Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
Section 1 - Chemical Product and Company Identification
Product Name Urethane Sealant
CAS# Mixture/None Assigned
Generic Name Sealant
Formula MIxture
Chemical Name: Mixture
Hazard Label L-10025
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: Urethane Sealant
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
Trade Secret Aromatic polyisocyanate resin 30-60
1317-65-3 Calcium carbonate 10-20
Trade Secret Phthalate plasticizer 5-10
85-68-7 Butyl benzyl phthalate 5-10
64742-95-6 Petroleum naphtha, light aromatic 1-10
Trade Secret Thickener 3-7
13463-67-7 Titanium dioxide 0.0-10.0
1309-37-1 Iron oxide 0.0-7.0
61788-32-7 Hydrogenated terphenyls >3
101-68-8 Methylene bisphenylisocyanate (MDI) 1-5
25551-13-7 Trimethyl benzene 1-5
Trade Secret Inert filler 1-5
1333-86-4 Carbon black 0.0-2.0
1330-20-7 Xylenes (o-, m-, p- isomers) 0.1-0.5
9016-87-9 Polymethylene polyphenylene isocyanate 0.1-0.5
26471-62-5 Toluene diisocyanate 0.1-0.5
14808-60-7 Quartz 0.01-0.4
Additional Component Information
* Note: Due to the product form, exposures to hazardous dusts or fumes are not expected to occur. Exposure limits are given
for reference only.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Various color paste with solvent odor.
Irritating to skin, eyes, and respiratory system. If inhalation occurs, move affected individual to fresh air, administer oxygen and
artificial respiration as necessary. Get immediate medical attention.
If ingestion occurs, do not induce vomiting. Give 1-2 cups milk or water, and seek medical attention.
Potential Health Effects
Summary
Exposure to vapors from this product may be irritating to the eyes, respiratory passages, and mucous membranes. MDI is a
strong sensitizer. Inhalation of mists or skin or eye contact may result in irritation and sensitization (allergy).
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Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
Inhalation
Irritation of the upper respiratory tract. Following sensitization, asthma-like reactions may occur with respiratory secretions,
cough, pain, and some restriction of air movement. Symptoms may persist for three to seven days. Vapors from this product
may cause eye and upper respiratory irritation, dry throat and mouth, nausea, headache, dizziness, drowsiness, and coma in
extreme cases. Prolonged exposures may lead to liver and kidney injury.
Skin
Immediately following sensitization, rash or redness may occur (allergic-type reactions). May stain skin. This material can be
absorbed into the body through the skin, but no harmful effects are expected from absorption during safe handling and use.
Absorption
Same as skin
Ingestion
This product is not intended to be ingested or eaten under normal conditions of use. If ingested, it may cause irritation and
corrosive effects on the digestive system.
Eyes
Immediately irritation (itching) or redness may occur. Materials containing MDI may react with moisture of the eye, forming a
thick material which may be difficult to wash from the eye.
Primary Routes of Entry (Exposure)
Inhalation (breathing), skin, and eye contact.
Target Organs
Skin, eye, lungs, central nervous system (CNS), respiratory system, kidney, liver.
Medical Conditions Aggravated by Exposure
Pre-existing respiratory diseases or conditions, especially asthma or chemically-induced asthma. Prior exposure and
sensitization to isocyanate, or other chemical sensitizers may cause asthmatic, or allergic reactions. Pre-existing eye, skin,
respiratory, central nervous system (CNS), liver and kidney diseases or conditions.
Section 4 - First Aid Measures
First Aid: Inhalation
Move affected individual to an area free of risk from further exposure. Administer oxygen or artificial respiration as needed.
Immediate or delayed asthma-like symptoms may develop. Obtain medical attention.
First Aid: Skin
Remove contaminated clothing. Wash affected areas with soap and warm water. Use safety shower for severe exposures. Get
medical attention if irritation or sensitization develops or persists. Launder contaminated clothing before reuse.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If ingested, do not induce vomiting and do not give anything by mouth if the
affected individual is unconscious or is losing consciousness. Otherwise, give one to two glasses of milk or water to drink, and
obtain medical attention.
