World Headquarters Page 1
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M02061
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Pyridine/Barbituric Acid Reagent
Catalog Number: 52013EB
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M02061
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Laboratory Reagent
CAS No.: Not applicable
Hazard: Causes eye and skin irritation Harmful if absorbed through skin. Combustible.
Date of MSDS Preparation:
Day: 13
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-(0)1-2515151
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Pyridine
EEC Number: 2038099
CAS No.: 110-86-1
Percent Range: 1,0 - 5,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 ppm
PEL: 5 ppm
EU Occupational Exposure Limits: 5 ppm (15 mg/m3)
Barbituric acid
EEC Number: 2006580
CAS No.: 67-52-7
Percent Range: 1,0 - 5,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Demineralized Water
EEC Number: 2317912
CAS No.: 7732-18-5
Percent Range: > 80
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
World Headquarters Page 2
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M02061
Loveland, CO USA 80539
(970) 669-3050
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Pyridine hydrochloride
EEC Number: 2110274
CAS No.: 628-13-7
Percent Range: 1,0 - 10,0
Percent Range Units: weight / volume
Ingredient EEC Symbol:
Ingredient R phrase(s) (R phrase details given in Heading 16):
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits:
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Pungent
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause: redness
Skin Absorption (EC): May be absorbed through skin.
Target Organs (SA E): Central nervous system
Ingestion (EC): Can cause: vomiting abdominal pain nausea central nervous system effects headache fatigue
anorexia
Target Organs (Ing E): Central nervous system Liver Kidneys
Inhalation: May cause: respiratory tract irritation pneumonitis Effects similar to those of ingestion.
Target Organs (Inh E): Central nervous system
Medical Conditions Aggravated: Pre-existing: Respiratory conditions Central nervous system diseases
Chronic Effects: Chronic overexposure may cause liver damage kidney damage
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. a suspected
teratogen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water for 15 minutes. Call physician immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Never give anything by mouth to an
unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: carbon monoxide, carbon dioxide. nitrogen oxides.
Fire / Explosion Hazards: None reported
World Headquarters Page 3
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M02061
Loveland, CO USA 80539
(970) 669-3050
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Evacuate area and fight fire from a safe distance.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non-reactive sorbent material. Stop spilled material from being
released to the environment.
Clean-up Technique: Scoop up slurry into a large beaker. Dispose of material in an E.P.A. approved hazardous waste
facility. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a gallon or more of liquid is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes Do not breathe mist or vapors. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Store in a cool, dry place. Keep away from: alkalies metals
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes Do not breathe: mist/vapor Wash thoroughly after handling. Keep
away from: alkalies metals
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits:
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Pungent
pH: 5.62
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: Not determined
Melting Point: Not applicable
Flash Point: 56 掳C (133 掳F)
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not determined
Upper Explosion Limits: Not determined
Specific Gravity (water = 1): Not determined
World Headquarters Page 4
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M02061
Loveland, CO USA 80539
(970) 669-3050
Evaporation Rate (water = 1): Not determined
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Miscible
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heating to decomposition.
Reactivity / Incompatibility: Incompatible with: chlorosulfonic acid nitric acid oxidizers
Hazardous Decomposition: Heating to decomposition releases: carbon dioxide carbon monoxide nitrogen oxides
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Ppyridine: oral rat LD50 = 891 mg/kg; barbituric acid: oral rat LD50 >5 gm/kg; pyridine
hydrochloride: oral rat LD50 = 1600 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: Pyridine: fathead minnow LC50 = 106 mg/l/96H; ciliateLC100 = 113.8 mmole/l/24H
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Pyridine Solution
--
ICAO Hazard Class: 3
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1282
World Headquarters Page 5
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M02061
Loveland, CO USA 80539
(970) 669-3050
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Pyridine Solution
--
I.M.O. Hazard Class: 3
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1282
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Pyridine Solution
--
A.D.R Hazard Class: 3
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 1282
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. Outside Testing.
NIOSH/OSHA Occupational Health Guidelines for Chemical Hazards. Cincinnati: Department of Health and Human
Services, 1981.
R PHRASES: Not applicable
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
|