HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
2301-53 FerroZine Iron Reagent
Print date : 30.04.2008 Product code : 230153 Page 1 of 6
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
2301-53 FerroZine Iron Reagent
Use of the substance/preparation
Water analysis
Company/undertaking identification
HACH LANGE GmbH
Company name :
Willst盲tterstr. 11
Street :
Place : D-40549 D眉sseldorf
+49 (0)211 5288-383
Telephone :
marion.ives@hach-lange.de
e-mail :
www.hach-lange.com
Internet :
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie
2. Hazards identification
Classification
Indications of danger : Toxic
R-phrases :
Causes burns.
Toxic by inhalation, in contact with skin and if swallowed.
3. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
CAS-No. Chemical name Quantity Classification
EC-No.
200-677-4 68-11-1 thioglycolic acid 40,0-50,0 % T, C R23/24/25-34
231-791-2 7732-18-5 Wasser 30,0-40,0 %
226-540-9 5421-46-5 Ammonium thioglycolate 15,0-25,0 %
69898-45-9 Ferrozine <1 %
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Take off contaminated clothing and shoes immediately.
Show this safety data sheet to the doctor in attendance.
Revision no. : 1.00 GB - EN Revision date : 27.04.2006
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
2301-53 FerroZine Iron Reagent
Print date : 30.04.2008 Product code : 230153 Page 2 of 6
After inhalation
Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion.
Consult a physician for severe cases.
After contact with skin
Wash off immediately with plenty of water.
If skin irritation persists, call a physician.
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician
immediately.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours. The following may develop in event of fire: sulfur oxides.,
Carbon monoxide, carbon dioxide (CO2)
Special protective equipment for fire-fighters
In the case of respirable dust and/or fumes, use self-contained breathing apparatus and dust
impervious protective suit.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust).Sweep up or vacuum up spillage and collect in suitable container for disposal.
7. Handling and storage
Handling
Advice on safe handling
Avoid contact with skin and eyes.
Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry and well-ventilated place.
Revision no. : 1.00 GB - EN Revision date : 27.04.2006
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
2301-53 FerroZine Iron Reagent
Print date : 30.04.2008 Product code : 230153 Page 3 of 6
Advice on storage compatibility
Incompatible with acids.
8. Exposure controls/personal protection
Exposure limit values
Exposure limits (EH40)
CAS-No. Chemical name ml/m鲁 mg/m鲁 F/ml Category Origin
68-11-1 Mercaptoacetic acid 1 3.8 TWA (8 h) WEL
- - STEL (15 min) WEL
Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace. Wash hands before breaks and at the end of
workday.
Respiratory protection
In the case of dust or aerosol formation use respirator with an approved filter.
Hand protection
Use barrier skin cream. The selected protective gloves have to satisfy the specifications of EU
Directive 89/689/EEC and the standard EN 374 derived from it.
Eye protection
Safety glasses with side-shields
9. Physical and chemical properties
General information
liquid
Physical state :
yellow
Colour :
strong, unpleasant
Odour :
Important health, safety and environmental information
Test method
3,5
pH-Value (at 20 掳C) :
Changes in the physical state
no data available
Melting point :
no data available
Boiling point :
no data available
Sublimation point :
no data available
Softening point :
not applicable
Flash point :
Explosive properties
not applicable
Density (at 20 掳C) : 1,310 g/cm鲁
miscible
Water solubility :
(at 20 掳C)
10. Stability and reactivity
Conditions to avoid
Extremes of temperature and direct sunlight.
Materials to avoid
strong acids and oxidizing agents
Revision no. : 1.00 GB - EN Revision date : 27.04.2006
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
2301-53 FerroZine Iron Reagent
Print date : 30.04.2008 Product code : 230153 Page 4 of 6
Hazardous decomposition products
To avoid thermal decomposition, do not overheat. Heating can release hazardous gases.
Ammonia, Sulphur oxides
11. Toxicological information
Acute toxicity
LD50/oral/rat = 190mg/kg
Specific effects in experiment on an animal
Thioglycolid acid: LD50/oral/rat = 114mg/kg
Thioglycolid acid: rabbit skin LDLo= 300
Corrosive and irritant effects
Causes burns.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
2810
UN number :
6.1
ADR/RID class :
Warning plate
ADR/RID packing group : III
Description of the goods
Toxic liquid, organic, n.o.s. (Thioglycolic acid/ammonium thioglycolate)
Inland waterways transport
Other applicable information (inland waterways transport)
Not tested
Marine transport
Revision no. : 1.00 GB - EN Revision date : 27.04.2006
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
2301-53 FerroZine Iron Reagent
Print date : 30.04.2008 Product code : 230153 Page 5 of 6
2810
UN number :
6.1
IMDG code :
--
Marine pollutant :
III
IMDG packing group :
F-A,S-A
EmS :
Description of the goods
Toxic liquid, organic, n.o.s. (Thioglycolic acid/ammonium thioglycolate solution)
Air transport
2810
UN/ID number :
8
ICAO/IATA-DGR :
III
ICAO packing group :
Description of the goods
Toxic liquid, organic, n.o.s. (Thioglycolic acid/ammonium thioglycolate solution)
Further Information
Additional Information:This product may be shipped as part of a chemical kit composed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit, Hazard Class: 9, UN Number3316, Package
group II, EMS Code: F-A, S-P
These transport data apply to the entire pack
15. Regulatory information
Labelling
T - Toxic
Danger symbols :
T - Toxic
Hazardous component(s) to be indicated on label
thioglycolic acid
R phrases
34 Causes burns.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
S phrases
25 Avoid contact with eyes.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
27/28 After contact with skin, take off immediately all contaminated clothing, and wash immediately
with plenty of water .
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
National regulatory information
Employment restrictions : Observe employment restrictions for young people. Observe employment
restrictions for child bearing mothers and nursing.
16. Other information
Full text of R-phrases referred to under sections 2 and 3
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
Revision no. : 1.00 GB - EN Revision date : 27.04.2006
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
2301-53 FerroZine Iron Reagent
Print date : 30.04.2008 Product code : 230153 Page 6 of 6
34 Causes burns.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1.00 GB - EN Revision date : 27.04.2006
|