HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, Sample cuvette, 1/2
Print date : 02.05.2008 Product code : LCK340-1 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK 340 Nitrat/Nitrate, Sample cuvette, 1/2
Use of the substance/preparation
Water analysis
Company/undertaking identification
HACH LANGE GmbH
Company name :
Willst盲tterstr. 11
Street :
Place : D-40549 D眉sseldorf
+49 (0)211 5288-383
Telephone :
marion.ives@hach-lange.de
e-mail :
www.hach-lange.com
Internet :
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie
2. Hazards identification
Classification
Indications of danger : Corrosive
R-phrases :
Causes severe burns.
3. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
CAS-No. Chemical name Quantity Classification
EC-No.
231-639-5 7664-93-9 sulphuric acid ... % 60 % C R35
231-791-2 7732-18-5 Water 7%
231-633-2 7664-38-2 phosphoric acid ... %, orthophosphoric 33 % C R34
acid ... %
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Take off all contaminated clothing immediately.
Consult a physician. Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air.
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, Sample cuvette, 1/2
Print date : 02.05.2008 Product code : LCK340-1 Page 2 of 5
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes. Consult a physician. Show this
safety data sheet to the doctor in attendance.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Show this safety
data sheet to the doctor in attendance.
After ingestion
Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting.
Consult a physician. Show this safety data sheet to the doctor in attendance.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. The product itself does not burn.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours. The following may develop in event of fire: sulfur oxides.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. In order to avoid contact with skin, keep
a safety distance and wear suitable protective clothing.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material and dispose of as hazardous waste.
7. Handling and storage
Handling
Advice on safe handling
Use only in well-ventilated areas. Do not breathe vapours/dust.
Storage
Requirements for storage rooms and vessels
Keep tightly closed in a dry, cool and well-ventilated place.
8. Exposure controls/personal protection
Exposure limit values
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, Sample cuvette, 1/2
Print date : 02.05.2008 Product code : LCK340-1 Page 3 of 5
Exposure limits (EH40)
CAS-No. Chemical name ml/m鲁 mg/m鲁 F/ml Category Origin
7664-38-2 Orthophosphoric acid - 1 TWA (8 h) WEL
- 2 STEL (15 min) WEL
Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Breathing apparatus only if aerosol or dust is formed.
Hand protection
Use barrier skin cream.
Wash hands before breaks and after work.
Chemical resistant protective gloves
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and
the resultant standard EN374.
Eye protection
Safety glasses with side-shields
Skin protection
Remove and wash contaminated clothing before re-use.
9. Physical and chemical properties
General information
liquid
Physical state :
colourless
Colour :
odourless
Odour :
Important health, safety and environmental information
Test method
<1
pH-Value (at 20 掳C) :
Changes in the physical state
not applicable
Flash point :
not applicable
Lower explosion limits :
not applicable
Upper explosion limits :
Density (at 20 掳C) : 1,78 g/cm鲁
completely soluble
Water solubility :
(at 20 掳C)
10. Stability and reactivity
Conditions to avoid
To avoid thermal decomposition, do not overheat. Above 300 掳C, hazardous fumes may be released.
Gives off hydrogen by reaction with metals.
Materials to avoid
metals
Hazardous decomposition products
Sulphur trioxide
Additional information
very reactive
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, Sample cuvette, 1/2
Print date : 02.05.2008 Product code : LCK340-1 Page 4 of 5
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Corrosive and irritant effects
The product causes burns of eyes, skin and mucous membranes.
12. Ecological information
Ecotoxicity
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Advice on disposal
Our local agencies will accept used cuvettes to ensure their proper disposal.
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
3316
UN number :
9
ADR/RID class :
Warning plate
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Other applicable information (inland waterways transport)
Not tested
Marine transport
3316
UN number :
9
IMDG code :
--
Marine pollutant :
II
IMDG packing group :
F-A,S-P
EmS :
Description of the goods
Chemical kit
Air transport
3316
UN/ID number :
9
ICAO/IATA-DGR :
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, Sample cuvette, 1/2
Print date : 02.05.2008 Product code : LCK340-1 Page 5 of 5
II
ICAO packing group :
Description of the goods
Chemical kit
Further Information
These transport data apply to the entire pack
15. Regulatory information
Labelling
C - Corrosive
Danger symbols :
C - Corrosive
Hazardous component(s) to be indicated on label
sulphuric acid ... %
phosphoric acid ... %, orthophosphoric acid ... %
R phrases
35 Causes severe burns.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
37/39 Wear suitable gloves and eye/face protection.