First Aid: Eyes
Flush eyes for at least 20 minutes while holding eyelids open. Refer to a physician or ophthalmologist for a complete follow-up.
First Aid: Notes to Physician
For MDI exposure to eyes, stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation
frequently. Workplace vapors have produced reversible corneal epithelial edema, impairing vision. MDI is a known skin
sensitizer. If exposure to skin occurs, treat symptomatically as for contact dermatitis or thermal burns. If burned, treat as
thermal burns. MDI is also a known pulmonary sensitizer. Treatment is essentially symptomatic. An individual having a skin or
pulmonary sensitization reaction to this material should be removed from further exposure to any isocyanate.
Section 5 - Fire Fighting Measures
Flash Point: 66潞C/150潞F Method Used: TCC
Upper Flammable Limit (UFL): 7 Lower Flammable Limit (LFL): 0.6
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
Down-wind personnel must be evacuated. Do not reseal contaminated containers; a chemical reaction generating carbon
dioxide gas pressure may occur resulting in rupture of the container. Dense smoke is emitted when product is burned without
sufficient oxygen. When using water spray, boil-over may occur when product temperature reaches the boiling point of water,
and the reaction forming carbon dioxide will accelerate (tank-type scenarios, not spills).
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Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
Hazardous Combustion Products
Decomposition products include isocyanate vapor and mist, carbon dioxide, carbon monoxide, nitrogen oxide, and traces of
hydrogen cyanide.
Extinguishing Media
Carbon dioxide (CO2), dry chemical, or foam. For large scale fires, alcohol-resistant foams are preferred, if available. General
purpose synthetic foams or protein foams may function, but much less effectively. If water is used, it should be used in very
large quantities. The reaction between water and isocyanate may be vigorous. If possible, contain fire run-off water.
Fire Fighting Equipment/Instructions
Wear self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode when fighting
fires. Fire fighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Fire fighters
should avoid inhaling any combustion products.
Section 6 - Accidental Release Measures
Containment Procedures
Remove all sources of ignition. Evacuate and ventilate spill area. Dam spill area with sand, earth, or other suitable absorbent.
Prevent entry of material into sewers, other water sources, or land areas. Wear full protective clothing and respiratory
protection during clean-up as required to maintain exposures below the applicable exposure limit. Shovel absorbed material
into containers in well-ventilated area.
Clean-Up Procedures
Dispose of spilled material in accordance with federal, state, and local regulations. Incineration is the preferred method of
disposal. Empty containers must be handled with care due to product residue. If you are unsure of the regulations, contact
your local Public Health Department, or local office of the Environmental Protection Agency (EPA).
Section 7 - Handling and Storage
Handling Procedures
Keep this container and vapors from this container away from heat, sparks and flame. Store in tightly closed containers to
prevent contamination. Keep containers sealed when not in use and clean spills promptly to reduce air concentrations and
floor hazards. Ground all equipment when handling flammable solvent borne materials.
Storage Procedures
Do not re-seal if contamination is suspected. Store in a cool location below (80潞F) away from sunlight and any source of heat,
sparks or flame. Handle with non-sparking tools.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be provided as necessary to prevent irritation of the eyes, skin, and respiratory tract, and to keep
exposure levels below the applicable exposure limits.
B: Component Exposure Limits
Calcium carbonate (1317-65-3)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Titanium dioxide (13463-67-7)
ACGIH: 10 mg/m3 TWA
OSHA: 10 mg/m3 TWA (total dust)
Iron oxide (1309-37-1)
ACGIH: 5 mg/m3 TWA (dust and fume, as Fe)
OSHA: 10 mg/m3 TWA (fume)
Hydrogenated terphenyls (61788-32-7)
ACGIH: 0.5 ppm TWA (non-irradiated)
OSHA: 0.5 ppm TWA; 5 mg/m3 TWA
Methylene bisphenylisocyanate (MDI) (101-68-8)
ACGIH: 0.005 ppm TWA
OSHA: 0.02 ppm Ceiling; 0.2 mg/m3 Ceiling
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Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
Trimethyl benzene (25551-13-7)
ACGIH: 25 ppm TWA
OSHA: 25 ppm TWA; 125 mg/m3 TWA
Carbon black (1333-86-4)
ACGIH: 3.5 mg/m3 TWA
OSHA: 3.5 mg/m3 TWA
Xylenes (o-, m-, p- isomers) (1330-20-7)
ACGIH: 100 ppm TWA
150 ppm STEL
OSHA: 100 ppm TWA; 435 mg/m3 TWA
150 ppm STEL; 655 mg/m3 STEL
Toluene diisocyanate (26471-62-5)
ACGIH: 0.005 ppm TWA
0.02 ppm STEL
Quartz (14808-60-7)
ACGIH: 0.05 mg/m3 TWA (respirable fraction)
OSHA: 0.1 mg/m3 TWA (respirable dust)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields, chemical goggles, or face mask recommended.
