Granular
MATERIAL SAFETY DATA SHEET
1. PRODUCT AND COMPANY IDENTIFICATION 5. FIRE-FIGHTING MEASURES
PRODUCT NAME: T-Methyl E-Pro Granular Fungicide Flash Point (Method): Not flammable
Active Ingredient: Thiophanate-methyl
Flammable Limits: N/A
Chemical Formula: C12H14N4O4S2
Product Description: Granular systemic fungicide for Fire and Explosion Hazard: None
ornamental plants and turf.
Means of Extinguishing: Use means suitable for extin-
COMPANY IDENTIFICATION: guishing surrounding fire.
Etigra
Fire-Fighting Instructions: Wear NIOSH approved self-
501 Cascade Pointe Lane, Suite 103
contained breathing apparatus with full-facepiece operated
Cary, NC 27513
in the pressure/demand mode.
www.etigra.com
Hazardous Combustion Products: Toxic oxides of carbon,
2. COMPOSITION/INFORMATION ON INGREDIENTS sulfur and nitrogen.
Thiophanate-methyl CAS No. 23564-05-8 2.08% NFPA Codes: Health: 1 Fire: 0 Reactivity: 0
Other Ingredients 97.92%
6. ACCIDENTAL RELEASE MEASURES
3. HAZARD IDENTIFICATION
Sweep up and dispose of in compliance with all Federal,
state and local laws.
EMERGENCY OVERVIEW
Causes moderate eye irritation. Avoid contact with eyes
7. HANDLING AND STORAGE
or clothing. Wash thoroughly with soap and water after
handling and before eating, drinking, chewing gum, or
HANDLING: Wash hands before eating, drinking, chewing
using tobacco.
gum, using tobacco or using toilet. Remove clothing
immediately if pesticide gets inside. Then wash thor-
POTENTIAL HEALTH EFFECTS:
oughly and put on clean clothing. Remove PPE immedi-
EYES: May cause transient eye irritation.
ately after handling this product. Wash the outside of
SKIN: Non-irritating
gloves before removing.
INHALATION: Excessive inhalation of dust may cause irri-
tation and coughing.
STORAGE: Store in original container in a dry, tempera-
CHRONIC: Irritation of eyes, nose and throat, dermatitis,
ture controlled area. Do not store in a manner where
headache and nausea.
cross-contamination with other pesticides, fertilizers,
food or feed could occur.
4. FIRST AID
OSHA PEL: None
IF IN EYES: Hold eye open and rinse slowly and gently with
ACGIH TLV: None
water for 15-20 minutes. Remove contact lenses, if present,
after the first 5 minutes, then continue rinsing eye. Call a
poison control center or doctor for treatment advice.
Etigra
Manufactured for: Emergency Phone: Chemtrec 800-424-9300
Etigra Effective Date:
501 Cascade Pointe Lane, Suite 103 EPA Reg. No. 79676-18
Cary, NC 27513
www.etigra.com
REV 0506
8. EXPOSURE CONTROLS/PERSONAL PROTECTION 12. ECOLOGICAL INFORMATION
ENGINEERING CONTROLS: None required for routine ENVIRONMENTAL INFORMATION: This pesticide is toxic
outdoor use. A local exhaust system, which captures the to fish. Do not apply directly to water, or to areas where
contaminant at its source, is recommended to prevent surface water is present or to intertidal areas below the
dispersion of the contaminant into the workroom air. mean high water mark. Do not apply where runoff is like-
ly to occur. Do not contaminate water by disposing of
PERSONAL PROTECTIVE EQUIPMENT: equipment washwaters.
When preparing or applying this product, refer to the
product label for specific PPE instructions. ECOTOXICOLOGICAL INFORMATION: The following eco-
toxicity values were obtained for the active ingredient:
Eyes and Face: Chemical goggles or safety glasses with
side shields recommended. FISH TOXICITY
96 hour LC50 (Trout): 8.3 ppm
Skin: Long-sleeved shirt and long pants or coveralls,
48 hour LC50 (Daphnia): 5.4 ppm
chemical resistant (Category A) gloves, and shoes plus
96 hour LC50 (Sheepshead minnow): 17 ppm
socks.
