T-Methyl 70 WSP
MATERIAL SAFETY DATA SHEET
IF IN EYES: Hold eye open and rinse slowly and gently with
1. PRODUCT AND COMPANY IDENTIFICATION
water for 15-20 minutes. Remove contact lenses, if present,
PRODUCT NAME: T-Methyl E-AG 70 WSP after the first 5 minutes, then continue rinsing eye. Call a
DESCRIPTION: A fungicide in water-soluble pack- poison control center or doctor for treatment advice.
aging.
IF INHALED: Move person to fresh air. If person is not
COMPANY IDENTIFICATION: breathing, call 911 or an ambulance, then give artificial
Etigra鈩? respiration, preferably by mouth-to-mouth if possible.
501 Cascade Pointe Lane, Suite 103 Call a poison control center or doctor for treatment
Cary, NC 27513 advice.
www.etigra.com
IF SWALLOWED: Have person sip a glass of water if able
to swallow. Do not induce vomiting unless told to do so by
2. COMPOSITION/INFORMATION ON INGREDIENTS
a poison control center or doctor. Do not give anything by
Ingredient Chemical Name Formula CAS # Composition
mouth to an unconscious person. Call a poison control
Thiophanate- Dimethyl [1,2-phenylenebis C12H14N4O4S2 23564-05-8 70%
methyl (iminocarbonothioyl)]bis[carbamate]
center or doctor immediately for treatment advice.
3. HAZARD IDENTIFICATION 5. FIRE-FIGHTING MEASURES
Flash point: N/A
HAZARDS TO HUMANS AND DOMESTIC ANIMALS:
Harmful if swallowed, absorbed through skin or inhaled. Flammable Limits (LFL-UFL): N/A
Causes moderate eye irritation. Avoid contact with skin,
Fire and Explosion Hazards: None known.
eyes or clothing. Avoid breathing dust or spray mist.
Means of Extinction: Use water spray, carbon dioxide,
ENVIRONMENTAL HAZARDS: Do not apply directly to foam or dry chemical.
water, or to areas where surface water is present or to
Fire Fighting Instructions: Evacuate area. To fight larger
intertidal areas below the mean high water mark. Runoff
fires, wear full protective clothing and NIOSH approved
from treated areas may be hazardous to aquatic organ-
self-contained breathing apparatus with full-facepiece
isms in neighboring areas. Do not contaminate water
operated in the pressure/demand mode. Thoroughly
when disposing of equipment wash water.
decontaminate firefighting equipment after use.
4. FIRST AID Firefighting Equipment: Self-contained breathing appara-
tus with full face piece and full bunker gear.
IF ON SKIN OR CLOTHING: Take off contaminated cloth-
ing. Rinse skin immediately with water for 15-20 minutes. Hazardous Combustion Products: May produce irritating
Call a poison control center or doctor for treatment gasses and vapors.
advice.
Etigra
Manufactured for: Emergency Phone: Chemtrec 800-424-9300
Etigra Effective Date: February 1, 2007
501 Cascade Pointe Lane, Suite 103 EPA Reg. No. 79676-55
Cary, NC 27513
www.etigra.com
REV 0207
6. ACCIDENTAL RELEASE MEASURES 11. TOXICOLOGICAL INFORMATION
Clean up spills immediately observing the precautions in ACUTE ORAL TOXICITY
Section 8 of this MSDS. Isolate the hazard area and keep Oral LD50 (rat): >5,000 mg/kg
unnecessary and unprotected personnel from entering.
ACUTE DERMAL TOXICITY
Prevent material from contaminating soil or from enter-
Dermal LD50 (rat): >2,000 mg/kg
ing sewage and drainage systems and bodies of water.
ACUTE INHALATION TOXICITY
SMALL SPILLS: Scoop up material and place in a con-
Inhalation LC50 (rat): 1.8 mg/L
tainer for reuse or disposal. Clean contaminated floors
and objects thoroughly with water, observing all environ- EYE IRRITANT
mental regulations. Rabbit 鈥? Slightly irritating
LARGE SPILLS: Avoid creating a dust cloud and take all
SKIN IRRITATION
possible measures to reduce airborne dust. Vacuum,
Rabbit 鈥? Non-irritating
shovel or sweep up material and place in a container for
reuse or disposal. After removal, flush contaminated area SENSITIZATION
thoroughly with water, observing all environmental regu- Guinea Pig 鈥? Contact sensitizer
lations.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
None known.
7. HANDLING AND STORAGE
CARCINOGENICITY:
Do not allow to come into contact with skin, eyes and
ACGIH: Not listed
clothing. Remove and wash contaminated clothing
IARC: Not listed
before reuse. Wash thoroughly with soap and water after
NTP: Not listed
handling and before eating, drinking, chewing gum,
OSHA: Not listed
using tobacco or using the toilet.
