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MSDS Material Safety Data Sheet
CAS

9006-04-6
1333-86-4
64742-04-7
64742-11-6
1314-13-2
7704-34-9

File Name: jm_com---EN3151.asp
                                     Material Name: JM EPDM Peel & Stick Walkway Pad                            Safety Data Sheet
ID: 3151

Section 1 - Product and Company Identification
Hazard Label No label required
Company Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA

Trade Names: JM EPDM Peel & Stick Walkway Pad

Section 2 - Hazards Identification
Emergency Overview
Under normal conditions of use and handling, this product is not expected to create any health or safety hazards.
Inhalation
Not expected under normal conditions of use.
Skin
Not expected under normal conditions of use.
Ingestion
Not expected under normal conditions of use.
Eyes
Not expected under normal conditions of use.
Section 3 - Composition/Information on Ingredients
CAS # Component Percent
9006-04-6 Rubber 26-30
Not Available Synthetic Rubber Blend 26-30
1333-86-4 Carbon black (bound) 18-21
Not Available Nylon or Polyester Fiber 8-10
64742-04-7 Extracts, petroleum, heavy paraffinic distillate solvent 3-4
64742-11-6 Extracts, petroleum, heavy naphthenic 3-4
1314-13-2 Zinc oxide 2-3
Not Available Non-hazardous tape ingredients 1-2
7704-34-9 Sulfur compounds 1-2

General Product Description
Black, pliable solid; rubber odor.
Section 4 - First Aid Measures
First Aid: Inhalation
None required
First Aid: Skin
None required
First Aid: Ingestion
None required
First Aid: Eyes
None required
Section 5 - Fire Fighting Measures
Flash Point: Not determined Method Used: Not determined
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion.

____________________________________________________________
Page 1 of 5 Issue Date: 08/04/2008 Revision: 1.0000
Material Name: JM EPDM Peel & Stick Walkway Pad Safety Data Sheet
ID: 3151

Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Clean-Up Procedures
Pick up large pieces. Vacuum dusts.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in
accordance with good industrial hygiene and safety practices.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept clean, dry, and in original
packaging.
Section 8 - Exposure Controls / Personal Protection
A: Component Exposure Limits
Rubber (9006-04-6)
ACGIH: 0.0001 mg/m3 TWA (inhalable fraction, as inhalable allergenic proteins)
Skin - potential significant contribution to overall exposure by the cutaneous route

Carbon black (bound) (1333-86-4)
OSHA: 3.5 mg/m3 TWA
3.5 mg/m3 TWA
ACGIH: 3.5 mg/m3 TWA

Zinc oxide (1314-13-2)
OSHA: 5 mg/m3 TWA (fume); 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
5 mg/m3 TWA (fume); 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
ACGIH: 2 mg/m3 TWA (respirable fraction)
10 mg/m3 STEL (respirable fraction)

PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with side shields are recommended to keep dust out of the eyes.
Personal Protective Equipment: Skin
Leather or cotton gloves should be worn to protect against mechanical abrasion. See also Personal Protective Equipment:
General, below.
Personal Protective Equipment: Respiratory
None required
Ventilation
None required
Personal Protective Equipment: General
Protective equipment should be provided as necessary to prevent irritation of the throat, eyes, and skin, and to keep
exposures below the applicable exposure limits identified in Section 8.

