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HISHICOLIN PO-8 (Ver. 1. 1. ) 10/ 21/2005
MATERIAL SAFETY DATA SHEET
[ HISHICOLIN PO每 8 ]
MSDS No.: 2101060301
Established: 07/09/ 2005
Revised: 10/21/ 2005
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
每e RODU CT N AME (GRADES):
P HISHICOLIN PO-8
每e AME OF MANU F ACTU RER:
N NIPP ON CHEMICAL INDUSTRIAL CO., LTD.
每e EAD OFF ICE (ADDRESS):
H 11-1, 9-chom e, Kam eido, Koto-k u, T ok yo, 136-8515, Japan
每e AME OF SECT ION:
N Organic Chem icals Sales Dept., Organic Chem icals Division
TEL. +81-3-3636-8048, F AX. +81-3-3636-8132
每e MERGEN CY T EL EP HON E:
E Same phone num ber listed above
2. COMPOSITION/INFORMATION ON INGREDIENTS
每e U BST AN CE OR P REP ARAT ION:
S Substance
每e HEMICAL N AME (GEN ERIC N AME):
C Tri-n-octylphosphine oxide
每eN GREDIENT S AN D COMP OSIT ION:
I min 90%
每e HEMICAL FORMU L A:
C (n-C8H17)3P=O
每e AS N o.:
C 78-50-2
每e AP AN ESE OFF ICIAL GAZETT E SERIAL N o.:
J (2)-2937
每e SCA IN VENT ORY:
T Registered
每e IN ECS N o.:
E 201-121-3
每eN GREDIENT S CONT RIBU TIN G T O T HE HAZARD:
I Tri-n-octylphosphine oxide
每eNPU RIT IES CONT RIBUT IN G T O T HE HAZARD:
I None
3. HAZARDS IDENTIFICATION
每e OST IMPORT ANT HAZARDS:
M Irritant
HU MAN HEAL TH: Irritating to eyes, respiratory system and skin.
4. FIRST-AID MEASURES
每eNHAL AT ION:
I
If inhaled, remove to fresh air. Use a bag valve mask or sim ilar device to perform artificial
respiration (rescue breathing) if needed. Get m edical attention.
每e KIN CON T ACT:
S
In case of contact, immediately wash with soap or mild detergent and large amounts of water
until no evidence of chem ical rem ains (at least 15-20 minutes). Get m edical attention, if needed.
每e YE CONT ACT:
E
In case of contact, immediately rinse the eyes with plenty of water, occasionally lifting upper and
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HISHICOLIN PO-8 (Ver. 1. 1. ) 10/ 21/2005
lower lids, until no evidence of chemical remains. Get medical attention imm ediately.
每eN GESTION:
I
If vomiting occurs, k eep head lower than hips to help prevent aspiration. Get m edical attention,
if needed.
5. FIRE-FIGHTING MEASURES
每e XT IN GU ISHING MEDIA:
E
Regular dry chemical, sand, lime, soda ash
每e P ECIF IC HAZARDS:
S
May ignite spontaneously on exposure to air. In case of fire, form fum es of phosphoric acid. Do
not breathe the fum es.
每e ROT ECT ION F IRE-F IGHT ERS:
P
To avoid the harm s of fum es, use breathing equipm ent. Keep unnecessary people away,
isolate hazard area and deny entry. Let the fire burn. Do not use water. Do not use form. Move
container from fire area, if it can be done without risk. Do not attem pt to extinguish fire unless
flow of material can be stopped first. Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material of com bustion by-products. Stay upwind and keep out of low areas.
Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius:
500 meters (1/3mile). Consider downwind evacuation if material is leaking.
6. ACCIDENTAL RELEASE MEASURES
每e ERSON AL P RECAUT IONS:
P
Wear protective equipm ent. Keep unprotected person away. Ensure adequate ventilation.
每e ET HODS F OR CL EAN IN G UP:
M
Ensure adequate ventilation.
7. HANDLING AND STORAGE
每HANDLING:
e
Avoid heat, flam es, spark s and other sources of ignition. Do not touch spilled m aterial. Stop
leak if possible without personal risk.