Personal Protective Equipment: Skin
Rubber gloves should be used to help prevent excessive skin contact.
Personal Protective Equipment: Respiratory
If air concentrations exceed established limits, a NIOSH-approved supplied air respirator or self-contained breathing apparatus
is required.
Ventilation
If vapor or mist is generated during processing or use, local exhaust ventilation should be provided to maintain exposures
below the applicable limits. The need for ventilation systems should be evaluated by a professional industrial hygienist, while
the design of specific ventilation systems should be conducted by a professional engineer.
Personal Protective Equipment: General
Loose-fitting, long-sleeved clothing should be worn to protect skin from exposure. Exposed areas should be washed with soap
and warm water. Clothing should be washed separately from other clothes, and the washer should be rinsed thoroughly (run
empty for a complete wash cycle).
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Various colors Solvent
Physical State: pH:
Paste Not applicable
Vapor Pressure: Vapor Density:
Not established >1 (Air = 1)
Boiling Point: Melting Point:
280潞F/138潞C Not established
Solubility (H2O): Specific Gravity:
Negligible 1.3
Freezing Point: Solids Content
Not established Not determined
Evaporation Rate: Viscosity:
Not determined Not determined
Percent Volatile: 10
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
Stable
Incompatibility
Avoid contact with water, amines, bases, oxidizers, alcohols.
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Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
Hazardous Decomposition
Decomposition products include isocyanate vapor and mist, carbon dioxide, carbon monoxide, nitrogen oxide, and traces of
hydrogen cyanide.
Hazardous Polymerization
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
MDI is an allergic sensitizing agent that may produce wheezing, coughing, shortness of breath, runny nose, sore throat,
coughing, and reduced lung function. Effects may be delayed. Eye contact may cause irritation with tearing (watery eyes),
reddening, and swelling. Ingestion may produce irritation, and corrosive effects on the digestive system.
B: Component Analysis - LD50/LC50
Butyl benzyl phthalate (85-68-7)
Inhalation LC50 Rat: >6.7 mg/L/4H; Oral LD50 Rat: 2330 mg/kg; Dermal LD50 Rabbit: >10 g/kg
Petroleum naphtha, light aromatic (64742-95-6)
Inhalation LC50 Rat: >5.2 mg/L/4H; Inhalation LC50 Rat: 3400 ppm/4H; Oral LD50 Rat: 8400 mg/kg; Dermal LD50 Rabbit:
>2000 mg/kg
Titanium dioxide (13463-67-7)
Oral LD50 Rat: >10000 mg/kg
Iron oxide (1309-37-1)
Oral LD50 Rat: >10000 mg/kg
Hydrogenated terphenyls (61788-32-7)
Inhalation LC50 Rat: >4.3 mg/L/4H; Oral LD50 Rat: 10200 mg/kg; Dermal LD50 Rabbit: 6800 mg/kg
Methylene bisphenylisocyanate (MDI) (101-68-8)
Oral LD50 Rat: 9200 mg/kg
Trimethyl benzene (25551-13-7)
Oral LD50 Rat: 8970 mg/kg
Carbon black (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit: >3 g/kg
Xylenes (o-, m-, p- isomers) (1330-20-7)
Inhalation LC50 Rat: 5000 ppm/4H; Oral LD50 Rat: 4300 mg/kg; Dermal LD50 Rabbit: >1700 mg/kg
Polymethylene polyphenylene isocyanate (9016-87-9)
Inhalation LC50 Rat: 490 mg/m3/4H; Oral LD50 Rat: 49 g/kg; Dermal LD50 Rabbit: >9400 mg/kg
Toluene diisocyanate (26471-62-5)
Inhalation LC50 Rat: 0.1 mg/L/4H; Inhalation LC50 Rat: 13.9 ppm/4H; Inhalation LC50 Rat: 66 ppm/1H; Oral LD50 Rat: 3360
mg/kg; Dermal LD50 Rabbit: 10000 mg/kg
Quartz (14808-60-7)
Oral LD50 Rat: 500 mg/kg
Carcinogenicity
A: General Product Information
No additional information available.