Section 9 - Physical & Chemical Properties
Appearance: Odor:
Black pliable solid, various sizes. Rubber
Physical State: pH:
Solid Not applicable
Vapor Pressure: Vapor Density:
Not applicable Not applicable
Boiling Point: Melting Point:
Not determined Not determined
Solubility (H2O): Specific Gravity:
Insoluble 0.88
Evaporation Rate: Viscosity:
Not applicable Not applicable
Percent Volatile: VOC:
0 3-4%



____________________________________________________________
Page 2 of 5 Issue Date: 08/04/2008 Revision: 1.0000
Material Name: JM EPDM Peel & Stick Walkway Pad Safety Data Sheet
ID: 3151

Section 10 - Stability & Reactivity Information
Stability
These products are not reactive.
Hazardous Decomposition
May form carbon dioxide and carbon monoxide.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
If dust evolves from this product during use it may cause temporary mechanical irritation or scratchiness of the throat and/or
itching of the eyes and skin.
B: Component Analysis - LD50/LC50
Carbon black (bound) (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit:>3 g/kg

Extracts, petroleum, heavy naphthenic (64742-11-6)
Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit:>2000 mg/kg

Extracts, petroleum, heavy paraffinic distillate solvent (64742-04-7)
Oral LD50 Rat: >2000 mg/kg; Dermal LD50 Rabbit:>2000 mg/kg

Zinc oxide (1314-13-2)
Oral LD50 Rat: >5000 mg/kg

Sulfur compounds (7704-34-9)
Inhalation LC50 Rat: >9.23 mg/L/4H; Oral LD50 Rat:>3000 mg/kg; Dermal LD50 Rabbit:>2000 mg/kg

Component Carcinogenicity
Carbon black (bound) (1333-86-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B 鈥? Possibly Carcinogenic to Humans (IARC Monograph 93 [in preparation], Monograph
65 [1996])

Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Carbon black (bound) (1333-86-4)
24 Hr EC50 Daphnia magna: >5600 mg/L

Extracts, petroleum, heavy naphthenic (64742-11-6)
16 Hr EC50 Pseudomonas putida: >1000 mg/L
48 Hr EC50 Daphnia magna: 1.4 mg/L

Extracts, petroleum, heavy paraffinic distillate solvent (64742-04-7)
16 Hr EC50 Pseudomonas putida: >1000 mg/L
48 Hr EC50 Daphnia magna: 1.4 mg/L

Sulfur compounds (7704-34-9)
96 Hr LC50 Brachydanio rerio: 866 mg/L [static]




____________________________________________________________
Page 3 of 5 Issue Date: 08/04/2008 Revision: 1.0000
Material Name: JM EPDM Peel & Stick Walkway Pad Safety Data Sheet
ID: 3151

Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Waste should be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of
hazardous wastes.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transport Information
International Transport Regulations
These products are not classified as dangerous goods according to international transport regulations.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR
372.65), or CERCLA (40 CFR 302.4).
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Carbon black (bound) 1333-86-4 Yes No Yes Yes Yes Yes
Extracts, petroleum, heavy naphthenic 64742-11-6 No No Yes No No No
Extracts, petroleum, heavy paraffinic distillate solvent 64742-04-7 No No Yes No No No
Zinc oxide 1314-13-2 Yes No Yes Yes Yes Yes
Sulfur compounds 7704-34-9 Yes No Yes No Yes Yes

TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.

None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
International Regulations
A: General Product Information
These products are considered articles under both U.S. and international product regulations and as such, these products do
not require registration or notification on the various country-specific inventories.
B: Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Carbon black (bound) 1333-86-4 1%
Zinc oxide 1314-13-2 1%

WHMIS Classification
This is not a WHMIS controlled product. This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations. This SDS contains all the information required by the Controlled Products Regulations.

Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems
____________________________________________________________
Page 4 of 5 Issue Date: 08/04/2008 Revision: 1.0000
Material Name: JM EPDM Peel & Stick Walkway Pad Safety Data Sheet
ID: 3151

P. O. Box 5108
Denver, CO USA 80217-5108

Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005

The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.

Date MSDS # Reason
01/30/07 3151-1.0000 New MSDS for products from new vendor.
08/04/08 3151-1.0001 Moved JM EPDM Walkway Pad to SDS 3167. Updated SDS to
GHS format.



End of Sheet 3151




____________________________________________________________
Page 5 of 5 Issue Date: 08/04/2008 Revision: 1.0000

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