HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
26588-25 HgEx Reagent A Stannous Sulfate Solution
Print date : 01.05.2008 Product code : 2658825 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
26588-25 HgEx Reagent A Stannous Sulfate Solution
Use of the substance/preparation
Water analysis
Company/undertaking identification
HACH LANGE GmbH
Company name :
Willst盲tterstr. 11
Street :
Place : D-40549 D眉sseldorf
+49 (0)211 5288-383
Telephone :
marion.ives@hach-lange.de
e-mail :
www.hach-lange.com
Internet :
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie
2. Hazards identification
Classification
This preparation is not classified as dangerous according to Directive 1999/45/EC.
The product does not need to be labelled in accordance with EC directives or respective national
laws.
3. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
CAS-No. Chemical name Quantity Classification
EC-No.
231-791-2 7732-18-5 Water 85-95 %
231-302-2 7488-55-3 Tin(II) sulfate 5-15 %
231-639-5 7664-93-9 sulphuric acid ... % 1-5 % C R35
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Take off all contaminated clothing immediately.
Consult a physician. Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air.
Revision no. : 1.00 GB - EN Revision date : 24.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
26588-25 HgEx Reagent A Stannous Sulfate Solution
Print date : 01.05.2008 Product code : 2658825 Page 2 of 5
After contact with skin
Wash off immediately with plenty of water.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. The product itself does not burn.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
7. Handling and storage
Handling
Advice on safe handling
Use only in well-ventilated areas.
Avoid contact with skin and eyes.
Storage
Requirements for storage rooms and vessels
Keep in a dry, cool place.
8. Exposure controls/personal protection
Exposure limit values
Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Wash hands before breaks and after work.
Revision no. : 1.00 GB - EN Revision date : 24.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
26588-25 HgEx Reagent A Stannous Sulfate Solution
Print date : 01.05.2008 Product code : 2658825 Page 3 of 5
Respiratory protection
Provide adequate ventilation.
Hand protection
Use barrier skin cream.
Chemical resistant gloves made of butyl rubber or nitrile rubber category III according to EN 374. In
full contact: Gloves material: Viton, Layer thickness: 0.70 mm, Breakthrough time: >480 min. In
splash contact: Glove material: nitrile rubber, Layer thickness 0,20 mm, Breakthrough time: > 30 min
Eye protection
Safety glasses with side-shields
Skin protection
Remove and wash contaminated clothing before re-use.
9. Physical and chemical properties
General information
liquid
Physical state :
dark green
Colour :
stinging
Odour :
Important health, safety and environmental information
Test method
<1
pH-Value (at 20 掳C) :
Changes in the physical state
100 掳C
Boiling point :
not applicable
Flash point :
not applicable
Lower explosion limits :
not applicable
Upper explosion limits :
Density (at 20 掳C) : 1,10 g/cm鲁
10. Stability and reactivity
Conditions to avoid
Extremes of temperature and direct sunlight.
To avoid thermal decomposition, do not overheat.
Materials to avoid
No dangerous reaction known under conditions of normal use.
Hazardous decomposition products
Sulphur oxides
Tin oxide fumes.
Additional information
Stable under recommended storage conditions.
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Specific effects in experiment on an animal
No data is available on the product itself.
12. Ecological information
Revision no. : 1.00 GB - EN Revision date : 24.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
26588-25 HgEx Reagent A Stannous Sulfate Solution
Print date : 01.05.2008 Product code : 2658825 Page 4 of 5
Ecotoxicity
No data is available on the product itself.
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
3264
UN number :
8
ADR/RID class :
Warning plate
ADR/RID packing group : III
Description of the goods
Corrosive liquid, acidic, inorganic, n.o.s.
Inland waterways transport
Other applicable information (inland waterways transport)
Not tested
Marine transport
3264
UN number :
8
IMDG code :
III
IMDG packing group :
F-A,S-B
EmS :
Description of the goods
Corrosive liquid, acidic, inorganic, n.o.s. (<10% Sulphuric acid solution)
Air transport
3264
UN/ID number :
8
ICAO/IATA-DGR :
III
ICAO packing group :
Description of the goods
Corrosive liquid, acidic, inorganic, n.o.s. (<10% Sulphuric acid solution)
Further Information
Revision no. : 1.00 GB - EN Revision date : 24.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
26588-25 HgEx Reagent A Stannous Sulfate Solution
Print date : 01.05.2008 Product code : 2658825 Page 5 of 5
Additional Information:This product may be shipped as part of a chemical kit composed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit, Hazard Class: 9, UN Number3316, Package
group II, EMS Code: F-A, S-P
15. Regulatory information
Labelling
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
EU regulatory information
Additional information
The product does not need to be labelled in accordance with EC directives or respective national
laws.
National regulatory information
Water contaminating class (D) : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
35 Causes severe burns.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1.00 GB - EN Revision date : 24.01.2008
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