World Headquarters Page 1
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00701
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: 2,2-Bipyridine
Catalog Number: 11622
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00701
Chemical Name: 2,2'-Bipyridine
Chemical Formula: C10H8N2
Chemical Family: Aromatic Amines
Use of the substance/preparation: Laboratory Reagent
CAS No.: 366-18-7
Hazard: May cause irritation. Harmful if swallowed
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-(0)1-2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
2,2-Bipyridine
EEC Number: 2066744
CAS No.: 366-18-7
Percent Range: 100,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: T - TOXIC
Ingredient R phrase(s) (R phrase details given in Heading 16): R 25 R 40
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White crystals
Odor: None
EU Symbols: T - TOXIC
R PHRASES: R 25: Toxic if swallowed. R 40: Limited evidence of a carcinogenic effect.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Toxic Can cause: abdominal pain muscular weakness kidney damage blood changes death
Target Organs (Ing E): Kidneys Blood
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Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00701
Loveland, CO USA 80539
(970) 669-3050
Inhalation: May cause: irritation of nose and throat
Target Organs (Inh E): Kidneys Blood
Medical Conditions Aggravated: None reported
Chronic Effects: Chronic overexposure may cause eye irritation skin irritation
Cancer / Reproductive Toxicity Information:
IARC Listed: No
Additional Cancer / Reproductive Toxicity Information: an experimental mutagen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Induce vomiting using syrup of ipecac or by sticking finger down throat. Never give anything by
mouth to an unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: cyanide compounds nitrogen oxides. carbon monoxide, carbon
dioxide.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Sweep up material. Incinerate material at an E.P.A. approved hazardous waste facility.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product. Use with adequate ventilation.
Storage: Keep container tightly closed when not in use. Protect from: heat moisture Keep away from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Use a fume hood to avoid exposure to dust, mist or vapor. Maintain general industrial hygiene
practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
World Headquarters Page 3
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00701
Loveland, CO USA 80539
(970) 669-3050
Inhalation Protection: dust / mist mask and / or laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Keep
away from: oxidizers Use with adequate ventilation.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White crystals
Physical State: Solid
Odor: None
pH: Not determined
Vapor Pressure: 1.30 x 10-5 mm Hg at 25掳C
Vapor Density (air = 1): Not applicable
Boiling Point: 272掳C
Melting Point: 69,7掳C
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): Not determined
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not determined
Solubility:
Water: 1:200
Acid: Not determined
Other: Soluble in alcohol, ether, benzene
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures Heating to decomposition.
Reactivity / Incompatibility: Incompatible with: oxidizers strong bases
Hazardous Decomposition: Toxic fumes of: nitrogen oxides carbon dioxide carbon monoxide
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral rat LD50 = 100 mg/kg
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: DNA damage - Hamster Lung - 12500 碌g/L; Mutated somatic cells - Hamster Lung - 14500 碌g/L
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: --
Not applicable
IARC Listed: No
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World Headquarters Page 4
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00701
Loveland, CO USA 80539
(970) 669-3050
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
Not applicable
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Toxic Solid, Organic, N.O.S.
(2,2'-Bipyridine)
ICAO Hazard Class: 6,1
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN2811
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Toxic Solid, Organic, N.O.S.
(2,2'-Bipyridine)
I.M.O. Hazard Class: 6,1
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN2811
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Toxic Solid, Organic, N.O.S.
(2,2'-Bipyridine)
A.D.R Hazard Class: 6,1
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 2811
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
EEC Number: 2066744
EEC LABEL COPY:
EU Symbols: T - TOXIC
R PHRASES: R 25: Toxic if swallowed. R 40: Limited evidence of a carcinogenic effect.
S PHRASES: S 22: Do not breathe dust. S 24: Avoid contact with skin.
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. In-house information. Vendor
Information. Technical Judgment. CCINFO CHEM Source/R茅f茅rences CHIMIE. Canadian Centre for Occupational
World Headquarters Page 5
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00701
Loveland, CO USA 80539
(970) 669-3050
Health and Safety. Hamilton, Ontario Canada: 30 June 1993. The Merck Index, 11th Ed. Rahway, New Jersey: Merck
and Co., Inc., 1989.
R PHRASES: R 25: Toxic if swallowed. R 40: Limited evidence of a carcinogenic effect.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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