Material Safety Data Sheet (MSDS) Kerox Pigments
Complies with OSHA 29 CFR 1910.120
Section I - Product Identification
Manufacturers/Distributors Name : Date Prepared : May 04, 1996 Last Update : June 08, 2004
Kerox Chemicals Pvt. Ltd.
Address : Kerox Chemicals Pvt. Ltd. Emergency Phone # : (+91-80) 2842-9532 / 9774 / 9775
No. 95, Basavanapura, Bannerghatta Road
Email : keroxoffice@kerox.org Web : www.kerox.org
Bangalore 鈥? 560 083, INDIA
General Chemical Name : Polyester Pigment Concentrate
Product (Trade) Name : Kerox鈩? Pigments
NFPA Classification : 4 = Extreme, 3 = High, 2 = Moderate, 1 = Slight, 0 = Insignificant
Health : 0 Fire : 1 Reactivity : 0 Other : None
Section II - Ingredients and Identity Information
Exposure Limits
Chemical / Common Name %Weight PEL (ppm) TLV (ppm) CAS #
Polyester Non-Styrenated Resin (Unsaturated) 30 - 60 % N/A N/A
See Page 3
Inorganic/Organic Pigment powder 65 - 25 % N/A N/A
(Some end products are Lead and Chromium Free
and some contain Lead and Chromium compounds)
Proprietary stabilizers & thickeners (non-hazardous) 5 - 15 % N/A N/A NA
Section III - Physical Data
o
N/A 1.4 - 1.9
Boiling Point ( C) Specific Gravity
N/A (No appreciable vapor present) Negligible (Less than 1 %)
Vapor Density % Volatility by Weight
N/A N/A
Evaporation Rate Odor
Section IV - Fire and Explosion Hazard Data
Flash Point (o C) : N/A Flammability : The material is not flammable (known safe up to 250o C).
LEL : N/A
Extinguishing Media :
Use carbon dioxide or dry chemical extinguishers for small fires, and foam for large fires. Water spray may be
used for fire extinguishing. In general, any Class B fire extinguishing agent may be used.
Unusual Fire & Explosion Hazards :
Material is combustible, but not flammable. Elevated temperatures (above 300oC) can cause rapid volatilization of
the polyester resin, which may ignite if air/oxygen is present. Thermal polymerization is also possible. Avoid
using open flames, such as from welding or cutting torches, on or near pigment containers.
Special Fire Fighting Procedures :
Cool pigment containers with water spray. Emergency personnel, firefighters, and anyone who may be exposed to
vapors or products of combustion, should wear a Self Contained Breathing Apparatus (SCBA).
Technical Document : # P-MSDS-2004 Page # 1 of 3
Material Safety Data Sheet (MSDS) Kerox Pigments
Complies with OSHA 29 CFR 1910.120
Section V - Health Hazard Information
Permissible Exposure Limits:
The pigments contain dry powders dispersed in a polyester resin matrix. The OSHA PEL's listed in Section II
refer to the dry pigment powders, when used in the dry form. The PEL's, therefore, strictly refer to the dry
pigment as a 'nuisance dust'. In the dispersed form, the PEL's are much higher. The PEL for the polyester resin is
much higher than that for the dry pigments, and are not listed here.
Potential Effects of Overexposure:
Eyes :
Prolonged exposure may cause irritation, redness, or tearing.
Skin :
Prolonged or repeated contact may result in slight skin irritation and dryness.
Inhalation :
Prolonged inhalation of volatile materials in the product may cause mucous membrane irritation and upper
respiratory discomfort. It may also result in headaches and nausea.
Ingestion :
Ingestion of the product can result in gastrointestinal disturbances, pain and discomfort.
First Aid Guidelines : See a doctor promptly after first aid procedure is performed.
Skin :
If the product gets on the skin, thoroughly wash exposed area with soap and water. Remove contaminated
clothing, and either discard or thoroughly launder before reuse.
