435 mg/m3 TWA
Belgium - TWA: 50 ppm VLE; 221 mg/m3 VLE
Belgium - STEL: 150 ppm VLE; 442 mg/m3 VLE
France - VME: 100 ppm VME; 435 mg/m3 VME
France - VLE: 150 ppm VLE; 650 mg/m3 VLE
Germany: 100 ppm TWA; 440 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 217 mg/m3 OEL
Malaysia: 199 ppm TWA; 434 mg/m3 TWA
Netherlands: 50 ppm MAC; 210 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 50 ppm VLA-ED; 221 mg/m3 VLA-ED
Spain: 100 ppm VLA-EC; 442 mg/m3 VLA-EC
CAS# 64742-89-8:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light colored
Odor: hydrocarbon-like - petroleum-like - mild odor
pH: Not available.
Vapor Pressure: 15 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 118.5-140.5 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: 232 deg C ( 449.60 deg F)
Flash Point: 14-18 deg C
Explosion Limits, lower: 0.9% vol
Explosion Limits, upper: 7.0% vol
Decomposition Temperature: Not available.
Solubility in water: Negligible.
Specific Gravity/Density: 0.74 @ 20/20C
Molecular Formula: C5 to C10 hydrocarbons
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide in cases of incomplete combustion, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 71-43-2: CY1400000
CAS# 100-41-4: DA0700000
CAS# 108-38-3: ZE2275000
CAS# 108-88-3: XS5250000
CAS# 111-65-9: RG8400000
CAS# 142-82-5: MI7700000
CAS# 1330-20-7: ZE2100000
CAS# 64742-89-8 unlisted.
LD50/LC50:
CAS# 71-43-2: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test,
rabbit, eye: 88 mg Moderate; Draize test, rabbit, eye: 2 mg/24H
Severe; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation,
mouse: LC50 = 9980 ppm; Inhalation, mouse: LC50 = 24 mL/kg/2H;
Inhalation, rat: LC50 = 10000 ppm/7H; Inhalation, rat: LC50 = 34
mL/kg/2H; Inhalation, rat: LC50 = 6.5 mL/kg/4H; Oral, mouse: LD50 =
4700 mg/kg; Oral, rat: LD50 = 930 mg/kg; Oral, rat: LD50 = 1 mL/kg;
Oral, rat: LD50 = 1800 mg/kg; Skin, rabbit: LD50 = >9400 uL/kg.
CAS# 100-41-4: Draize test, rabbit, eye: 500 mg Severe; Inhalation,
mouse: LC50 = 35500 mg/m3/2H; Inhalation, rat: LC50 = 55000
mg/m3/2H; Oral, rat: LD50 = 3500 mg/kg; Oral, rat: LD50 = 3500
mg/kg; Skin, rabbit: LD50 = 17800 uL/kg.
CAS# 108-38-3: Draize test, rabbit, eye: 5 mg/24H Severe; Draize
test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 =
5267 ppm/6H; Oral, rat: LD50 = 4988 mg/kg; Skin, rabbit: LD50 = 14100
uL/kg.
CAS# 108-88-3: Draize test, rabbit, eye: 870 ug Mild; Draize test,
rabbit, eye: 2 mg/24H Severe; Draize test, rabbit, skin: 435 mg Mild;
Draize test, rabbit, skin: 500 mg Moderate; Draize test, rabbit,
skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 400 ppm/24H;
Inhalation, mouse: LC50 = 30000 mg/m3/2H; Inhalation, mouse: LC50 =
19900 mg/m3/7H; Inhalation, mouse: LC50 = 10000 mg/m3; Inhalation,
rat: LC50 = 49 gm/m3/4H; Oral, rat: LD50 = 636 mg/kg; Skin, rabbit:
LD50 = 14100 uL/kg.
CAS# 111-65-9: Inhalation, rat: LC50 = 118 gm/m3/4H.
CAS# 142-82-5: Inhalation, rat: LC50 = 103 gm/m3/4H.
