Material Name: Superseal庐 Edge Treatment Material Safety Data
Sheet ID: 2014
Section 1 - Chemical Product and Company Identification
Product Name Superseal庐 Edge Treatment
CAS# Mixture/None Assigned
Generic Name Coatings (Acrylic)
Formula Mixture
Chemical Name: Acrylic Emulsion
Hazard Label SS-001
Manufacturer Information
Johns Manville Insulations Group Telephone: 303-978-2000
Commercial and Industrial Division Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec)
Denver, CO 80127 USA
Trade Names: Superseal庐 Edge Treatment; Superseal庐 HV
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
Not Available Acrylic emulsion 80-90
1163-19-5 Decabromodiphenyl oxide 1-10
1309-64-4 Antimony trioxide 1-5
7664-41-7 Ammonia <0.5*
Additional Component Information
* Ammonia is used to adjust the pH.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: SuperSeal Edge Treatment is a black water dispersion with slight ammonia odor.
SuperSeal HV is a black paste with slight ammonia odor.
Under normal conditions of use and handling, this product is not expected to create any health or safety hazards.
Potential Health Effects
Summary
Due to the form of the product hazardous exposures are unlikely to occur. Exposure may cause slight temporary irritation to
skin, eyes, nose, or throat.
Inhalation
Temporary irritation of nose and throat may occur.
Skin
Temporary irritation (itching) or redness may occur.
Absorption
Not applicable
Ingestion
This product is not intended to be ingested or eaten under normal conditions of use. If ingested, it may cause nausea and
systemic poisoning.
Eyes
Temporary irritation (itching) or redness may occur.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
Target Organs
Upper respiratory passages, skin, and eyes.
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Material Name: Superseal庐 Edge Treatment Material Safety Data
Sheet ID: 2014
Medical Conditions Aggravated by Exposure
None identified.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
Remove contaminated clothing. Wash exposed skin with soap and cold water. Launder contaminated clothing before reusing.
First Aid: Ingestion
This product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting. Drink plenty of water.
Contact a physician immediately.
First Aid: Eyes
Flush eyes with large amounts of water for 5-20 minutes. Contact a medical professional.
First Aid: Notes to Physician
Treat symptomatically. Emesis may be indicated in recent (within 30 minutes) ingestion of large quantities.
Section 5 - Fire Fighting Measures
Flash Point: Nonflammable Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion.
Extinguishing Media
NA
Fire Fighting Equipment/Instructions
Product as supplied is water based and will not burn.
Section 6 - Accidental Release Measures
Containment Procedures
Dam, mop, absorb onto sawdust, and place in suitable container. Prevent entry of material into sewers or other water
sources. Material causes permanent stains.
Clean-Up Procedures
No additional information available.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Store at temperatures between 4掳-35掳C/40掳-95掳F.
Storage Procedures
Do not freeze.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
No information available for the product.
B: Component Exposure Limits
Ammonia (7664-41-7)
ACGIH: 25 ppm TWA
35 ppm STEL
OSHA: 35 ppm STEL; 27 mg/m3 STEL
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields, chemical goggles, or face mask recommended.
Personal Protective Equipment: Skin
Use impervious gloves.
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Page 2 of 6 Issue Date: 01/15/2007 Revision: 1.0203
Material Name: Superseal庐 Edge Treatment Material Safety Data
Sheet ID: 2014
Personal Protective Equipment: Respiratory
Respiratory protection is not required if mechanical or dilution ventilation is sufficient to keep the exposure levels below the
applicable exposure limits.
Ventilation
Local exhaust or general dilution ventilation should be provided to keep exposure levels below the applicable exposure limits.
Personal Protective Equipment: General
An apron or coveralls impervious to chemicals can be used to protect clothing. Wash exposed skin after contact, before breaks
and meals, and at end of work period.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Black water dispersion or black paste. Slight ammonia odor
Physical State: pH:
Liquid or Paste 8-11
Vapor Pressure: Vapor Density:
17 mm Hg (approximate) Not applicable
Boiling Point: Melting Point:
100潞C/212潞F
Solubility (H2O): Specific Gravity:
Dispersible Not determined
Freezing Point: Evaporation Rate:
Not determined Same as water
Bulk Density: Percent Volatile:
10.0-13.0 lbs/gallon @ 77潞F 25-32%
VOC: 1.198 g/L
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Keep away from excess heat. Do not freeze.
Incompatibility
Cationic chemicals and mineral acids.
Hazardous Decomposition
Dried films forced to burn will produce carbon monoxide, carbon dioxide, smoke, antimony halides, and hydrogen bromide.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Skin, eye, and upper respiratory irritation may occur after contact with product.