B: Component Carcinogenicity
Butyl benzyl phthalate (85-68-7)
IARC: Group 3 - Not Classifiable (IARC Monograph 73, 1999)
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Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
Titanium dioxide (13463-67-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 3 - Not Classifiable (IARC Monograph 47, 1989)
Iron oxide (1309-37-1)
ACGIH: A4 - Not Classifiable as a Human Carcinogen (dust and fume)
IARC: Group 3 - Not Classifiable (IARC Supplement 7, 1987; Monograph 1, 1972)
Methylene bisphenylisocyanate (MDI) (101-68-8)
IARC: Group 3 - Not Classifiable (IARC Monograph 71, 1999; Supplement 7, 1987; Monograph 19,
1979)
Carbon black (1333-86-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 65, 1996)
Xylenes (o-, m-, p- isomers) (1330-20-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 3 - Not Classifiable (IARC Monograph 71, 1999; Monograph 47, 1989)
Polymethylene polyphenylene isocyanate (9016-87-9)
IARC: Group 3 - Not Classifiable (IARC Supplement 7, 1987; Monograph 19, 1979)
Toluene diisocyanate (26471-62-5)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
NTP: Reasonably Anticipated To Be A Carcinogen (Possible Select Carcinogen)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 71, 1999; Supplement 7, 1987;
Monograph 39, 1986)
Quartz (14808-60-7)
ACGIH: A2 - Suspected Human Carcinogen
IARC: Group 1 - Known Human Carcinogen (IARC Monograph 68, 1997, listed under Crystalline silica,
inhaled in the form of quartz or cristobalite from occupational sources)
Chronic Toxicity
Repeated, prolonged skin contact will defat the skin, causing drying, cracking, and dermatitis. Exposure to vapors, or
prolonged skin contact may result in sensitization to isocyanate products due to the presence of isocyanates. Exposure to
vapors can cause skin, central nervous system (CNS), liver, and kidney damage.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Butyl benzyl phthalate (85-68-7)
96 Hr LC50 rainbow trout: 2.9 mg/L (static);96 Hr LC50 fathead minnow: 1.7 mg/L (static);96 Hr LC50 bluegill sunfish: 1.0
mg/L (static)
96 Hr EC50 freshwater algae (Selenastrum capricornutum and Skeletonema costatum): 0.1 mg/L
48 Hr EC50 water flea: 3.0 mg/L (Static)
Trimethyl benzene (25551-13-7)
96 Hr LC50 fathead minnow: 7.72 mg/L (flow-through);96 Hr LC50 goldfish: 12.52 mg/L (flow-through)
Xylenes (o-, m-, p- isomers) (1330-20-7)
96 Hr LC50 fathead minnow: 13.4 mg/L (flow-through);96 Hr LC50 rainbow trout: 8.05 mg/L (flow-through);96 Hr LC50 bluegill:
16.1 mg/L (flow-through)
24 hr EC50 Photobacterium phosphoreum: 0.0084 mg/L
48 Hr EC50 water flea: 3.82 mg/L
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Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
This product is not regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under Resource
Conservation and Recovery Act (RCRA) regulations.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
International Transportation Regulations
DOT: Consumer Commodity, ORM-D
Package limits must not exceed 5L inner, 30kg outer
IATA: ID 8000, Consumer Commodity, 9
Package limits must not exceed 500 mL inner, 30kg outer
IMDG: UN 1133, Adhesives, 3, PGII
Package limits must not exceed 5L Inner package, 30 kg outer package
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Immediate (acute) health hazard. Delayed