96 hour LC50 (Mysid shrimp): 1.1 ppm
Respiratory Protection: None required for routine outdoor
use. For exposures in enclosed areas, a dust mask or AVIAN TOXICITY
OSHA approved respirator. Dietary LC50 (Mallard): > 10,000 ppm
13. DISPOSAL CONSIDERATIONS
9. PHYSICAL AND CHEMICAL PROPERTIES
NEVER PLACE UNUSED PRODUCT DOWN ANY INDOOR
Appearance: Off-white granules
OR OUTDOOR DRAIN.
Odor: Faint sulfur odor
pH: 5.11 PESTICIDE DISPOSAL: Wastes resulting from the use of
Density (Pour): 0.469 g/mL this product may be disposed of on site or at an approved
waste disposal facility.
10. STABILITY AND REACTIVITY
CONTAINER DISPOSAL: Completely empty bag into
CONDITIONS TO AVOID: Extreme heat. Contact with application equipment. Then dispose of in a sanitary
strong oxidizers, acids, bases, and salt suspensions. landfill or by incineration, or, if allowed by State and local
authorities, by burning. If burned, stay out of smoke.
CHEMICAL STABILITY: Stable
CHEMICAL INCOMPATIBILITY: Strong oxidizers, highly 14. TRANSPORT INFORMATION
alkaline materials, lime sulfur, bordeux mixture, copper
DOT HAZARD CLASS OR DIVISION: Not Regulated
compounds.
U.S. DOT PROPER SHIPPING NAME: N/A
HAZARDOUS POLYMERIZATION: Will not occur
UN NUMBER: N/A
11. TOXICOLOGICAL INFORMATION
DOT PACKING GROUP: N/A
ACUTE ORAL TOXICITY REPORTABLE QUANTITY: None
Oral LD50 (rat): > 5000 mg/kg MARINE POLLUTANT: Not listed
ACUTE DERMAL TOXICITY U.S. SURFACE FREIGHT CLASS: Agricultural Fungicides,
Dermal LD50 (rat): > 5000 mg/kg Solid, NOIBN
ACUTE INHALATION TOXICITY 15. REGULATORY INFORMATION
Inhalation LC50 (rat): > 2.11 mg/L
FIFRA 鈥?
EYE IRRITATION
All pesticides are governed under the Federal Insecticide,
Rabbit: Mildly irritating
Fungicide, and Rodenticide Act. The regulatory informa-
SKIN IRRITATION tion presented below is pertinent only when this product
Rabbit: Slightly irritating is handled outside of the normal use and application as a
pesticide.
DERMAL SENSITIZATION
Guinea pig: Not a contact sensitizer CERCLA REPORTABLE QUANTITY 鈥?
Thiophanate-methyl: 1 lb.
CARCINOGENICITY:
IARC: Not listed SARA Title III 鈥? Section 302 Extremely Hazardous
NTP: Not listed Substances
OSHA: Not listed Not listed
OTHER: (ACGIH) Not listed
SARA Title III 鈥? Section 311 Hazard Categories
Immediate
SARA Title III 鈥? Section 312 Threshold Planning Quantity DISCLAIMER:
The threshold planning quantity (TPQ) for this product Etigra believes the information and recommendations
treated as a mixture is 10,000 lbs. This product contains provided above to be accurate. NO WARRANTY OF FIT-
no ingredients with a TPQ of less than 10,000 lbs. NESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF
MERCHANTABILITY, OR ANY OTHER WARRANTY,
SARA Title III 鈥? Section 313 Reportable Ingredients
EXPRESS OR IMPLIED, IS MADE CONCERNING THE
Thiophanate-methyl (23564-05-8)
INFORMATION PROVIDED HEREIN. The information pro-
vided above relates only to the specific product designat-
CALIFORNIA PROP 65 STATUS 鈥?
ed and may not be applicable where such product is used
This product contains a chemical known to the State of
in combination with any other materials or in any
California to cause birth defects or other reproductive
process. Use of this product is regulated by the U.S.
harm.
Environmental Protection Agency (EPA). It is a violation
16. OTHER INFORMATION of Federal law to use this product in a manner inconsis-
tent with its labeling. Additionally, as the conditions and
This product has been classified in accordance with the
methods of use are beyond the control of Etigra, Etigra
hazard criteria of the Controlled Products Regulations
expressly disclaims any and all liability as to any results
(CPR) and the MSDS contains all of the information
obtained or arising from any use of the product or
required by CPR.
reliance on such information.
Etigra鈩? is a trademark of Etigra.
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