ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
TRIOCIDE庐 525 EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. CHEMICAL IDENTIFICATION
TRIOCIDE庐 525EC
Product Name:
Aryloxyalkanoic acid
Chemical Class:
Use: Triocide庐525EC is used for post-emergence control of broad-leaved weeds
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel # (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Proportions
Substance (% w/w ) Chemical structure
Mecoprop
CH3
CAS No. 7085-19-0
Cl OCHCO2H
Chemical name: (RS)-2-(4-chloro-o-tolyloxy) 55.30
propionic acid
CH3
EC Hazard Xn, R22, Xi, R38, R41, R20/21/22.
S2, S13, S20/21, S26, S46.
Bromoxynil CN
CAS No. 1689-99-2
7.26
Chemical name: 2,6-dibromo-4-cyanophenyl
Br
Br
Octanoate
OH
EC Hazard R63, Xn, R21/22
Ioxynil CN
CAS No. 3861-47-0
7.15
Chemical name: 4-cyano-2,6-di-iodophenyl
Octanoate I I
OH
EC Hazard R63, Xn, R22
Blend of anionic and nonionic surfactants 6.54
Organic Solvent 23.,75
TRIOCIDE 525EC / HERBICIDE
MSDS: 1/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
EC Hazard:
Xn: Harmful
R22 Harmful if swallowed
Xi: Irritant
R38 Irritating to skin
R63: Possible risk of harm to the unborn child.
R41 Risk of serious damage to eyes
R20/21/22 Harmful by inhalation, in contact with skin and if
swallowed
S2 Keep out of reach of children
S13: Keep away from food, drink and animal feeding stuffs.
S20/21: when using do not eat, drink or smoke.
S26: In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
S46: if swallowed, seek medical advice immediately and
show this container or label.
3. HAZARD IDENTIFICATION
Harmful if swallowed
Irritating to skin
Risk of serious damage to eyes
Signs of Poisoning:
Symptoms of acute over exposure include headaches, fatigue, nausea and
vomitting from solvent.
Effects of Single Exposures:
Ingestion:
The active ingredient presents a hazard whilst excessive prolonged
exposure may cause chronic effects.
Eye:
Prolonged contact of the eye with the concentrate may cause irritation.
Skin:
The concentrate may irritate the skin. Prolonged or repeated exposure to
the solvent may cause deflate of the skin which could lead to secondary
dermatitis.
Inhaled:
A moderate hazard when handling the concentrate, but care should be
taken to avoid inhalation of spray mists.
TRIOCIDE 525EC / HERBICIDE
MSDS: 2/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Chronic Effect:
Chronic over Exposure: Weight loss and damage to liver and kidneys may
be expected if exposure is excessive over a period of time.
4. FIRST AID MEASURES
FIRST AID
Swallowed:
Do not induce vomiting. Rinse mouth with water. Keep patient warm and
rested. Seek medical attention immediately.
If swallowed, and if more than ten minutes away from a hospital, induce
vomiting, vomiting should be supervised by a physician.
Eye:
Immediately irrigate with copious quantity of water for at least 15 minutes.
Eyelids to be held open. Get medical attention.
Skin:
Remove contaminated clothing and launder before re-use. Wash affected
area thoroughly with soap and water. Seek medical attention.
Inhaled:
Remove patient to fresh air until recovered. Give artificial resuscitation if
breathing has stopped. Seek medical attention immediately.
First Aid Facilities
Advice to Doctor:
Following ingestion, there is burning of the oral mucosa, hyper salivation,
stomach cramps, vomiting & diarrhea. Other reported symptoms include
convulsions, cerebral depression and mental confusion, with difficulty in
speaking. A short period of myotonia is followed by muscular weakness, a
general reduction in motor activity, ataxia and in co ordination and gradual
loss of reflexes. In severe cases coma may develop, followed by death. The
pulse may be rapid and sometimes irregular with a low blood pressure.
Ventricular fibrillation has been reported.
Kidney & liver damage have been reported in animal experiments but not so
far in man.
The only known cases of Phenoxyacid poisoning are those from deliberate
ingestion and no poisoning arising occupationally has ever been verified.
No antidote is available and treatment should be symptomatic. Gastric
lavage with medical charcoal in water is recommended.
5. FIRE FIGHTING MEASURES
Suitable Extinguisher:
Water 鈥? Take measures to avoid water entering drains or water courses.
TRIOCIDE 525EC / HERBICIDE
MSDS: 3/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Carbon dioxide.
Alcohol resistant foam.
Dry powder
Unsuitable Extinguisher:
None known
Special Exposure Hazards:
Dangerous, Toxic fumes may be given off (HCl, Cl2, CO)
Protective equipment:
Proactive equipment and breathing apparatus
Fire and Explosion:
Flammable
Flash point : >35 C
Thermal decomposition products may include, but not limited to, toxic fumes
of hydrogen bromide, hydrogen cyanide or other compounds of bromine and
nitrogen if involved in fires or exposed to extreme heat.
Fire Fighting Measures:
In case of fire use dry chemical, foam or CO2 extinguishing media. Wear
full protective clothing and self-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
Personnel Precautions:
Avoid contact with skin, wear personnel protective equipment.
Environmental Precautions:
Do not allow to enter drains or water courses. Advice relevant authorities in
case of contamination of public waters.
Methods of Cleaning:
Collect contaminated material in heavy duty plastic bags or drums. Dispose
of through a reputable waste disposal contractor.
Inform the local water Service Company and national Rivers Authority
immediately if spillage enters drains or water courses.