CAS# 1330-20-7: Draize test, rabbit, eye: 87 mg Mild; Draize test,
rabbit, eye: 5 mg/24H Severe; Draize test, rabbit, skin: 100%
Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate; Inhalation,
rat: LC50 = 5000 ppm/4H; Oral, mouse: LD50 = 2119 mg/kg; Oral, rat:
LD50 = 4300 mg/kg; Skin, rabbit: LD50 = >1700 mg/kg.
CAS# 64742-89-8.
Carcinogenicity:
Benzene -
ACGIH: A1 - Confirmed Human Carcinogen
California: carcinogen, initial date 2/27/87
NTP: Known carcinogen
IARC: Group 1 carcinogen
Ethylbenzene -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 6/11/04
IARC: Group 2B carcinogen
m-Xylene -
Not listed by ACGIH, IARC, or NTP.
Toluene -
Not listed by ACGIH, IARC, or NTP.
Octane -
Not listed by ACGIH, IARC, or NTP.
n-Heptane -
Not listed by ACGIH, IARC, or NTP.
Xylenes (o-, m-, p- isomers) -
Not listed by ACGIH, IARC, or NTP.
Solvent naphtha (petroleum), light aliphatic -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PETROLEUM DISTILLATES, NOS
Hazard Class: 3
UN Number: 1268
Packing Group: II
IMO
Shipping Name: PETROLEUM DISTILLATES, NOS
Hazard Class: 3
UN Number: 1268
Packing Group: II
RID/ADR
Shipping Name: PETROLEUM DISTILLATES, NOS
Hazard Class: 3
UN Number: 1268
Packing group: II
USA RQ: CAS# 71-43-2: 10 lb final RQ (receives an adjustable RQ of 10 lbs based
USA RQ: CAS# 100-41-4: 1000 lb final RQ; 454 kg final RQ
USA RQ: CAS# 108-38-3: 1000 lb final RQ (Listed under Xylene, mixed); 454 kg fin
USA RQ: CAS# 108-88-3: 1000 lb final RQ; 454 kg final RQ
USA RQ: CAS# 1330-20-7: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
R 65 Harmful: may cause lung damage if swallowed.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 71-43-2: 3
CAS# 100-41-4: 1
CAS# 108-38-3: No information available.
CAS# 108-88-3: 2
CAS# 111-65-9: 1
CAS# 142-82-5: 1
CAS# 1330-20-7: 2
CAS# 64742-89-8: No information available.
Canada
CAS# 71-43-2 is listed on Canada's DSL List.
CAS# 100-41-4 is listed on Canada's DSL List.
CAS# 108-38-3 is listed on Canada's DSL List.
CAS# 108-88-3 is listed on Canada's DSL List.
CAS# 111-65-9 is listed on Canada's DSL List.
CAS# 142-82-5 is listed on Canada's DSL List.
CAS# 1330-20-7 is listed on Canada's DSL List.
CAS# 64742-89-8 is listed on Canada's DSL List.
CAS# 71-43-2 is listed on Canada's Ingredient Disclosure List.
CAS# 100-41-4 is listed on Canada's Ingredient Disclosure List.
CAS# 108-38-3 is listed on Canada's Ingredient Disclosure List.
CAS# 108-88-3 is listed on Canada's Ingredient Disclosure List.
CAS# 111-65-9 is listed on Canada's Ingredient Disclosure List.
CAS# 142-82-5 is listed on Canada's Ingredient Disclosure List.
CAS# 1330-20-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 64742-89-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 71-43-2 is listed on the TSCA inventory.
CAS# 100-41-4 is listed on the TSCA inventory.
CAS# 108-38-3 is listed on the TSCA inventory.
CAS# 108-88-3 is listed on the TSCA inventory.
CAS# 111-65-9 is listed on the TSCA inventory.
CAS# 142-82-5 is listed on the TSCA inventory.
CAS# 1330-20-7 is listed on the TSCA inventory.
CAS# 64742-89-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 38 Irritating to skin.
R 20 Harmful by inhalation.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 5/13/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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