B: Component Analysis - LD50/LC50
Decabromodiphenyl oxide (1163-19-5)
Inhalation LC50 Rat: >48.2 mg/L/1H; Oral LD50 Rat: >2000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Antimony trioxide (1309-64-4)
Oral LD50 Rat: >34600 mg/kg
Ammonia (7664-41-7)
Inhalation LC50 Rat: 5.1 mg/L/1H; Inhalation LC50 Rat: 2000 ppm/4H; Oral LD50 Rat: 350 mg/kg
Carcinogenicity
A: General Product Information
According to the International Agency for Research on Cancer (IARC), Monograph, Volume 47, antimony trioxide is classified
as a Group 2B chemical agent: possibly carcinogenic to humans. The Monograph states that benign and malignant lung
tumors have been seen in rats exposed to concentrations of antimony trioxide of 4.2 and 45 mg/m3. No lung tumors were
reported in rats exposed to 1.6 mg/m3. However, there is inadequate evidence of the carcinogenicity of antimony trioxide in
humans.
B: Component Carcinogenicity
Decabromodiphenyl oxide (1163-19-5)
IARC: Group 3 - Not Classifiable (IARC Monograph 71 [1999] Monograph 48 [1990])
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Material Name: Superseal庐 Edge Treatment Material Safety Data
Sheet ID: 2014
Antimony trioxide (1309-64-4)
ACGIH: A2 - Suspected Human Carcinogen (production)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 47 [1989])
Chronic Toxicity
None known.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No additional information available.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Decabromodiphenyl oxide (1163-19-5)
72 Hr EC50 Skeletonema costatum: >1 mg/L
Antimony trioxide (1309-64-4)
96 Hr LC50 Pimephales promelas: 833.0 mg/L; 96 Hr LC50 Lepomis macrochirus: 530 mg/L; 96 Hr LC50 Brachydanio rerio:
>1000 mg/L [static]
72 Hr EC50 Selenastrum capricornutum: 67 mg/L
7 Hr EC50 Pseudomonas putida: >3.5 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L
Ammonia (7664-41-7)
96 Hr LC50 Cyprinus carpio: 1.1 mg/L; 96 Hr LC50 Lepomis macrochirus: 0.26-4.6 mg/L; 96 Hr LC50 Pimephales promelas:
0.73-2.35 mg/L; 96 Hr LC50 Poecilia reticulata: >1.5 mg/L
5 min EC50 Photobacterium phosphoreum: 2.0 mg/L (15 掳C)
48 Hr EC50 Daphnia magna: 25.4 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
Shipping Name: This product is not classified as a hazardous material for transport.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Decabromodiphenyl oxide (1163-19-5)
SARA 313: 1.0 % de minimis concentration
Antimony trioxide (1309-64-4)
CERCLA: 1000 lb final RQ; 454 kg final RQ
Ammonia (7664-41-7)
SARA 302: 500 lb TPQ
CERCLA: 100 lb final RQ; 45.4 kg final RQ
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Page 4 of 6 Issue Date: 01/15/2007 Revision: 1.0203
Material Name: Superseal庐 Edge Treatment Material Safety Data
Sheet ID: 2014
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Decabromodiphenyl oxide 1163-19-5 No No Yes Yes Yes Yes
Antimony trioxide 1309-64-4 Yes No Yes Yes Yes Yes
Ammonia 7664-41-7 Yes No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Antimony trioxide CAS# 1309-64-4
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
The following components listed in this product are listed on the TSCA Export Notification 12(b) list.
TSCA 12(b)
Component CAS TSCA 12 (b)
Decabromodiphenyl oxide 1163-19-5 Yes
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Decabromodiphenyl oxide 1163-19-5 Yes Yes Yes
Antimony trioxide 1309-64-4 Yes Yes Yes
Ammonia 7664-41-7 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Antimony trioxide 1309-64-4 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville Insulations Group
Commercial & Industrial Division
P.O. Box 5108
Denver, CO 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
08/01/00 2014-1.0000 New MSDS authoring system.
10/14/02 2014-1.0100 Update Sect. 15 for TSCA 12B: Tetrahydrofuran has been delisted.
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Page 5 of 6 Issue Date: 01/15/2007 Revision: 1.0203
Material Name: Superseal庐 Edge Treatment Material Safety Data
Sheet ID: 2014
10/22/03 2014-1.0101 Section 15, TSCA 12b, add decabromodiphenyl oxide; Update
Section 15, State data, Antimony Trioxide and Ammonia.
02/09/05 2014-1.0102 Minor edits throughout MSDS. VOC data entered in section 9.
11/30/05 2014-1.0202 Regulatory update. Minor edits in Section 11 LD50 and Section 15
WHMIS.
01/15/07 2014-1.0203 Minor edits throughout.
This is the end of MSDS # 2014
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