Spill or Leak:
In case of spill or leak cover the spill with an absorbent (non-combustible
material such as sand or earth) for disposal. Wash the spill area with water
containing detergent and flush with water and remove any residues. Prevent
spilled material from entering drains waterways and sewers.
TRIOCIDE 525EC / HERBICIDE
MSDS: 4/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
7. HANDLING AND STORAGE
Store the product in original tightly closed containers in a well-ventilated,
secure area out of reach of children and domestic animals. Do not use or
store near heat or open flame. Do not store food or feed in storage area.
Prevent eating, drinking or smoking in areas where there is a potential
exposure to the product. Wash hands before eating, drinking or smoking
after using the product.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Take Measures to Prevent:
Avoid contact with skin, eyes and clothing. Avoid dust formation.
Exposure Control Limits & Sources:
This chemical has not been assigned an occupational exposure standard
(OES) inEH/40. it is recommended that exposure levels of 10 mg/m3 (8 hour
TWA reference period) and 20 mg/m3 (10 minute reference period) are used
for this material which are those assigned to a similar chemical.
Concentrations at or above these levels are defined as substantial
concentrations and therefore substances hazardous to health within the
meaning of regulation 2(1) in the COSHH regulations.
Exposure Standards:
No exposure standards have been set for this product. The manufacturer of
the solvent has recommended a TLV of 100 ppm for the solvent. Natural
ventilation only is required under normal circumstances of use.
Engineering Controls:
Local exhaust should be provided if material is handled in confined spaces
to minimize exposure to solvent vapors.
Personnel Protection:
May irritate the eye and skin. Avoid contact with eyes and skin. DO NOT
inhale spray mist. When preparing spray and using the prepared spray,
wear cotton overalls buttoned to the neck and wrist and washable hat,
elbow-length PVC gloves and face sheild. After use and before eating,
drinking or smoking, wash hands, arms and face thoroughly with soap and
water. After each day鈥檚 use, wash gloves, face shield and contaminated
clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear Yellow Liquid free of visible impurities
Water Content <5.0 g/Kg
Density 1.0167 鈥? 1.1367 Kg/L
Flash Point >35 C
TRIOCIDE 525EC / HERBICIDE
MSDS: 5/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Acidity as H2SO4 < 5.0 g/Kg
10. STABILITY AND REACTIVITY
Reactivity:
Stability: Stable under normal conditions.
Conditions to avoid: Exposure to strong oxidizers. Avoid contact with
chlorine and in organic Peroxides
Hazardous Polymerization Will not occur
Materials to avoid: Corrosive to iron and aluminium.
Hazardous Decomposition products: HCl, Cl2, CO may be developing with
heating.
11. TOXICOLOGICAL INFORMATION
Active ingredients:
Mecoprop Technical:
Acute oral LD50 (rats) 930-1166 mg/Kg
Acute dermal LD50 >4000 mg/Kg
Bromoxynil Octanoate:
Acute oral LD50 (rats) 365 mg/Kg
Acute dermal LD50 >2000 mg/Kg
Ioxynil Octanoate:
Acute oral LD50 (rats) 190 mg/Kg
Acute dermal LD50 >912 mg/Kg
12. ECOLOGICAL INFORMATION
Dangerous to fish and other aquatic life. Do not contaminate surface water
or ditches with this product or used containers. Not toxic to bees.
Biological Degradability:
Readily biodegradable according to the appropriate OECD test DT50 8 鈥? 14
days.
Field data
No bioaccumulation.
Bees Toxicity:
Not Toxic to Bees
The Acceptable Daily Intake (ADI) of Bromoxynil for a human is
0.003mg/Kg/day, set for the public for daily, lifetime exposure. This is based
on the NOEL of 0.3 mg/Kg/day, the level determined to show no effects
during long term exposure for the most sensitive indicators and the most
sensitive species.
TRIOCIDE 525EC / HERBICIDE
MSDS: 6/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
13. DISPOSAL CONSIDERATION
Pesticide wastes are toxic. Do not reuse product containers. Dispose of
product containers, waste containers and residues according to local health
and environmental regulations.
Safe Handling of Residues / waste:
Dispose of safely in accordance with the control of Pollution Act, 1974 and
regulations made there under.
14. TRANSPORT INFORMATION
UN. No: UN 2903
Proper Shipping name: Pesticide, Liquid, toxic, Flammable, N.O.S, flash
point 鈮?23掳C
(Mecoprop + Bromoxynil Octanoate + Ioxynil
Octanoate)
Class: 6.1
Classification Code: TF2
Packing group: III
Subsidiary Risks: 6.1 +3
Special provisions: 61
Limited quantities: LQ19
Packaging: Packing instructions P001
IBC03
R001
Special packing provisions
Mixed Packaging Provisions MP15
Instructions T7
UN Portable tanks: Special Provisions TP2
Tank Code L4BH
ADR Tank: Special Provision TU15 TE1 TE15 TE19
Vehicle for tank carriage FL
Transport Catogery 2
Special provision carriage: Packages
Bulk
Loading, unloading & CV13 CV28
Handling
Operation S2 S9
Hazard Identification 63
TRIOCIDE 525EC / HERBICIDE
MSDS: 7/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
15. REGULATORY INFORMATION
Toxicity Class WHO (a.i) II
EPA (formulation) II
Label info: Classification according to EEC directives.
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in accordance with
the product label instructions.
TRIOCIDE 525EC / HERBICIDE
MSDS: 8/8
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