Store in a cool, dry place and in such a manner as to pre- MUTAGENIC DATA: No evidence of mutagenic effects
vent cross contamination with other pesticides, fertilizers, during in vivo and in vitro assays.
food, and feed. Store in original container and out of the
ADDITIONAL DATA: Not known to cause reproductive or
reach of children, preferably in a secured storage area.
birth defects at normal exposure levels.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
12. ECOLOGICAL INFORMATION
Engineering Controls: Facilities storing or utilizing this
This pesticide is toxic to aquatic invertebrates and
material should be equipped with an eyewash station and
wildlife. Do not apply directly to water, or to areas where
a safety shower.
surface water is present or to intertidal areas below the
Protective Clothing: Long-sleeved shirt, long pants and mean high water mark. Drift and runoff may be haz-
shoes plus socks. When mixing/loading or handling con- ardous to aquatic organisms in neighboring areas. Do not
centrated product, wear chemical resistant gloves. contaminate water when disposing of equipment wash-
water or rinsate.
General: Wash thoroughly with soap and water after han-
dling. Discard clothing and other absorbent materials that
13. DISPOSAL CONSIDERATIONS
have been heavily contaminated with this product; do not
reuse them. Follow the manufacturer鈥檚 instructions for Do not contaminate water, food or feed by disposal.
cleaning and maintaining PPE. If no such instructions for
PESTICIDE DISPOSAL: Pesticide wastes are toxic.
washable exist, use detergent and hot water. Keep and
Improper disposal of excess pesticide, or rinsate is a vio-
wash PPE separately from other laundry.
lation of Federal Law. If these wastes cannot be disposed
of by use according to label instructions, contact your
9. PHYSICAL AND CHEMICAL PROPERTIES
State Pesticide or Environmental Control Agency, or the
Appearance: Fine light-tan powder Hazardous Waste Representative at the nearest EPA
Odor: Faint sulfur odor Regional Office for guidance.
pH: 7.49
CONTAINER DISPOSAL: Completely empty bag into appli-
Flashpoint (PMA-4): N/A cation equipment. Then dispose of empty bag in a sani-
Melting Point: 172掳C with decomposition tary landfill or by incineration, or, if allowed by state and
Solubility in Water: Insoluble local authorities, by burning. If burned, stay out of smoke.
10. STABILITY AND REACTIVITY 14. TRANSPORT INFORMATION
CONDITIONS TO AVOID: Stable under normal use and DOT PROPER SHIPPING NAME: Not regulated by DOT
transportation situations. DOT HAZARD CLASS OR DIVISION: N/A
HAZARDOUS DECOMPOSITION PRODUCTS: Data not DOT UN/NA NUMBER: N/A
available.
DOT PACKING GROUP: N/A
INCOMPATIBILITY WITH OTHER MATERIALS: Strong oxi- REPORTABLE QUANTITY: N/A
dizers.
MARINE POLLUTANT: Not listed
POLYMERIZATION: Will not occur.
DOT EMERGENCY RESPONSE GUIDE: N/A
15. REGULATORY INFORMATION
FIFRA 鈥?
All pesticides are governed under the Federal Insecticide,
Fungicide, and Rodenticide Act. The regulatory informa-
tion presented below is pertinent only when this product
is handled outside of the normal use and application as a
pesticide.
SARA Title III 鈥? Section 302 Extremely Hazardous
Substances
Not listed
SARA Title III 鈥? Section 311/312 Hazard Categories
Immediate
SARA Title III 鈥? Section 312 Threshold Planning Quantity
N/A
SARA Title III 鈥? Section 313 Reportable Ingredients
Thiophanate-methyl (23564-05-8)
CERCLA 鈥?
Thiophanate-methyl: 1 lb.
CALIFORNIA PROP 65 STATUS 鈥?
Listed (Thiophanate-methyl)
16. OTHER INFORMATION
This product has been classified in accordance with the
hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information
required by CPR.
DISCLAIMER:
Etigra believes the information and recommendations
provided above to be accurate. NO WARRANTY OF FIT-
NESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF
MERCHANTABILITY, OR ANY OTHER WARRANTY,
EXPRESS OR IMPLIED, IS MADE CONCERNING THE
INFORMATION PROVIDED HEREIN. The information pro-
vided above relates only to the specific product designat-
ed and may not be applicable where such product is used
in combination with any other materials or in any
process. Use of this product is regulated by the U.S.
Environmental Protection Agency (EPA). It is a violation
of Federal law to use this product in a manner inconsis-
tent with its labeling. Additionally, as the conditions and
methods of use are beyond the control of Etigra, Etigra
expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or
reliance on such information.
|