World Headquarters Page 1
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00460
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: TanniVer庐 3 Tannin-Lignin Reagent
Catalog Number: 256032
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00460
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of Tannin/Lignin
CAS No.: Not applicable
Hazard: Causes burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-(0)1-2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Lithium Sulfate
EEC Number: 2338204
CAS No.: 10102-25-7
Percent Range: 10,0 - 20,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Hydrochloric Acid
EEC Number: 2315957
CAS No.: 7647-01-0
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 ppm ceiling
PEL: 5 ppm ceiling
EU Occupational Exposure Limits: Hydrogen chloride: 5 ppm (8 mg/m3); STEL 10 ppm (15 3)
Sodium Molybdate
EEC Number: 2315517
CAS No.: 10102-40-6
Percent Range: 1,0 - 5,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
World Headquarters Page 2
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00460
Loveland, CO USA 80539
(970) 669-3050
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 mg/m鲁 (as Mo)
PEL: 5 mg/m鲁 (as Mo)
EU Occupational Exposure Limits: 5 mg/m3 as Mo
Demineralized Water
EEC Number: 2317912
CAS No.: 7732-18-5
Percent Range: 60,0 - 70,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Phosphoric Acid
EEC Number: 2316332
CAS No.: 7664-38-2
Percent Range: 1,0 - 10,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 1 mg/m3
PEL: 1 mg/m3
EU Occupational Exposure Limits: 0,2 ppm (1 mg/m3); STEL 0,5 ppm (2 mg/m3)
Sodium Tungstate VI
EEC Number: 2367434
CAS No.: 10213-10-2
Percent Range: 5,0 - 15,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 1 mg/m3 (W)
PEL: 1 mg/m3 (W)
EU Occupational Exposure Limits: 1 mgm3
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, yellow liquid
Odor: None
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
World Headquarters Page 3
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00460
Loveland, CO USA 80539
(970) 669-3050
Potential Health Effects:
Eye Contact (EC): None reported
Skin Contact (EC): None reported
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: irritation of the mouth and esophagus drowsiness weakness blurred vision anemia
gastrointestinal disturbances nausea diarrhea central nervous system effects respiratory arrest circulatory collapse
coma
Target Organs (Ing E): Circulatory system Central nervous system
Inhalation: May cause: irritation of nose and throat difficult breathing drowsiness blurred vision central nervous
system effects respiratory arrest circulatory disturbances coma
Target Organs (Inh E): Central nervous system Circulatory system
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions Impaired
pulmonary function such as obstructive airway diseases.
Chronic Effects: Lithium compounds have been implicated in development of aplastic anemia. Signs of lithium
poisoning include dehydration, extreme weight loss, fine tremor of hands, nausea, vomiting and diarrhea, Chronic
overexposure may cause central nervous system effects enzyme activity effects pulmonary fibrosis
Cancer / Reproductive Toxicity Information:
IARC Group 3: Non-classifiable
Hydrochloric acid
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Never give anything by mouth to an
unconscious person. Call physician immediately.
Inhalation: Remove to fresh air.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Does not burn, but may melt in a fire, releasing toxic fumes.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non-reactive sorbent material. Stop spilled material from being
released to the environment.
Clean-up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoop up slurry into
a large beaker. Dilute with a large excess of water. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or
sodium bicarbonate. Flush reacted material to the drain with a large excess of water. Decontaminate the area of the spill
with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled.
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World Headquarters Page 4
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00460
Loveland, CO USA 80539
(970) 669-3050
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Protect from: heat Keep away from: metals wood
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of Tannin/Lignin
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Maintain general industrial
hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Protect from: heat Keep away from: metals wood
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, yellow liquid
Physical State: Liquid
Odor: None
pH: 1,0
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: ~100掳 C (~212掳 F)
Melting Point: Not determined
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,172
Evaporation Rate (water = 1): 0,59
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0.610 in/yr
Aluminum: Not determined
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Extreme temperatures
Reactivity / Incompatibility: Incompatible with: strong bases metals wood
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: chlorides sulfur oxides
Hazardous Polymerization: Will not occur.
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World Headquarters Page 5
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00460
Loveland, CO USA 80539
(970) 669-3050
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium Tungstate: Oral rat LD50 = 1190 mg/kg; H3PO4: Oral rat LD50 = 1530 mg/kg;
HCl: Oral rabbit LD50 = 900 mg/kg, Inhal. LC50 = 3124 ppm; Sodium Molybdate: Oral rat LD50 = 4000 mg/kg; Lithium
Sulfate: Oral mouse LD50 = 1190 mg/kg
IARC Group 3: Non-classifiable
Hydrochloric acid
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: HCl: LC100 trout 10 mg/l 24-hr; LC50 shrimp 100 to 330 ppm/48-hr (salt water);
LC50 Starfish 100 to 330 mg/l/48-hr; LC50 cockle 330 to 1000 mg/l/48-hr; TLm mosquito fish 282 ppm/96-hr (fresh
water); LC50 goldfish 178 mg/l
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(Hydrochloric Acid/Phosphoric Acid Solution)
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN3264
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(Hydrochloric Acid/Phosphoric Acid Solution)
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN3264
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(Hydrochloric Acid/Phosphoric Acid Solution)
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 3264
A.D.R. Packing Group: II
World Headquarters Page 6
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00460
Loveland, CO USA 80539
(970) 669-3050
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
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16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,
1989. pp. 2332-2983. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Sax, N. Irving and
Richard J. Lewis, Sr., revised by. Hawley's Condensed Chemical Dictionary, Eleventh Ed. New York: Van Nostrand
Reinhold Co., 1987. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand
Reinhold Co., 1989. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams
and Wilkins Co., 1984. CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario
Canada: 30 June 1993. Technical Judgment.
R PHRASES: Not applicable
Use of the substance/preparation: Determination of Tannin/Lignin
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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