(chronic) health hazard. Fire hazard.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Butyl benzyl phthalate (85-68-7)
CERCLA: 100 lb final RQ; 45.4 kg final RQ
Methylene bisphenylisocyanate (MDI) (101-68-8)
SARA 313: 1.0 % de minimis concentration (Listed under Chemical Category N120, Diisocyanates)
CERCLA: 5000 lb final RQ; 2270 kg final RQ
Xylenes (o-, m-, p- isomers) (1330-20-7)
CERCLA: 100 lb final RQ; 45.4 kg final RQ
Toluene diisocyanate (26471-62-5)
SARA 313: 0.1 % de minimis concentration
CERCLA: 100 lb final RQ (listed under Toluene diisocyanate); 45.4 kg final RQ (listed under Toluene
diisocyanate)
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
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Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Calcium carbonate 1317-65-3 No No Yes Yes No Yes
Butyl benzyl phthalate 85-68-7 Yes No Yes No Yes Yes
Titanium dioxide 13463-67-7 No No Yes Yes Yes Yes
Iron oxide 1309-37-1 Yes No Yes Yes Yes Yes
Hydrogenated terphenyls 61788-32-7 Yes No Yes Yes No Yes
Methylene bisphenylisocyanate (MDI) 101-68-8 Yes No Yes Yes Yes Yes
Trimethyl benzene 25551-13-7 Yes No Yes Yes Yes Yes
Carbon black 1333-86-4 Yes No Yes Yes Yes Yes
Xylenes (o-, m-, p- isomers) 1330-20-7 Yes No Yes Yes Yes Yes
Toluene diisocyanate 26471-62-5 Yes No Yes No No Yes
Quartz 14808-60-7 No No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Carbon black CAS# 1333-86-4
Toluene diisocyante CAS# 26471-62-5
Quartz CAS# 14808-60-7
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Calcium carbonate 1317-65-3 Yes No Yes
Butyl benzyl phthalate 85-68-7 Yes Yes Yes
Petroleum naphtha, light aromatic 64742-95-6 Yes Yes Yes
Titanium dioxide 13463-67-7 Yes Yes Yes
Iron oxide 1309-37-1 Yes Yes Yes
Hydrogenated terphenyls 61788-32-7 Yes Yes Yes
Methylene bisphenylisocyanate (MDI) 101-68-8 Yes Yes Yes
Trimethyl benzene 25551-13-7 Yes Yes Yes
Carbon black 1333-86-4 Yes Yes Yes
Xylenes (o-, m-, p- isomers) 1330-20-7 Yes Yes Yes
Polymethylene polyphenylene isocyanate 9016-87-9 Yes Yes No
Toluene diisocyanate 26471-62-5 Yes Yes Yes
Quartz 14808-60-7 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Butyl benzyl phthalate 85-68-7 1%
Iron oxide 1309-37-1 1%
Methylene bisphenylisocyanate (MDI) 101-68-8 0.1 %
Trimethyl benzene 25551-13-7 1%
Carbon black 1333-86-4 1%
Toluene diisocyanate 26471-62-5 0.1 %
WHMIS Classification
Controlled Product Classification: D2A, based on respiratory sensitization properties of MDI.
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Material Name: Urethane Sealant Material Safety Data
Sheet ID: 3150
Ingredient Disclosure (0.1%): methylenebis (phenyl isocyanate).
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
03/12/01 3150-1.0000 Product moved from MSDS 3103 to its own sheet because of new
vendor ingredient information.
7/19/01 3150-1.0100 Sec. 11 Update LD50 for Petroleum Naphtha; Sec. 15 Update
Inventory Information
12/08/03 3150-1.0101 Regulatory review. Minor edits.
12/28/05 3150-1.0102 Regulatory update. Minor edits in Section 8 Exposure, Section 11
LD50, Section 12 Ecotox, and Section 15 SARA, CERCLA,
WHMIS, and state. Section 14 Transportation addition of IATA and
IMDG info.
This is the end of MSDS # 3150
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