Eyes :
Thoroughly wash the eyes in a running stream of water for a minimum of 15 minutes. Seek medical aid.
Inhalation :
Remove victim from the exposure area, to an open area with fresh air. If the person is unconscious, administer
artificial respiration and/or oxygen. Seek professional medical help immediately.
Ingestion :
Seek professional medical help immediately. Do not induce vomiting, as this may be a breathing hazard.
Primary Routes of Entry :
Inhalation and / or skin absorption.
Section VI - Reactivity Data
Stability :
Stable
Hazardous Polymerization :
Will not occur.
Conditions to Avoid :
Excessive heat and prolonged exposure to direct sunlight. Store product in a cool place.
Incompatibility :
Strong oxidizing agents, acids, and peroxides (except in small quantities while curing).
Hazardous Decomposition Products :
Thermal decomposition may generate carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, and / or
organic acids.
Technical Document : # P-MSDS-2004 Page # 2 of 3
Material Safety Data Sheet (MSDS) Kerox Pigments
Complies with OSHA 29 CFR 1910.120
Section VII - Spill or Leak Procedures
Response to Spills and Release :
Since the product is a thick paste it will flow very slowly. Taking care not to contact any material, gently turn the
container upright, to prevent further product leakage. Move the container to a secondary contained area, or place it
on top of a plastic sheet. Take a scooping knife or a shovel, and remove all the material from the contaminated
area, and transfer to a disposal plastic bag. If the spill is on open ground, scoop all soil that shows visible traces of
the colored product, and transfer to the disposal bag. If the spill is on a room floor, desk, or table, wipe final traces
of visible colored pigment with a soap solution or isopropyl alcohol, and transfer the wipe cloth/paper to the
disposal bag. If the spills are large, dike the entire area around the spill, so as to prevent any material transfer to
water streams, systems, or sewers.
Waste Disposal Methods :
鈥? Recycle and reuse, if possible.
鈥? Covert the waste pigment to a solid product by mixing with resin and catalyzing, the same way as if it were
being used as a raw material. The stabilized solid product, can be either used for practical purposes, or
disposed off to an EPA approved facility.
鈥? Incinerate product at an EPA approved incineration facility.
鈥? Dispose to an EPA approved landfill, complying with the relevant Federal and State regulations, DOT
regulations, and manifesting requirements.
Section VIII - Special Protection Information
Protective Garments : Wear plastic gloves, shoes, and an apron while handling the product.
Respiratory Protection : Use the product in a well ventilated area, requires no special respiratory protective equipment.
However, a NIOSH approved half face respiratory protective equipment, may be used, and is recommended.
Ventilation : Use product in a well ventilated open area, and / or in an area with adequate mechanical (general and / or
local exhaust) ventilation.
Eye protection : Wear chemical safety goggles.
Section X - Special Precautions
Under any circumstances do not bring the product in contact with skin, eyes, and / or inhale and / or ingest product. Store
product in a cool, well ventilated area, and keep the containers always closed during storage. Do not keep the product near
an open flame, or a source of heat.
CAS # : Lead and Chromium free pigments have the following CAS #鈥檚: 12259-21-1, 1309-37-1, 1317-61-9, 1328-53-6,
1333-86-4, 13463-67-7, 164-14-8, 2425-85-6, 5567-15-7, 57455-37-5, 6358-30-1.
Lead and Chromium compounds based pigments have the following CAS #鈥檚: 1344-37-2, 12656-85-8.
Disclaimer of Liability : The information in this brochure has been prepared by Kerox Chemicals Pvt. Ltd.., using careful
analysis, and is to the best of our knowledge accurate and prepared in good faith. Kerox makes no representation that all
the information in this MSDS is accurate and complete, though we believe that we have strived to achieve this. As the
conditions of use are beyond our control, Kerox does not assume any responsibility and expressly disclaim any liability for
any use of the pigment product. Conforms to USA, OSHA 174, Sept. 1985.
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