World Headquarters Page 1
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M01276
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Mixed Bromcresol Green Methyl Red Indicator Solution
Catalog Number: 2628732
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M01276
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Indicator for pH
CAS No.: Not applicable
Hazard: Flammable. Causes moderate eye irritation.
Date of MSDS Preparation:
Day: 13
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-(0)1-2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Isopropanol
EEC Number: 2006617
CAS No.: 67-63-0
Percent Range: > 99,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Xi - IRRITATING F - HIGHLY FLAMMABLE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 11 R 36 R 67
TLV: 400 ppm (500 ppm STEL)
PEL: 400 ppm
EU Occupational Exposure Limits: 200 ppm (500 mg/m3)
Bromcresol Green
EEC Number: 2009728
CAS No.: 76-60-8
Percent Range: 0,1
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Methyl Red
EEC Number: 2077761
CAS No.: 493-52-7
Percent Range: < 0,1
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
World Headquarters Page 2
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M01276
Loveland, CO USA 80539
(970) 669-3050
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless
Odor: Alcoholic
EU Symbols: F - HIGHLY FLAMMABLE Xi - IRRITATING
R PHRASES: R 11: Highly flammable. R 36: Irritating to eyes. R 67: Vapours may cause drowsiness and dizziness.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes moderate irritation
Skin Contact (EC): Causes mild irritation
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): Causes: drowsiness dizziness incoordination giddiness depression headache abdominal pain
nausea vomiting diarrhea blood pressure problems rapid pulse and respirations respiratory arrest coma death
Target Organs (Ing E): Central nervous system
Inhalation: Causes: irritation of nose and throat drowsiness dizziness incoordination giddiness headache
depression abdominal pain nausea vomiting diarrhea blood pressure changes rapid pulse and respirations respiratory
arrest coma death
Target Organs (Inh E): Central nervous system
Medical Conditions Aggravated: Pre-existing: Skin conditions Respiratory conditions
Chronic Effects: No effects anticipated
Cancer / Reproductive Toxicity Information:
IARC Listed: No
Additional Cancer / Reproductive Toxicity Information: an experimental teratogen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Flammable Liquid
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: Flammable Liquid Do not expose to sparks or other ignition sources. May react violently
with: strong oxidizers
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Carbon dioxide Alcohol foam. Dry chemical.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Containers can build up pressure if exposed to heat.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
World Headquarters Page 3
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M01276
Loveland, CO USA 80539
(970) 669-3050
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Remove all combustible material
from spill area. Remove all ignition and spark-creating sources from the spill area. Cover spilled liquid with a
commercially available flammable liquid sorbent such as vapor barrier blanket or activated carbon to avoid evolution of
fumes. Vapors may travel to a source of ignition and flash back. May be ignited by: heat, sparks, or flames. Material will
float on water creating a fire hazard. Dike the material to create a barrier to combustibles.
Clean-up Technique: Eliminate all sources of ignition. Do not breathe the fumes. Cover with an inert material, such as
sand. Use only non-sparking tools. Sweep up material. Incinerate material at an E.P.A. approved hazardous waste facility.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling. Use
with adequate ventilation. Maintain general industrial hygiene practices when using this product.
Storage: Store away from: combustible materials oxidizers sparks, flames and other ignition sources Protect from: heat
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Indicator for pH
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Use a fume hood to avoid
exposure to dust, mist or vapor. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Use with adequate ventilation. Protect from: heat Keep away from: oxidizers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: For Isopropyl alcohol: 200 ppm (500 mg/m3)
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless
Physical State: Liquid
Odor: Alcoholic
pH: Not determined
Vapor Pressure: 33 mm @ 20掳C
Vapor Density (air = 1): 2,07
Boiling Point: ~82掳C
Melting Point: Not applicable
Flash Point: 11,7掳C; 53掳F
Method: Closed cup
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not determined
Upper Explosion Limits: Not determined
Specific Gravity (water = 1): 0,78
Evaporation Rate (water = 1): 2,3
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Not determined
World Headquarters Page 4
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M01276
Loveland, CO USA 80539
(970) 669-3050
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: Incompatible with: potassium-tert-butoxide cobalt chloride aluminum oleum nitro
compounds oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Isopropanol: Skin rabbit 500 mg - MILD: Eye rabbit 100 mg - SEVERE; Eye rabbit 10
mg - MODERATE; Eye rabbit 100 mg/24H - MODERATE
Mutation Data: Isopropanol: Cytogenetic analysis, rat, inhalation - 1030 碌g/m鲁/16W (Intermittent)
Reproductive Effects Data: IPA: Oral rat TDLo 11340 mg/kg-Maternal effects-menstrual cycle changes or disordersl
Oral rat TDLo 5040 mg/kg-Litter size; Oral rat TDLo 20160 mg/kg-Pre-implantation mortality; Oral rat TDLo 32400
碌g/kg-Embryo or fetus death;
Oral rat TDLo 6480 mg/kg-Effects on newborn-growth statistics; Inhalation rat TCLo 3500 ppm/7H-Embryo or fetus
death; Inhalation rat TCLo 10000ppm/7H-Pre-implantation mortality, post-implntation mortality, embryo or fetus death
Ingredient Toxicological Data: Isopropanol: Oral rat LD50 = 5045 mg/kg; Oral Human LDLo = 2770 mg/kg
IARC Listed: No
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: IPA: LD50 goldfish 5000 mg/L/24H; LC50 brown shrimp 1400 mg/L/48H; LC50
brown shrimp 1150 mg/L/96H;; LC50 fathead minnows 11160 mg/L/24H; Cell multiplication test Mecrocystis aeruginosa
(algae) 1000 mg/L
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Isopropanol Solution
--
ICAO Hazard Class: 3
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1219
World Headquarters Page 5
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M01276
Loveland, CO USA 80539
(970) 669-3050
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Isopropanol Solution
--
I.M.O. Hazard Class: 3
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1219
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Isopropanol Solution
--
A.D.R Hazard Class: 3
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 1219
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: F - HIGHLY FLAMMABLE Xi - IRRITATING
R PHRASES: R 11: Highly flammable. R 36: Irritating to eyes. R 67: Vapours may cause drowsiness and dizziness.
S PHRASES: S 7: Keep container tightly closed. S 16: Keep away from sources of ignition - No smoking. S 24/25:
Avoid contact with skin and eyes. S 26: In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
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16. OTHER INFORMATION
References: In-house information. NIOSH Registry of Toxic Effects of Chemical Substances, 1985-86. Cincinnati: U.S.
Department of Health and Human Services, April, 1987. Patty, Frank A. Industrial Hygiene and Toxicology, 3rd Revised
Edition. Volume 2. New York: A Wiley-Interscience Publication, 1981. Gosselin, R. E. et al. Clinical Toxicology of
Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Technical Judgment. NIOSH/OSHA
Occupational Health Guidelines for Chemical Hazards. Cincinnati: Department of Health and Human Services, 1981.
Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989.
Vendor Information. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Air Contaminants,
Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and
Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
R PHRASES: R 11: Highly flammable. R 36: Irritating to eyes. R 67: Vapours may cause drowsiness and dizziness.
Use of the substance/preparation: Indicator for pH
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
World Headquarters Page 6
Hach Company Date Printed 1/13/06
P.O.Box 389 MSDS No: M01276
Loveland, CO USA 80539
(970) 669-3050
HACH COMPANY 漏2006
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