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
National regulatory information
Water contaminating class (D) : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
34 Causes burns.
35 Causes severe burns.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, LCK 340 A; 2/2
Print date : 02.05.2008 Product code : LCK340-2 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK 340 Nitrat/Nitrate, LCK 340 A; 2/2
Use of the substance/preparation
Water analysis
Company/undertaking identification
HACH LANGE GmbH
Company name :
Willst盲tterstr. 11
Street :
Place : D-40549 D眉sseldorf
+49 (0)211 5288-383
Telephone :
marion.ives@hach-lange.de
e-mail :
www.hach-lange.com
Internet :
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie
2. Hazards identification
Classification
R-phrases :
Flammable.
3. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
CAS-No. Chemical name Quantity Classification
EC-No.
231-791-2 7732-18-5 Water >95 %
200-661-7 67-63-0 isopropanol, isopropyl alcohol, <5 % F, Xi R11-36-67
propan-2-ol
209-400-1 576-26-1 2,6-xylenol <1 % T, C, N R24/25-34-51-53
204-662-3 123-92-2 isopentyl acetate <1 % R10-66
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Take off all contaminated clothing immediately.
After inhalation
Move to fresh air.
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, LCK 340 A; 2/2
Print date : 02.05.2008 Product code : LCK340-2 Page 2 of 5
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Show this safety
data sheet to the doctor in attendance.
After ingestion
Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting.
Consult a physician. Show this safety data sheet to the doctor in attendance.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
carbon dioxide (CO2), foam, dry powder
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. In order to avoid contact with skin, keep
a safety distance and wear suitable protective clothing.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material and dispose of as hazardous waste.
7. Handling and storage
Handling
Advice on safe handling
Use only in well-ventilated areas. Do not breathe vapours/dust.
Storage
Requirements for storage rooms and vessels
Keep tightly closed in a dry, cool and well-ventilated place.
8. Exposure controls/personal protection
Exposure limit values
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, LCK 340 A; 2/2
Print date : 02.05.2008 Product code : LCK340-2 Page 3 of 5
Exposure limits (EH40)
CAS-No. Chemical name ml/m鲁 mg/m鲁 F/ml Category Origin
123-92-2 Pentyl acetates 50 270 TWA (8 h) WEL
100 541 STEL (15 min) WEL
67-63-0 Propan-2-ol 400 999 TWA (8 h) WEL
500 1250 STEL (15 min) WEL
Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Breathing apparatus only if aerosol or dust is formed.
Hand protection
Use barrier skin cream.
Wash hands before breaks and after work.
Chemical resistant protective gloves
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and
the resultant standard EN374.
Eye protection
Safety glasses with side-shields
Skin protection
Remove and wash contaminated clothing before re-use.
9. Physical and chemical properties
General information
liquid
Physical state :
colourless
Colour :
aromatic
Odour :
Important health, safety and environmental information
Test method
6
pH-Value (at 20 掳C) :
Changes in the physical state
approx.100 掳C
Boiling point :
53 掳C DIN 51755
Flash point :
not applicable
Lower explosion limits :
not applicable
Upper explosion limits :
Vapour pressure : 2-Prop. 43 hPa
(at 20 掳C)
Density (at 20 掳C) : 0,95 g/cm鲁
completely soluble
Water solubility :
10. Stability and reactivity
Conditions to avoid
No dangerous reaction known under conditions of normal use.
Hazardous decomposition products
No decomposition if used as directed.
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, LCK 340 A; 2/2
Print date : 02.05.2008 Product code : LCK340-2 Page 4 of 5
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
12. Ecological information
Ecotoxicity
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Advice on disposal
Our local agencies will accept used cuvettes to ensure their proper disposal.
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
3316
UN number :
9
ADR/RID class :
Warning plate
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Other applicable information (inland waterways transport)
Not tested
Marine transport
3316
UN number :
9
IMDG code :
--
Marine pollutant :
II
IMDG packing group :
F-A, S-P
EmS :
Description of the goods
Chemical kit
Air transport
3316
UN/ID number :
9
ICAO/IATA-DGR :
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 340 Nitrat/Nitrate, LCK 340 A; 2/2
Print date : 02.05.2008 Product code : LCK340-2 Page 5 of 5
II
ICAO packing group :
Description of the goods
Chemical kit
Further Information
These transport data apply to the entire pack
15. Regulatory information
Labelling
Hazardous component(s) to be indicated on label
isopropanol, isopropyl alcohol, propan-2-ol
R phrases
10 Flammable.
S phrases
07 Keep container tightly closed.
16 Keep away from sources of ignition - No smoking.
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
National regulatory information
Water contaminating class (D) : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
10 Flammable.
11 Highly flammable.
24/25 Toxic in contact with skin and if swallowed.
34 Causes burns.
36 Irritating to eyes.
51 Toxic to aquatic organisms.
53 May cause long-term adverse effects in the aquatic environment.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1.00 GB - EN Revision date : 07.01.2008
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