每e T ORAGE:
S
Keep container closed. Store in a cool, dry conditions in well sealed containers.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
每EN GIN EERING MEASU RES:
e
Provide local exhaust ventilation system. Ventilation equipm ent should be explosion-resistant if
explosive concentrations of material are present. Ensure compliance with applicable exposure
limits.
每e ERSON AL P ROT ECT IVE EQU IP MENT:
P
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HISHICOLIN PO-8 (Ver. 1. 1. ) 10/ 21/2005
RESP IRAT ORY PROT ECTION:
Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum. Consider warning
properties before use. Any chemical cartridge respirator with organic vapor cartridge(s).
Any chemical cartridge expiratory with a full-face piece and organic vapor cartridge(s).
EYE P ROT ECT ION:
Wear splash resistant safety goggles with a face shield. Provide an em ergency eye wash
fountain and quick drench shower in the imm ediate work area.
SKIN AND BODY P ROT ECT ION:
Wear appropriate chemical resistant clothing and gloves.
每e YGIEN E MEASU RES:
H
Any air-purifying respirator with a full-face piece and an organic vapor canister. For Unknown
Concentrations or Immediately Dangerous to Life or Health: Any supplied-air respirator with
full-face piece and operated in a pressure dem and or other positive-pressure mode in
combination with a separate esc-ape supply. Any self-contained breathing apparatus with a full
face piece.
9. PHYSICAL AND CHEMICAL PROPERTIES
每e HYSICAL ST AT E:
P Crystalline
COL OU R: White or pale yellow
ODOR: Sweetish
每e OILING POIN T:
B 200! (13. 3P a)
每e ELT IN G P OINT:
M 54-56!
每e LASH P OINT:
F 230!
每e ECOMPOSIT ION T EMP ERATU RE:
D >500!
每e EN SITY:
D 0. 831 g/cm 3 (55! )
每e OLU BIL IT Y:
S Soluble in benzene, hexane and m ethanol.
10. PHYSICAL HAZARD (STABILITY & REACTIVITY)
每STABILIT Y:
e
Decom position will not occur if used and stored according to specifications.
每e ON DITION TO AVOID:
C
No dangerous reaction k nown.
每e AZARDOU S DECOMPOSIT ION P RODU CT S:
H
Thermal decomposition products: phosphine, oxides of nitrogen, carbon, phosphorus
11. TOXICOLOGICAL INFORMATION
每ACUT E TOXICIT Y:
e
ORAL: >3, 200mg/kg rat LD50
每LOCAL EF F ECTS:
e Irritant to sk in and mucous m em brane.
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12. ECOLOGICAL INFORMATION
每PERSIST EN CE/DEGRADABIL ITY:
e
Tri-n-octylphosphine oxide is not readily biodegradable.
每e COT OXCIT Y:
E
Do not allow material to release to the environm ent without proper governm ental perm it.
Toxic to fish: Bluegill Sunfish L C50(96hr) > 11. 3 m gL
13. DISPOSAL CONSIDERATION
Whatever cannot be saved for recovery m ay be burned in an approved incinerator or
disposed in an approved waste facility. Ensure com pliance with local, state and federal
regulations.
14. TRANSPORT INFORMATION
每e ROP ER SHIP PIN G N AME:
P Environm entally hazardous substance, solid, n. o. s.
(Trioctylphosphine oxide)
每e N CL ASS:
U 9
每e N N o.:
U 3077
每e ACKIN G GROUP:
P III
15. REGULATORY INFORMATION
16. OTHER INFORMATION
飥?? Notices 飥??
1) The Material Safety Data Sheet is a brief summary of general precautions necessary for
proper use of Our Company Product. For a special use and handling, use upon safety
confirm ation and implem entation of the measures suited to the application.
2) The contents entered into this sheet was prepared based on the documents and test data
available at the tim e of preparation but does not guarantee at all the descriptions of
Com position/Inform ation on Ingredients, Physical & Chemical Properties and Hazards
Identification.
3) Every chemical product may present unknown hazards and should be used with utmost
caution. All users should bear the responsibility of setting of the safe use conditions.
4) The information herein is subject to change by new findings such as new literatures and
test results and revisions of laws and regulations.
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